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Wingenfelder, U.; Hansen, C.; Furrer, G.; Schulin, R. |
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Title |
Removal of heavy metals from mine waters by natural zeolites |
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Journal Article |
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Year |
2005 |
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Environ Sci Technol, ES & T |
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39 |
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12 |
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4606-4613 |
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Groundwater problems and environmental effects Pollution and waste management non radioactive remediation heavy metal mine drainage acid mine drainage; acidification; Central Europe; chemical composition; chemical fractionation; dissolved materials; Europe; framework silicates; geochemistry; grain size; heavy metals; hydrochemistry; ion exchange; lead; metals; mines; mining; mobilization; models; pH; pollutants; pollution; precipitation; remediation; samples; silicates; spectra; Switzerland; toxic materials; X-ray diffraction data; X-ray fluorescence spectra; zeolite group |
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G. Furrer, Institute of Terrestrial Ecology, Swiss Federal Institute of Technology, Zurich, Grabenstrasse 3, CH-8952 Schlieren, Switzerland gerhard.furrer@env.ethz.ch |
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0013-936x |
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Removal of heavy metals from mine waters by natural zeolites; 2006-086777; References: 42; illus. incl. 3 tables United States (USA); GeoRef; English |
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CBU @ c.wolke @ 5382 |
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71 |
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Author |
Conca, J.L.; Wright, J. |
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Title |
An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd |
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Journal Article |
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Year |
2006 |
Publication |
Appl. Geochem. |
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21 |
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12 |
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2188-2200 |
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Pollution and waste management non radioactive Groundwater quality apatite groundwater remediation zinc lead cadmium acid mine drainage copper sulfate nitrate permeability water treatment precipitation chemistry |
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Phosphate-induced metal stabilization involving the reactive medium Apatite II(TM) [Ca10-xNax(PO4)6-x(CO3)x(OH)2], where x < 1, was used in a subsurface permeable reactive barrier (PRB) to treat acid mine drainage in a shallow alluvial groundwater containing elevated concentrations of Zn, Pb, Cd, Cu, SO4 and NO3. The groundwater is treated in situ before it enters the East Fork of Ninemile Creek, a tributary to the Coeur d'Alene River, Idaho. Microbially mediated SO4 reduction and the subsequent precipitation of sphalerite [ZnS] is the primary mechanism occurring for immobilization of Zn and Cd. Precipitation of pyromorphite [Pb10(PO4)6(OH,Cl)2] is the most likely mechanism for immobilization of Pb. Precipitation is occurring directly on the original Apatite II. The emplaced PRB has been operating successfully since January of 2001, and has reduced the concentrations of Cd and Pb to below detection (2 μg L-1), has reduced Zn to near background in this region (about 100 μg L-1), and has reduced SO4 by between 100 and 200 mg L-1 and NO3 to below detection (50 μg L-1). The PRB, filled with 90 tonnes of Apatite II, has removed about 4550 kg of Zn, 91 kg of Pb and 45 kg of Cd, but 90% of the immobilization is occurring in the first 20% of the barrier, wherein the reactive media now contain up to 25 wt% Zn. Field observations indicate that about 30% of the Apatite II material is spent (consumed). |
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0883-2927 |
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Dec.; An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd; Science Direct |
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CBU @ c.wolke @ 17248 |
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44 |
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Nairn, R.W.; Griffin, B.C.; Strong, J.D.; Hatley, E.L. |
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Title |
Remediation challenges and opportunities at the Tar Creek Superfund Site, Oklahoma |
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Book Chapter |
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2001 |
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Proceedings of the Annual National Meeting – American Society for Surface Mining and Reclamation, vol.18 |
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579-584 |
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abandoned mines acid mine drainage collapse structures constructed wetlands environmental analysis geologic hazards ground water human ecology Kansas land subsidence lead metals mines Missouri Oklahoma pollution reclamation remediation springs Superfund sites surface water Tar Creek Superfund Site United States water resources wetlands zinc 22, Environmental geology |
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The Tar Creek Superfund Site is a portion of the abandoned lead and zinc mining area known as the Tri-State Mining District (OK, KS and MO) and includes over 100 square kilometers of disturbed land surface and contaminated water resources in extreme northeastern Oklahoma. Underground mining from the 1890s through the 1960s degraded over 1000 surface hectares, and left nearly 50 km of tunnels, 165 million tons of processed mine waste materials (chat), 300 hectares of tailings impoundments and over 2600 open shafts and boreholes. Approximately 94 million cubic meters of contaminated water currently exist in underground voids. In 1979, metal-rich waters began to discharge into surface waters from natural springs, bore holes and mine shafts. Six communities are located within the boundaries of the Superfund site. Approximately 70% of the site is Native American owned. Subsidence and surface collapse hazards are of significant concern. The Tar Creek site was listed on the National Priorities List (NPL) in 1983 and currently receives a Hazard Ranking System score of 58.15, making Tar Creek the nation's number one NPL site. A 1993 Indian Health Service study demonstrated that 35% of children had blood lead levels above thresholds dangerous to human health. Recent remediation efforts have focused on excavation and replacement of contaminated residential areas. In January 2000, Governor Frank Keating's Tar Creek Task Force was created to take a “vital leadership role in identifying solutions and resources available to address” the myriad environmental problems. The principle final recommendation was the creation of a massive wetland and wildlife refuge to ecologically address health, safety, environmental, and aesthetic concerns. Additional interim measures included continuing the Task Force and subcommittees; study of mine drainage discharge and chat quality; construction of pilot treatment wetlands; mine shaft plugging; investigations of bioaccumulation issues; establishment of an authority to market and export chat, a local steering committee, and a GIS committee; and development of effective federal, state, tribal, and local partnerships. |
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Vincent, R.; Burger, J.A.; Marino, G.G.; Olyphant, G.A.; Wessman, S.C.; Darmody, R.G.; Richmond, T.C.; Bengson, S.A.; Nawrot, J.R. |
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Remediation challenges and opportunities at the Tar Creek Superfund Site, Oklahoma; GeoRef; English; 2002-036287; 18th annual national meeting of the American Society for Surface Mining and Reclamation; Land reclamation, a different approach, Albuquerque, NM, United States, June 3-7, 2001 References: 20; illus. incl. 1 table |
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CBU @ c.wolke @ 16526 |
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290 |
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Erten-Unal, M.; Wixson, B.G. |
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Biotreatment and Chemical Speciation of Lead and Zinc Mine/Mill Wastewater Discharges in Missouri, USA |
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Journal Article |
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1999 |
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Water Air Soil Pollut. |
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116 |
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3-4 |
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501-522 |
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biotreatment lead and zinc mine wastewater MINTEQ speciation biotreatment lead and zinc mine wastewater minteq speciation trout salmo-gairdneri water |
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Continued mining development in the world's largest lead producing area has generated and increased concern over effective mine water treatment in Missouri's New Lead Belt. A new type of mine/mill wastewater treatment system was constructed which consisted of a tailings pond followed by a series of artificially constructed meandering biotreatment channels and a polishing lagoon. This system provided additional retention time and distance for the removal of heavy metals by abundant aquatic plants and sedimentation. Seasonal field sampling and analytical testing that evaluated the present system confirmed that it provided good treatment for removal of heavy metals within the company property and produced a final effluent within the state and federal regulatory guidelines. On average, greater than 95% of zinc and manganese in the drainage water were removed by the biotreatment system, while lead and copper were 50 to 60%. A chemical equilibrium model, MINTEQ, was also used to identify various species of lead and zinc in the biotreatment system. The model predicted that the major species of carbonates and hydroxides would be the predominant complexes of lead and zinc for the pH and alkalinity values reported in the biotreatment system. These results were also supported by the literature. |
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0049-6979 |
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Dec.; Biotreatment and Chemical Speciation of Lead and Zinc Mine/Mill Wastewater Discharges in Missouri, USA; Isi:000083273200004; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10115.pdf; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 17472 |
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16 |
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Author |
Stoica, L.; Dima, G. |
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Pb(II) removal from aqueous systems by biosorption-flotation on mycelial residues of Penicillium chrysogenum |
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Book Chapter |
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2000 |
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7th international Mine Water Association congress; Mine water and the environment |
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472-481 |
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bioremediation; flotation; ground water; lead; metals; Penicillium; Penicillium chrysogenum; pollution; remediation; sorption; water treatment 22, Environmental geology |
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Uniwersytet Slaski |
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Sosnowiec |
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Rozkowski, A. |
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8387431230 |
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Pb(II) removal from aqueous systems by biosorption-flotation on mycelial residues of Penicillium chrysogenum; GeoRef; English; 2002-018169; 7th international Mine Water Association congress; Mine water and the environment, Katowice-Ustron, Poland, Sept. 11-15, 2000 References: 6; illus. incl. 4 tables |
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CBU @ c.wolke @ 5852 |
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228 |
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