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Barton, C.D.; Karathanasis, A.D. |
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Title |
Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage |
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Book Chapter |
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Year |
1997 |
Publication |
AAPG Eastern Section and the Society for Organic Petrology joint meeting; abstracts |
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1545 |
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acid mine drainage aerobic environment air-water interface anaerobic environment attenuation buffers constructed wetlands controls diffusion iron manganese metals mineral composition pollution precipitation processes SEM data solubility solution sulfate ion sulfur wetlands X-ray diffraction data 22, Environmental geology |
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Abstract |
The use of constructed wetlands for acid mine drainage amelioration has become a popular alternative to conventional treatment methods, however, the metal attenuation processes of these systems are poorly understood. Precipitates from biotic and abiotic zones of a staged constructed wetland treating high metal load (approx. equal to 1000 mg L (super -1) ) and low pH (approx. 3.0) acid mine drainage were characterized by chemical dissolution, x-ray diffraction, thermal analysis and scanning electron microscopy. Characterization of abiotic/aerobic zones within the treatment system suggest the presence of crystalline iron oxides and hydroxides such as hematite, lepidocrocite, goethite, and jarosite. At the air/water interface of initial abiotic treatment zones, SO (sub 4) /Fe ratios were low enough (<2.0) for the formation of jarosite and goethite, but as the ratio increased due to treatment and subsequent reductions in iron concentration, jarosite was transformed to other Fe-oxyhydroxysulfates and goethite formation was inhibited. In addition, elevated pH conditions occurring in the later stages of treatment promoted the formation of amorphous iron oxyhydroxides. Biotic wetland cell substrate characterizations suggest the presence of amorphous iron minerals such as ferrihydrite and Fe(OH) (sub 3) . Apparently, high Fe (super 3+) activity, low Eh and low oxygen diffusion rates in the anaerobic subsurface environment inhibit the kinetics of crystalline iron precipitation. Some goethite, lepidocrocite and hematite, however, were observed near the surface in biotic areas and are most likely attributable to increased oxygen levels from surface aeration and/or oxygen transport by plant roots. Alkalinity generation from limestone dissolution within the substrate and bacterially mediated sulfate reduction also has a significant role on the mineral retention process. The formation of gypsum, rhodochrocite and siderite are by-products of alkalinity generating reactions in this system and may have an impact on S, Mn, and Fe solubility controls. Moreover, the buffering of acidity through excess alkalinity appears to facilitate the precipitation and retention of metals within the system. |
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AAPG Bulletin |
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81 |
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Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage; GeoRef; English; 1997-067790; AAPG Eastern Section and the Society for Organic Petrology joint meeting, Lexington, KY, United States, Sep. 27-30, 1997 |
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CBU @ c.wolke @ 16630 |
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70 |
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Author |
Schueck, J.H. |
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Title |
Limestone diversion wells; a low-maintenance, cost-effective method for treating acid-mine drainage with limestone |
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Book Chapter |
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Year |
1995 |
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Guidebook for the Annual Field Conference of Pennsylvania Geologists, vol.60 Applied geology in the Lock Haven and Williamsport region, Clinton and Lycoming counties, northcentral Pennsylvania |
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9-12 |
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Keywords |
acid mine drainage; Babb Creek watershed; Blossburg coal basin; carbonate rocks; ground water; hydrology; limestone; Pennsylvania; pollution; remediation; sedimentary rocks; Tioga County Pennsylvania; United States; water wells; watersheds; wells 22, Environmental geology |
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Carnein, C.R.; Way, J.H. |
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Limestone diversion wells; a low-maintenance, cost-effective method for treating acid-mine drainage with limestone; GeoRef; English; 1996-018760; 60th annual field conference of Pennsylvania geologists, Williamsport, PA, United States, Oct. 5-7, 1995 References: 3; 1 table, sketch map |
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CBU @ c.wolke @ 6420 |
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77 |
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Cravotta, C.A., III; Watzlaf, G.R.; Naftz, D.L.; Morrison, S.J.; Fuller, C.C.; Davis, J.A. |
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Design and performance of limestone drains to increase pH and remove metals from acidic mine drainage Handbook of groundwater remediation using permeable reactive barriers; applications to radionuclides, trace metals, and nutrients |
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Book Chapter |
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2002 |
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acid mine drainage; alkaline earth metals; aquatic environment; aquifers; calcium; carbonate rocks; chemical properties; construction; construction materials; crushed stone; dissolved materials; drainage; effluents; ground water; limestone; magnesium; metals; pH; pollution; porous materials; precipitation; retention; saturation; sedimentary rocks; sulfate ion; suspended materials 22, Environmental geology |
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Academic Press |
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Amsterdam |
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0125135637 |
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Design and performance of limestone drains to increase pH and remove metals from acidic mine drainage Handbook of groundwater remediation using permeable reactive barriers; applications to radionuclides, trace metals, and nutrients; GeoRef; English; 2004-040518; References: 66; illus. incl. 4 tables |
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CBU @ c.wolke @ 5686 |
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81 |
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Author |
Karathanasis, A.D.; Barton, C.D. |
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Title |
The revival of a failed constructed wetland treating a high Fe load AMD |
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Book Chapter |
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Year |
1999 |
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Proceedings; biogeochemistry of trace elements in coal and coal combustion byproducts |
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abandoned mines acid mine drainage anaerobic environment carbonate rocks characterization composting constructed wetlands design environmental analysis ferrihydrite geologic hazards hydrology hydroxides iron iron hydroxides Kentucky limestone metals minerals mines organic compounds oxides pollution remediation runoff sedimentary rocks sediments solubility sulfate ion United States water quality water treatment wetlands 22, Environmental geology |
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Kluwer Academic/Plenum Publishers |
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New York |
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Sajwan, K.S.; Alva, A.K.; Keefer, R.F. |
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0306462885 |
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The revival of a failed constructed wetland treating a high Fe load AMD; GeoRef; English; 2002-039561; Fourth international conference on the Biogeochemistry of trace elements, Berkeley, CA, United States, June 23, 1997 References: 45; illus. incl. 2 tables, sketch maps |
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CBU @ c.wolke @ 16571 |
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82 |
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Author |
Wolkersdorfer, C. |
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Title |
Mine water tracing |
Type |
Journal Article |
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Year |
2002 |
Publication |
Geological Society Special Publication |
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Volume |
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198 |
Pages |
47-60 |
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Groundwater problems and environmental effects Pollution and waste management non radioactive geomechanics abstracts: excavations (77 10 10) geological abstracts: environmental geology (72 14 2) flooding seepage abandoned mine tracer groundwater flow |
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Abstract |
This paper describes how tracer tests can be used in flooded underground mines to evaluate the hydrodynamic conditions or reliability of dams. Mine water tracer tests are conducted in order to evaluate the flow paths of seepage water, connections from the surface to the mine, and to support remediation plans for abandoned and flooded underground mines. There are only a few descriptions of successful tracer tests in the literature, and experience with mine water tracing is limited. Potential tracers are restricted due to the complicated chemical composition or low pH mine waters. A new injection and sampling method ('LydiA'-technique) overcomes some of the problems in mine water tracing. A successful tracer test from the Harz Mountains in Germany with Lycopodium clavatum, microspheres and sodium chloride is described, and the results of 29 mine water tracer tests indicate mean flow velocities of between 0.3 and 1.7 m min-1. |
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C. Wolkersdorfer, TU Bergakademie Freiberg, Lehrstuhl fur Hydrogeologie, Gustav-Zeuner-Strasse 12, Freiberg, Sachsen D-09599, Germany c.wolke@tu-freiberg.de |
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0305-8719 |
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Mine water tracing; 2463597; United-Kingdom 71; Geobase |
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CBU @ c.wolke @ 17528 |
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83 |
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