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Conca, J.L.; Wright, J. |
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Title |
An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd |
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Journal Article |
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Year |
2006 |
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Appl. Geochem. |
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21 |
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12 |
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2188-2200 |
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Pollution and waste management non radioactive Groundwater quality apatite groundwater remediation zinc lead cadmium acid mine drainage copper sulfate nitrate permeability water treatment precipitation chemistry |
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Abstract |
Phosphate-induced metal stabilization involving the reactive medium Apatite II(TM) [Ca10-xNax(PO4)6-x(CO3)x(OH)2], where x < 1, was used in a subsurface permeable reactive barrier (PRB) to treat acid mine drainage in a shallow alluvial groundwater containing elevated concentrations of Zn, Pb, Cd, Cu, SO4 and NO3. The groundwater is treated in situ before it enters the East Fork of Ninemile Creek, a tributary to the Coeur d'Alene River, Idaho. Microbially mediated SO4 reduction and the subsequent precipitation of sphalerite [ZnS] is the primary mechanism occurring for immobilization of Zn and Cd. Precipitation of pyromorphite [Pb10(PO4)6(OH,Cl)2] is the most likely mechanism for immobilization of Pb. Precipitation is occurring directly on the original Apatite II. The emplaced PRB has been operating successfully since January of 2001, and has reduced the concentrations of Cd and Pb to below detection (2 μg L-1), has reduced Zn to near background in this region (about 100 μg L-1), and has reduced SO4 by between 100 and 200 mg L-1 and NO3 to below detection (50 μg L-1). The PRB, filled with 90 tonnes of Apatite II, has removed about 4550 kg of Zn, 91 kg of Pb and 45 kg of Cd, but 90% of the immobilization is occurring in the first 20% of the barrier, wherein the reactive media now contain up to 25 wt% Zn. Field observations indicate that about 30% of the Apatite II material is spent (consumed). |
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0883-2927 |
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Dec.; An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd; Science Direct |
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CBU @ c.wolke @ 17248 |
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44 |
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Author |
Kuyucak, N. |
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Title |
Acid mine drainage; treatment options for mining effluents |
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Journal Article |
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Year |
2001 |
Publication |
Mining Environmental Management |
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9 |
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2 |
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12-15 |
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acid mine drainage; alkalinity; cadmium; chemical reactions; copper; cyanides; decontamination; degradation; effluents; flotation; heavy metals; lead; lime; metals; mines; nickel; oxidation; pH; physicochemical properties; pollution; reagents; reduction; remediation; seepage; sludge; solid waste; solvents; stability; tailings; toxic materials; toxicity; waste disposal; water quality; zinc |
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0969-4218 |
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Acid mine drainage; treatment options for mining effluents; 2001-050827; References: 23; illus. United Kingdom (GBR); GeoRef; English |
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CBU @ c.wolke @ 5723 |
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324 |
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Stoica, L.; Dima, G. |
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Pb(II) removal from aqueous systems by biosorption-flotation on mycelial residues of Penicillium chrysogenum |
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Book Chapter |
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2000 |
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7th international Mine Water Association congress; Mine water and the environment |
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472-481 |
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bioremediation; flotation; ground water; lead; metals; Penicillium; Penicillium chrysogenum; pollution; remediation; sorption; water treatment 22, Environmental geology |
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Uniwersytet Slaski |
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Sosnowiec |
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Rozkowski, A. |
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8387431230 |
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Pb(II) removal from aqueous systems by biosorption-flotation on mycelial residues of Penicillium chrysogenum; GeoRef; English; 2002-018169; 7th international Mine Water Association congress; Mine water and the environment, Katowice-Ustron, Poland, Sept. 11-15, 2000 References: 6; illus. incl. 4 tables |
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CBU @ c.wolke @ 5852 |
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228 |
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Schwartz, M.O.; Ploethner, D. |
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From mine water to drinking water; heavy-metal removal by carbonate precipitation in the Grootfontein-Omatako Canal, Namibia |
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1999 |
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Africa; aluminum; cadmium; canals; carbonates; copper; drinking water; geochemistry; Grootfontein-Omatako Canal; heavy metals; hydrochemistry; iron; lead; manganese; metallogenic provinces; metals; mine drainage; mineral deposits, genesis; mines; Namibia; policy; precipitation; purification; Southern Africa; transport; water management; water treatment 22, Environmental geology |
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Bundesanst. fuer Geowiss. und Rohstoffe |
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Hanover |
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From mine water to drinking water; heavy-metal removal by carbonate precipitation in the Grootfontein-Omatako Canal, Namibia; GeoRef; English; 2002-033925; International congress on Mine, water and environment, Seville, Spain, Sept. 13, 1999 References: 7; 2 tables, sketch maps |
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CBU @ c.wolke @ 5929 |
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250 |
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Nairn, R.W.; Griffin, B.C.; Strong, J.D.; Hatley, E.L. |
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Remediation challenges and opportunities at the Tar Creek Superfund Site, Oklahoma |
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Book Chapter |
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2001 |
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Proceedings of the Annual National Meeting – American Society for Surface Mining and Reclamation, vol.18 |
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579-584 |
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abandoned mines acid mine drainage collapse structures constructed wetlands environmental analysis geologic hazards ground water human ecology Kansas land subsidence lead metals mines Missouri Oklahoma pollution reclamation remediation springs Superfund sites surface water Tar Creek Superfund Site United States water resources wetlands zinc 22, Environmental geology |
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Abstract |
The Tar Creek Superfund Site is a portion of the abandoned lead and zinc mining area known as the Tri-State Mining District (OK, KS and MO) and includes over 100 square kilometers of disturbed land surface and contaminated water resources in extreme northeastern Oklahoma. Underground mining from the 1890s through the 1960s degraded over 1000 surface hectares, and left nearly 50 km of tunnels, 165 million tons of processed mine waste materials (chat), 300 hectares of tailings impoundments and over 2600 open shafts and boreholes. Approximately 94 million cubic meters of contaminated water currently exist in underground voids. In 1979, metal-rich waters began to discharge into surface waters from natural springs, bore holes and mine shafts. Six communities are located within the boundaries of the Superfund site. Approximately 70% of the site is Native American owned. Subsidence and surface collapse hazards are of significant concern. The Tar Creek site was listed on the National Priorities List (NPL) in 1983 and currently receives a Hazard Ranking System score of 58.15, making Tar Creek the nation's number one NPL site. A 1993 Indian Health Service study demonstrated that 35% of children had blood lead levels above thresholds dangerous to human health. Recent remediation efforts have focused on excavation and replacement of contaminated residential areas. In January 2000, Governor Frank Keating's Tar Creek Task Force was created to take a “vital leadership role in identifying solutions and resources available to address” the myriad environmental problems. The principle final recommendation was the creation of a massive wetland and wildlife refuge to ecologically address health, safety, environmental, and aesthetic concerns. Additional interim measures included continuing the Task Force and subcommittees; study of mine drainage discharge and chat quality; construction of pilot treatment wetlands; mine shaft plugging; investigations of bioaccumulation issues; establishment of an authority to market and export chat, a local steering committee, and a GIS committee; and development of effective federal, state, tribal, and local partnerships. |
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Vincent, R.; Burger, J.A.; Marino, G.G.; Olyphant, G.A.; Wessman, S.C.; Darmody, R.G.; Richmond, T.C.; Bengson, S.A.; Nawrot, J.R. |
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Remediation challenges and opportunities at the Tar Creek Superfund Site, Oklahoma; GeoRef; English; 2002-036287; 18th annual national meeting of the American Society for Surface Mining and Reclamation; Land reclamation, a different approach, Albuquerque, NM, United States, June 3-7, 2001 References: 20; illus. incl. 1 table |
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CBU @ c.wolke @ 16526 |
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290 |
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