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Blowes, D.W.; Ptacek, C.J.; Benner, S.G.; McRae, C.W.T.; Puls, R.W. |
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Title |
Treatment of dissolved metals using permeable reactive barriers |
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Journal Article |
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1998 |
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Groundwater Quality: Remediation and Protection |
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250 |
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483-490 |
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adsorption; aquifers; attenuation; dissolved materials; metals; nutrients; oxidation; pollutants; pollution; precipitation; reduction; water treatment Groundwater quality Pollution and waste management non radioactive Groundwater acid mine drainage aquifer pollution conference proceedings containment barrier metal tailings Canada Ontario Nickel Rim Mine United States North Carolina Elizabeth City mine water treatment |
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Permeable reactive barriers are a promising new approach to the treatment of dissolved contaminants in aquifers. This technology has progressed rapidly from laboratory studies to full-scale implementation over the past decade. Laboratory treatability studies indicate the potential for treatment of a large number of inorganic contaminants, including As, Cd, Cr, Cu, Hg, Fe, Mn, Mo, Ni, Pb, Se, Tc, U, V, NO3, PO4, and SO4. Small scale field studies have indicated the potential for treatment of Cd, Cr, Cu, Fe, Ni, Pb, NO3, PO4, and SO4. Permeable reactive barriers have been used in full-scale installations for the treatment of hexavalent chromium, dissolved constituents associated with acid-mine drainage, including SO4, Fe, Ni, Co and Zn, and dissolved nutrients, including nitrate and phosphate. A full-scale barrier designed to prevent the release of contaminants associated with inactive mine tailings impoundment was installed at the Nickel Rim mine site in Canada in August 1995. This reactive barrier removes Fe, SO,, Ni and other metals. The effluent from the barrier is neutral in pH and contains no acid-generating potential, and dissolved metal concentrations are below regulatory guidelines. A full-scale reactive barrier was installed to treat Cr(VI) and halogenated hydrocarbons at the US Coast Guard site in Elizabeth City, North Carolina, USA in June 1996. This barrier removes Cr(VI) from >8 mg l(-1) to <0.01 mg l(-1). |
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0144-7815 |
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Treatment of dissolved metals using permeable reactive barriers; Isip:000079718200072; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 8601 |
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178 |
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Groudev, S.N.; Georgiev, P.S.; Spasova, I.I.; Nicolova, M.N. |
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Title |
In situ treatment of mine waters by means of a permeable barrier |
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Journal Article |
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Year |
2000 |
Publication |
Groundwater 2000 |
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417-418 |
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mine water treatment |
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Acid ground waters contaminated with radioactive elements (U, Ra, Th), toxic heavy metals (Cu, Zn, Cd, Mn, Fe), arsenic and sulphates were treated by means of a permeable barrier. The barrier was filled with a mixture of biodegradable solid organic substrates (spent mushroom compost, sawdust and cow manure) and was inhabited by a mixed microbial community consisting of sulphate-reducing bacteria and other metabolically interdependent microorganisms. An efficient removal of the pollutants was achieved by this barrier during the different climatic seasons, even at ambient temperatures close to degrees C. The microbial dissimilatory sulphate reduction and the sorption of pollutants by the organic matter in the barrier were the main processes involved in this removal. |
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In situ treatment of mine waters by means of a permeable barrier; Isip:000088384300185; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 8407 |
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173 |
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Macklin, M.G. |
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A geomorphological approach to the management of rivers contaminated by metal mining |
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Journal Article |
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2006 |
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Geomorphology |
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79 |
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3-4 |
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423-447 |
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mine water treatment |
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As the result of current and historical metal mining, river channels and floodplains in many parts of the world have become contaminated by metal-rich waste in concentrations that may pose a hazard to human livelihoods and sustainable development. Environmental and human health impacts commonly arise because of the prolonged residence time of heavy metals in river sediments and alluvial soils and their bioaccumulatory nature in plants and animals. This paper considers how an understanding of the processes of sediment-associated metal dispersion in rivers, and the space and timescales over which they operate, can be used in a practical way to help river basin managers more effectively control and remediate catchments affected by current and historical metal mining. A geomorphological approach to the management of rivers contaminated by metals is outlined and four emerging research themes are highlighted and critically reviewed. These are: (1) response and recovery of river systems following the failures of major tailings dams; (2) effects of flooding on river contamination and the sustainable use of floodplains; (3) new developments in isotopic fingerprinting, remote sensing and numerical modelling for identifying the sources of contaminant metals and for mapping the spatial distribution of contaminants in river channels and floodplains; and (4) current approaches to the remediation of river basins affected by mining, appraised in light of the European Union's Water Framework Directive (2000/60/EC). Future opportunities for geomorphologically-based assessments of mining-affected catchments are also identified. (c) 2006 Elsevier B.V. All rights reserved. |
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A geomorphological approach to the management of rivers contaminated by metal mining; Wos:000241084500014; Times Cited: 1; ISI Web of Science |
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Call Number |
CBU @ c.wolke @ 16934 |
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105 |
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Bearcock, J.M. |
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Title |
Accelerated precipitation of ochre for mine water remediation |
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Journal Article |
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2006 |
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Geochim. Cosmochim. Acta |
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70 |
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18 |
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A42-A42 |
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mine water treatment |
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Accelerated precipitation of ochre for mine water remediation; Wos:000241374200094; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 16919 |
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104 |
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Author |
Benner, S.G. |
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Title |
Geochemistry of a permeable reactive barrier for metals and acid mine drainage |
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Journal Article |
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Year |
1999 |
Publication |
Environmental Science & Technology |
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33 |
Issue |
16 |
Pages |
2793-2799 |
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Keywords |
mine water treatment |
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A permeable reactive barrier, designed to remove metals and generate alkalinity by promoting sulfate reduction and metal sulfide precipitation, was installed in August 1995 into an aquifer containing effluent from mine tailings. Passage of groundwater through the barrier results in striking improvement in water quality. Dramatic changes in concentrations of SO4 (decrease of 2000-3000 mg/L), Fe (decrease of 270-1300 mg/L), trace metals (e.g., Ni decreases 30 mg/L), and alkalinity (increase of (800-2700 mg/L) are observed. Populations of sulfate reducing bacteria are 10 000 times greater, and bacterial activity, as measured by dehydrogenase activity, is 10 rimes higher within the barrier compared to the up-gradient aquifer. Dissolved sulfide concentrations increase by 0.2-120 mg/ L, and the isotope S-34 is enriched relative to S-32 in the dissolved phase SO42- within the barrier. Water chemistry, coupled with geochemical speciation modeling, indicates the pore water in the barrier becomes supersaturated with respect to amorphous Fe sulfide. Solid phase analysis of the reactive mixture indicates the accumulation of Fe monosulfide precipitates. Shifts in the saturation states of carbonate, sulfate, and sulfide minerals and most of the observed changes in water chemistry in the barrier and down-gradient aquifer can be attributed, either directly or indirectly, to bacterially mediated sulfate reduction. |
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Geochemistry of a permeable reactive barrier for metals and acid mine drainage; Wos:000082074500017; Times Cited: 57; ISI Web of Science |
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CBU @ c.wolke @ 17115 |
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132 |
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