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Coulton, R.; Bullen, C.; Hallett, C. |
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Title |
The design and optimisation of active mine water treatment plants |
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Journal Article |
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Year |
2003 |
Publication |
Land Contam. Reclam. |
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11 |
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2 |
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273-280 |
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sludge mine water treatment mine water active treatment precipitation iron manganese high density sludge sulphide Groundwater problems and environmental effects Pollution and waste management non radioactive manganese sulfide pollutant removal iron water treatment mine drainage |
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Abstract |
This paper provides a 'state of the art' overview of active mine water treatment. The paper discusses the process and reagent selection options commonly available to the designer of an active mine water treatment plant. Comparisons are made between each of these options, based on technical and financial criteria. The various different treatment technologies available are reviewed and comparisons made between conventional precipitation (using hydroxides, sulphides and carbonates), high density sludge processes and super-saturation precipitation. The selection of reagents (quick lime, slaked lime, sodium hydroxide, sodium carbonate, magnesium hydroxide, and proprietary chemicals) is considered and a comparison made on the basis of reagent cost, ease of use, final effluent quality and sludge settling criteria. The choice of oxidising agent (air, pure oxygen, peroxide, etc.) for conversion of ferrous to ferric iron is also considered. Whole life costs comparisons (capital, operational and decommissioning) are made between conventional hydroxide precipitation and the high density sludge process, based on the actual treatment requirements for four different mine waters. |
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R. Coulton, Unipure Europe Ltd., Wonastow Road, Monmouth NP25 5JA, United Kingdom |
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0967-0513 |
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The design and optimisation of active mine water treatment plants; 2530436; United-Kingdom 4; Geobase |
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CBU @ c.wolke @ 17513 |
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59 |
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Author |
Rukin, N. |
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Title |
Whittle mine water treatment system: In-river attenuation of manganese |
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Journal Article |
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Year |
2003 |
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Land Contam. Reclam. |
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11 |
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2 |
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137-144 |
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Pollution and waste management non radioactive Groundwater problems and environmental effects geological abstracts: environmental geology (72 14 2) geomechanics abstracts: excavations (77 10 10) river water natural attenuation manganese water treatment mine drainage coal mine |
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Much work has been undertaken on the design of treatment systems to remove iron from ochreous mine water discharges. Unlike iron, manganese removal is far more difficult and generally requires active chemical dosing rather than passive treatment. The need for manganese removal can therefore significantly change the economics, management attention and sustainability of a site. Understanding natural attenuation of manganese in river systems is therefore key to deciding whether (active) manganese treatment is needed to protect downstream receptors. Nuttall (2002, this volume) describes the effectiveness of the passive treatment system at Whittle in reducing both iron and manganese concentrations in ochreous mine waters. This paper discusses the results of in-river monitoring and provides evidence for manganese removal downstream of the discharge point. In addition to dilution, attenuation appears to be in the order of 20 to 50%, depending on relative rates of mine water discharge and river flows. Such attenuation means that active treatment may not be needed for the long-term operation of the Whittle scheme. Operation of the scheme commenced in July 2002, with monitoring to further examine evidence for manganese attenuation and any impact on the ecology of the recipient watercourses. |
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N. Rukin, Entec UK Ltd., 160-162 Abbey Foregate, Shrewsbury SY2 6BZ, United Kingdom |
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0967-0513 |
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Whittle mine water treatment system: In-river attenuation of manganese; 2530418; United-Kingdom 2; Geobase |
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CBU @ c.wolke @ 17521 |
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257 |
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Cravotta, C.A., III; Trahan, M.K. |
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Title |
Limestone drains to increase pH and remove dissolved metals from acidic mine drainage |
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1999 |
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Appl. Geochem. |
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14 |
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5 |
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581-606 |
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manganese oxide redox processes sulfate waters iron-oxides adsorption ions oxidation surfaces environments aluminum |
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Despite encrustation by Fe and Al hydroxides, limestone can be effective for remediation of acidic mine drainage (AMD). Samples of water and limestone (CaCO3) were collected periodically for 1 a at 3 identical limestone-filled drains in Pennsylvania to evaluate the attenuation of dissolved metals and the effects of pH and Fe- and Al-hydrolysis products on the rate of CaCO3 dissolution. The influent was acidic and relatively dilute (pH < 4; acidity < 90 mg) but contained 1-4 mg . L-1 of O-2, Fe3+, Al3+ and Mn2+. The total retention time in the oxic limestone drains (OLDs) ranged from 1.0 to 3.1 hr. Effluent remained oxic (O-2 > 1 mg . L-1) but was near neutral (pH = 6.2-7.0); Fe and Al decreased to less than 5% of influent concentrations. As pH increased near the inflow, hydrous Fe and Al oxides precipitated in the OLDs, The hydrous oxides, nominally Fe(OH)(3) and Al(OH)(3), were visible as loosely bound, orange-yellow coatings on limestone near the inflow. As time elapsed, Fe(OH)(3) and Al(OH)(3) particles were transported downflow. The accumulation of hydrous oxides and elevated pH (> 5) in the downflow part of the OLDs promoted sorption and coprecipitation of dissolved Mn, Cu, Co, Ni and Zn as indicated by decreased concentrations of the metals in effluent and their enrichment relative to Fe in hydrous-oxide particles and coatings on limestone. Despite thick (similar to 1 mm) hydrous-oxide coatings on limestone near the inflow, CaCO3 dissolution was more rapid near the inflow than at downflow points within and the OLD where the limestone was not coated. The high rates of CaCO3 dissolution and Fe(OH3) precipitation were associated with the relatively low pH and high Fe3+ concentration near the inflow. The rate of CaCO3 dissolution decreased with increased pH and concentrations of Ca2+ and HCO3- and decreased Pco(2). Because overall efficiency is increased by combining neutralization and hydrolysis reactions, an OLD followed by a settling pond requires less land area than needed for a two-stagetreatment system consisting of an anoxic limestone drain and oxidation-settling pond or wetland. To facilitate removal of hydrous-oxide sludge, a perforated-pipe subdrain can be installed within an OLD. (C) 1999 Elsevier Science Ltd. |
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0883-2927 |
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Jul; Limestone drains to increase pH and remove dissolved metals from acidic mine drainage; Isi:000080043300004; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10102.pdf; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 17470 |
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22 |
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Bernoth, L.; Firth, I.; McAllister, P.; Rhodes, S. |
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Title |
Biotechnologies for Remediation and Pollution Control in the Mining Industry |
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Journal Article |
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2000 |
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Miner. Metall. Process. |
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17 |
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2 |
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105-111 |
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bioremediation pollution control soil contamination solvents oils diesel hydrocarbons cyanide acid rock drainage microbial mats manganese bioremediation oxidation drainage removal water algae |
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As biotechnologies emerge from laboratories into main-stream application, the benefits they, offer are judged against competing technologies and business criteria. Bioremediation technologies have passed this test and are now widely used for the remediation of contaminated soils and ground waters. Bioremediation includes several distinct techniques that are used for the treatment of excavated soil and includes other techniques that are used for in situ applications. They play an important and growingrole in the mining industry for cost-effective waste management and site remediation. Most applications have been for petroleum contaminants, but advances continue to be made in the treatment of more difficult organ ic and inorganic species. This paper discusses the role of biotechnologies in remediation and pollution control from a mining-industry perspective. Several case studies are presented, including the land application of oily wastewater from maintenance workshops, the composting of hydrocarbon-contaminated soils and sludges, the bioventing of hydrocarbon solvents, the intrinsic bioremediation of diesel hydrocarbons, the biotreatment of cyanide in water front a gold mine, and the removal of manganese from acidic mine drainage. |
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0747-9182 |
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Biotechnologies for Remediation and Pollution Control in the Mining Industry; Isi:000087094600005; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 17307 |
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450 |
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McLeod, K.W.; Ciravolo, T.G. |
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Sensitivity of water tupelo (Nyssa aquatica) and bald cypress (Taxodium distichum) seedlings to manganese enrichment under water-saturated conditions |
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2003 |
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Environmental Toxicology and Chemistry |
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22 |
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12 |
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2948-2951 |
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Heavy metals ecological abstracts: pollution (73 7 3) seedling saturated medium biomass manganese sensitivity analysis bioaccumulation Nyssa aquatica Taxodium distichum |
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In anaerobic soils of wetlands, Mn is highly available to plants because of the decreasing redox potential and pH of flooded soil. When growing adjacent to each another in wetland forests, water tupelo (Nyssa aquatica L.) had 10 times greater leaf manganese concentration than bald cypress (Taxodium distichum [L.] Richard). This interspecific difference was examined over a range of manganese-enriched soil conditions in a greenhouse experiment. Water tupelo and bald cypress seedlings were grown in fertilized potting soil enriched with 0, 40, 80, 160, 240, 320, and 400 mg Mn/L of soil and kept at saturated to slightly flooded conditions. Leaf Mn concentration was greater in water tupelo than bald cypress for all but the highest Mn addition treatment. Growth of water tupelo seedlings was adversely affected in treatments greater than 160 mg Mn/L. Total biomass of water tupelo in the highest Mn treatment was less than 50% of the control. At low levels of added Mn, bald cypress was able to restrict uptake of Mn at the roots with resulting low leaf Mn concentrations. Once that root restriction was exceeded, Mn concentration in bald cypress leaves increased greatly with treatment; that is, the highest treatment was 40 times greater than control (4,603 vs 100 < mu >g/g, respectively), but biomass of bald cypress was unaffected by manganese additions. Bald cypress, a tree that does not naturally accumulate manganese, does so under manganese-enriched conditions and without biomass reduction in contrast to water tupelo, which is severely affected by higher soil Mn concentrations. Thus, bald cypress would be less affected by increased manganese availability in swamps receiving acidic inputs such as acid mine drainage, acid rain, or oxidization of pyritic soils. |
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K.W. McLeod, Savannah River Ecology Laboratory, University of Georgia, P.O. Drawer E, Aiken, SC 29802, United States mcleod@srel.edu |
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0730-7268 |
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Sensitivity of water tupelo (Nyssa aquatica) and bald cypress (Taxodium distichum) seedlings to manganese enrichment under water-saturated conditions; 2574798; United-States 15; Geobase |
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CBU @ c.wolke @ 16010 |
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302 |
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