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Wingenfelder, U.; Hansen, C.; Furrer, G.; Schulin, R. |
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Title |
Removal of heavy metals from mine waters by natural zeolites |
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Journal Article |
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2005 |
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Environ Sci Technol, ES & T |
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39 |
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12 |
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4606-4613 |
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Groundwater problems and environmental effects Pollution and waste management non radioactive remediation heavy metal mine drainage acid mine drainage; acidification; Central Europe; chemical composition; chemical fractionation; dissolved materials; Europe; framework silicates; geochemistry; grain size; heavy metals; hydrochemistry; ion exchange; lead; metals; mines; mining; mobilization; models; pH; pollutants; pollution; precipitation; remediation; samples; silicates; spectra; Switzerland; toxic materials; X-ray diffraction data; X-ray fluorescence spectra; zeolite group |
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G. Furrer, Institute of Terrestrial Ecology, Swiss Federal Institute of Technology, Zurich, Grabenstrasse 3, CH-8952 Schlieren, Switzerland gerhard.furrer@env.ethz.ch |
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0013-936x |
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Removal of heavy metals from mine waters by natural zeolites; 2006-086777; References: 42; illus. incl. 3 tables United States (USA); GeoRef; English |
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CBU @ c.wolke @ 5382 |
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71 |
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Van Hille, R.P.; Boshoff, G.A.; Rose, P.D.; Duncan, J.R. |
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Title |
A continuous process for the biological treatment of heavy metal contaminated acid mine water |
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Journal Article |
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Year |
1999 |
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Resour. Conserv. Recycl. |
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27 |
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1-2 |
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157-167 |
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mine water treatment biological treatment heavy metal acid mine water alkaline precipitation green-algae chlorella |
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Alkaline precipitation of heavy metals from acidic water streams is a popular and long standing treatment process. While this process is efficient it requires the continuous addition of an alkaline material, such as lime. In the long term or when treating large volumes of effluent this process becomes expensive, with costs in the mining sector routinely exceeding millions of rands annually. The process described below utilises alkalinity generated by the alga Spirulina sp., in a continuous system to precipitate heavy metals. The design of the system separates the algal component from the metal containing stream to overcome metal toxicity. The primary treatment process consistently removed over 99% of the iron (98.9 mg/l) and between 80 and 95% of the zinc (7.16 mg/l) and lead (2.35 mg/l) over a 14-day period (20 l effluent treated). In addition the pH of the raw effluent was increased from 1.8 to over 7 in the post-treatment stream. Secondary treatment and polishing steps depend on the nature of the effluent treated. In the case of the high sulphate effluent the treated stream was passed into an anaerobic digester at a rate of 4 l/day. The combination of the primary and secondary treatments effected a removal of over 95% of all metals tested for as well as a 90% reduction in the sulphate load. The running cost of such a process would be low as the salinity and nutrient requirements for the algal culture could be provided by using tannery effluent or a combination of saline water and sewage. This would have the additional benefit of treating either a tannery or sewage effluent as part of an integrated process. |
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0921-3449 |
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Jul; A continuous process for the biological treatment of heavy metal contaminated acid mine water; Isi:000081142100017; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/9937.pdf; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 9937 |
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26 |
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Sottnik, P.; Sucha, V. |
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Moznosti upravy kysleho banskeho vytoku loziska Banska Stiavnica-Sobov. Remediation of acid mine drainage from Sobov Mine, Banska Stiavnica |
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Journal Article |
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2001 |
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Mineralia Slovaca |
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33 |
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1 |
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53-60 |
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acid mine drainage aluminum Banska Stiavnica Slovakia Central Europe copper Eh Europe gangue heavy metals iron manganese metals metamorphic rocks oxidation pH pollution precipitation pyrite quartzites reduction remediation Slovakia Sobov Mine sulfides vegetation waste disposal wetlands 22, Environmental geology |
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A waste dump formed during the exploitation of quartzite deposit in Sobov mine (Slovakia) produces large quantity of acid mine drainage (AMD) which is mainly a product of pyrite oxidation. Sulphuric acid--the most aggressive oxidation product--attacks gangue minerals, mainly clays, as well. This process lead to a sharp decrease of the pH values (2-2.5) and increase of Fe, Al and SO (super 2-) (sub 4) contents (TDS = 20-30 mg/1). Passive treatment system was designed to remediate AMD. Chemical redox reactions along with microbial activity cause a precipitation of mobile contamination into a more stable forms. The sulphides are formed in the anaerobic cell, under reducing conditions. Fe-, Al- oxyhydroxides are precipitated in the aerobic part of the system. Precipitation decreases the Fe and Al contents along with immobilization of some heavy metal closely related to oxyhydroxides. Besides oxidation, the wetland vegetation is an active part of on aerobic cell. The system has been working effectively since September 1999. The pH values of outflowing water are apparently higher (6.2-6.8) and contents of dissolved elements (Fe from 2.260 to 4.1; Al from 900 to 0.18; Mn from 51 to 23; Cu from 4.95 to 0.03 mg/l) is significantly lowers. |
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0369-2086 |
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Moznosti upravy kysleho banskeho vytoku loziska Banska Stiavnica-Sobov. Remediation of acid mine drainage from Sobov Mine, Banska Stiavnica; 2004-084366; References: 21; illus. incl. sects. Slovak Republic (SVK); GeoRef; Slovakian |
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CBU @ c.wolke @ 16534 |
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235 |
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Schwartz, M.O.; Ploethner, D. |
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From mine water to drinking water; heavy-metal removal by carbonate precipitation in the Grootfontein-Omatako Canal, Namibia |
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Book Chapter |
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1999 |
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Africa; aluminum; cadmium; canals; carbonates; copper; drinking water; geochemistry; Grootfontein-Omatako Canal; heavy metals; hydrochemistry; iron; lead; manganese; metallogenic provinces; metals; mine drainage; mineral deposits, genesis; mines; Namibia; policy; precipitation; purification; Southern Africa; transport; water management; water treatment 22, Environmental geology |
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Bundesanst. fuer Geowiss. und Rohstoffe |
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Hanover |
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From mine water to drinking water; heavy-metal removal by carbonate precipitation in the Grootfontein-Omatako Canal, Namibia; GeoRef; English; 2002-033925; International congress on Mine, water and environment, Seville, Spain, Sept. 13, 1999 References: 7; 2 tables, sketch maps |
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Call Number |
CBU @ c.wolke @ 5929 |
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250 |
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Author |
Rammlmair, D.; Grissemann, C. |
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Title |
Natural attenuation in slag heaps versus remediation |
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Book Chapter |
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2000 |
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Applied mineralogy in research, economy, technology, ecology and culture |
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645-648 |
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acid mine drainage; alteration; concentration; concepts; crust; deposition; design; development; diagenesis; exhalative processes; fines; fluvial features; ground water; leaching; metallurgy; mining; mining geology; mobilization; natural attenuation; physicochemical properties; Plantae; pollution; precipitation; remediation; rivers; slag; time scales; toxic materials; transportation; volatiles; wind transport 22, Environmental geology |
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Rammlmair, D.; Mederer, J.; Oberthuer, T.; Heimann, R.B.; Pentinghaus, H.J. |
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9058091643 |
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Natural attenuation in slag heaps versus remediation; GeoRef; English; 2007-039910; Sixth international congress on Applied mineralogy in research, economy, technology, ecology, and culture, Gottingen, Federal Republic of Germany, July 17-19, 2000 References: 5; illus. |
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CBU @ c.wolke @ 5864 |
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266 |
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