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Matlock, M.M.; Howerton, B.S.; Atwood, D.A. |
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Title |
Chemical precipitation of heavy metals from acid mine drainage |
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Journal Article |
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Year |
2002 |
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Water Res |
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36 |
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19 |
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4757-4764 |
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Keywords |
mine water treatment BDET Acid mine drainage Water treatment Remediation Heavy metals Chemical precipitation Mercury Iron |
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Abstract |
The 1,3-benzenediamidoethanethiol dianion (BDET, known commercially as MetX) has been developed to selectively and irreversibly bind soft heavy metals from aqueous solution. In the present study BDET was found to remove >90% of several toxic or problematic metals from AMD samples taken from an abandoned mine in Pikeville, Kentucky. The concentrations of metals such as iron, may be reduced at pH 4.5 from 194 ppm to below 0.009 ppm. The formation of stoichiomietric BDET-metal precipitates in this process was confirmed using X-ray powder diffraction (XRD), proton nuclear magnetic resonance (1H NMR), and infrared spectroscopy (IR). |
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0043-1354 |
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Nov.; Chemical precipitation of heavy metals from acid mine drainage; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/15005.pdf; Science Direct |
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CBU @ c.wolke @ 15005 |
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48 |
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Wingenfelder, U.; Hansen, C.; Furrer, G.; Schulin, R. |
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Title |
Removal of heavy metals from mine waters by natural zeolites |
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Journal Article |
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2005 |
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Environ Sci Technol, ES & T |
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39 |
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12 |
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4606-4613 |
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Groundwater problems and environmental effects Pollution and waste management non radioactive remediation heavy metal mine drainage acid mine drainage; acidification; Central Europe; chemical composition; chemical fractionation; dissolved materials; Europe; framework silicates; geochemistry; grain size; heavy metals; hydrochemistry; ion exchange; lead; metals; mines; mining; mobilization; models; pH; pollutants; pollution; precipitation; remediation; samples; silicates; spectra; Switzerland; toxic materials; X-ray diffraction data; X-ray fluorescence spectra; zeolite group |
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G. Furrer, Institute of Terrestrial Ecology, Swiss Federal Institute of Technology, Zurich, Grabenstrasse 3, CH-8952 Schlieren, Switzerland gerhard.furrer@env.ethz.ch |
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0013-936x |
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Removal of heavy metals from mine waters by natural zeolites; 2006-086777; References: 42; illus. incl. 3 tables United States (USA); GeoRef; English |
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CBU @ c.wolke @ 5382 |
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71 |
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McLeod, K.W.; Ciravolo, T.G. |
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Sensitivity of water tupelo (Nyssa aquatica) and bald cypress (Taxodium distichum) seedlings to manganese enrichment under water-saturated conditions |
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Journal Article |
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2003 |
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Environmental Toxicology and Chemistry |
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22 |
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12 |
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2948-2951 |
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Heavy metals ecological abstracts: pollution (73 7 3) seedling saturated medium biomass manganese sensitivity analysis bioaccumulation Nyssa aquatica Taxodium distichum |
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In anaerobic soils of wetlands, Mn is highly available to plants because of the decreasing redox potential and pH of flooded soil. When growing adjacent to each another in wetland forests, water tupelo (Nyssa aquatica L.) had 10 times greater leaf manganese concentration than bald cypress (Taxodium distichum [L.] Richard). This interspecific difference was examined over a range of manganese-enriched soil conditions in a greenhouse experiment. Water tupelo and bald cypress seedlings were grown in fertilized potting soil enriched with 0, 40, 80, 160, 240, 320, and 400 mg Mn/L of soil and kept at saturated to slightly flooded conditions. Leaf Mn concentration was greater in water tupelo than bald cypress for all but the highest Mn addition treatment. Growth of water tupelo seedlings was adversely affected in treatments greater than 160 mg Mn/L. Total biomass of water tupelo in the highest Mn treatment was less than 50% of the control. At low levels of added Mn, bald cypress was able to restrict uptake of Mn at the roots with resulting low leaf Mn concentrations. Once that root restriction was exceeded, Mn concentration in bald cypress leaves increased greatly with treatment; that is, the highest treatment was 40 times greater than control (4,603 vs 100 < mu >g/g, respectively), but biomass of bald cypress was unaffected by manganese additions. Bald cypress, a tree that does not naturally accumulate manganese, does so under manganese-enriched conditions and without biomass reduction in contrast to water tupelo, which is severely affected by higher soil Mn concentrations. Thus, bald cypress would be less affected by increased manganese availability in swamps receiving acidic inputs such as acid mine drainage, acid rain, or oxidization of pyritic soils. |
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K.W. McLeod, Savannah River Ecology Laboratory, University of Georgia, P.O. Drawer E, Aiken, SC 29802, United States mcleod@srel.edu |
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0730-7268 |
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Sensitivity of water tupelo (Nyssa aquatica) and bald cypress (Taxodium distichum) seedlings to manganese enrichment under water-saturated conditions; 2574798; United-States 15; Geobase |
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CBU @ c.wolke @ 16010 |
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302 |
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Boonstra, J.; van Lier, R.; Janssen, G.; Dijkman, H.; Buisman, C.J.N. |
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Title |
Biological treatment of acid mine drainage |
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Book Chapter |
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1999 |
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Process Metallurgy, vol.9, Part B |
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559-567 |
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acid mine drainage adsorption alkaline earth metals arsenic Bingham Canyon Mine bioremediation Budelco Zinc Refinery cadmium copper Cornwall England England Europe Great Britain heavy metals iron magnesium manganese metals Netherlands pH phase equilibria pollution remediation sulfate ion United Kingdom United States Utah Western Europe Wheal Jane Mine zinc 22, Environmental geology |
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Amils, R.; Ballester, A. |
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Biohydrometallurgy and the environment toward the mining of the 21st century; proceedings of the International biohydrometallurgy symposium IBS'99, Part B, Molecular biology, biosorption, bioremediation |
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0444501932 |
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Biological treatment of acid mine drainage; GeoRef; English; 2000-049809; International biohydrometallurgy symposium IBS'99, Madrid, Spain, June 20-23, 1999 References: 11; illus. incl. 5 tables |
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CBU @ c.wolke @ 16595 |
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442 |
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Stewart, D.; Norman, T.; Cordery-Cotter, S.; Kleiner, R.; Sweeney, E.; Nelson, J.D. |
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Title |
Utilization of a ceramic membrane for acid mine drainage treatment |
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Journal Article |
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Year |
1997 |
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Tailings and Mine Waste '97 |
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453-460 |
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acid mine drainage; Black Hawk Colorado; Central City Colorado; ceramic materials; Colorado; cost; disposal barriers; geochemistry; Gilpin County Colorado; heavy metals; mines; organic compounds; pollution; remediation; surface water; tailings; United States; utilization; volatile organic compounds; volatiles; waste disposal mine water treatment |
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BASX Systems LLC has developed a treatment system based on ceramic membranes for the removal of heavy metals from an acid mine drainage stream. This stream also contained volatile organic compounds that were required to be removed prior to discharge to a Colorado mountain stream. The removal of heavy metals was greater than 99% in most cases. A decrease of 30% in chemicals required for treatment and a reduction by more than 75% in labor over a competing technology were achieved. These decreases were obtained for operating temperatures of less than 5 degrees C. This system of ceramic microfiltration is capable of treating many different types of acid mine waste streams for heavy metals removal. |
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90-5410-857-6 |
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Jan 13-17; Utilization of a ceramic membrane for acid mine drainage treatment; Isip:A1997bg96u00050; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 8744 |
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135 |
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