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Conca, J.L.; Wright, J. |
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Title |
An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd |
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Journal Article |
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Year |
2006 |
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Appl. Geochem. |
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21 |
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12 |
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2188-2200 |
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Pollution and waste management non radioactive Groundwater quality apatite groundwater remediation zinc lead cadmium acid mine drainage copper sulfate nitrate permeability water treatment precipitation chemistry |
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Abstract |
Phosphate-induced metal stabilization involving the reactive medium Apatite II(TM) [Ca10-xNax(PO4)6-x(CO3)x(OH)2], where x < 1, was used in a subsurface permeable reactive barrier (PRB) to treat acid mine drainage in a shallow alluvial groundwater containing elevated concentrations of Zn, Pb, Cd, Cu, SO4 and NO3. The groundwater is treated in situ before it enters the East Fork of Ninemile Creek, a tributary to the Coeur d'Alene River, Idaho. Microbially mediated SO4 reduction and the subsequent precipitation of sphalerite [ZnS] is the primary mechanism occurring for immobilization of Zn and Cd. Precipitation of pyromorphite [Pb10(PO4)6(OH,Cl)2] is the most likely mechanism for immobilization of Pb. Precipitation is occurring directly on the original Apatite II. The emplaced PRB has been operating successfully since January of 2001, and has reduced the concentrations of Cd and Pb to below detection (2 μg L-1), has reduced Zn to near background in this region (about 100 μg L-1), and has reduced SO4 by between 100 and 200 mg L-1 and NO3 to below detection (50 μg L-1). The PRB, filled with 90 tonnes of Apatite II, has removed about 4550 kg of Zn, 91 kg of Pb and 45 kg of Cd, but 90% of the immobilization is occurring in the first 20% of the barrier, wherein the reactive media now contain up to 25 wt% Zn. Field observations indicate that about 30% of the Apatite II material is spent (consumed). |
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0883-2927 |
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Dec.; An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd; Science Direct |
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CBU @ c.wolke @ 17248 |
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44 |
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Laine, D.M. |
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1999 |
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581-584 |
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hydrogeology mining water treatment quality hydroxide flow pumping hydrochemistry sedimentation wetland |
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International Mine Water Association |
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Ii |
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Fernández Rubio, R. |
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Mine, Water & Environment |
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Remediation of the Old Meadows Gravity Minewater Discharge; 1; AMD ISI | Wolkersdorfer; FG 'de' 5 Abb., 1 Tab. |
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CBU @ c.wolke @ 9757 |
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320 |
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Kleinmann, R.; Majumdar, S.K.; Miller, E.W.; Brenner, F.J. |
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1998 |
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497-509 |
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abandoned mines; acid mine drainage; coal mines; constructed wetlands; drainage; environmental effects; mines; mitigation; pollutants; pollution; remediation; surface water; toxic materials; water quality; water treatment; wetlands 22, Environmental geology |
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The Pennsylvania Academy of Science Book Publications |
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25 |
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Ecology of wetlands and associated systems |
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Constructing wetlands for passive treatment of coal mine drainage; 2002-024212; GeoRef; English; References: 27; illus. incl. 2 tables United States (USA) |
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CBU @ c.wolke @ 6210 |
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330 |
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Blowes, D.W.; Ptacek, C.J.; Benner, S.G.; McRae, C.W.T.; Puls, R.W. |
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Title |
Treatment of dissolved metals using permeable reactive barriers |
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Journal Article |
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1998 |
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Groundwater Quality: Remediation and Protection |
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250 |
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483-490 |
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adsorption; aquifers; attenuation; dissolved materials; metals; nutrients; oxidation; pollutants; pollution; precipitation; reduction; water treatment Groundwater quality Pollution and waste management non radioactive Groundwater acid mine drainage aquifer pollution conference proceedings containment barrier metal tailings Canada Ontario Nickel Rim Mine United States North Carolina Elizabeth City mine water treatment |
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Permeable reactive barriers are a promising new approach to the treatment of dissolved contaminants in aquifers. This technology has progressed rapidly from laboratory studies to full-scale implementation over the past decade. Laboratory treatability studies indicate the potential for treatment of a large number of inorganic contaminants, including As, Cd, Cr, Cu, Hg, Fe, Mn, Mo, Ni, Pb, Se, Tc, U, V, NO3, PO4, and SO4. Small scale field studies have indicated the potential for treatment of Cd, Cr, Cu, Fe, Ni, Pb, NO3, PO4, and SO4. Permeable reactive barriers have been used in full-scale installations for the treatment of hexavalent chromium, dissolved constituents associated with acid-mine drainage, including SO4, Fe, Ni, Co and Zn, and dissolved nutrients, including nitrate and phosphate. A full-scale barrier designed to prevent the release of contaminants associated with inactive mine tailings impoundment was installed at the Nickel Rim mine site in Canada in August 1995. This reactive barrier removes Fe, SO,, Ni and other metals. The effluent from the barrier is neutral in pH and contains no acid-generating potential, and dissolved metal concentrations are below regulatory guidelines. A full-scale reactive barrier was installed to treat Cr(VI) and halogenated hydrocarbons at the US Coast Guard site in Elizabeth City, North Carolina, USA in June 1996. This barrier removes Cr(VI) from >8 mg l(-1) to <0.01 mg l(-1). |
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0144-7815 |
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Treatment of dissolved metals using permeable reactive barriers; Isip:000079718200072; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 8601 |
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178 |
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Younger, P.L.; Neal, C.; House, W.A.; Leeks, G.J.L.; Marker, A.H. |
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The longevity of minewater pollution; a basis for decision-making U.K. fluxes to the North Sea; Land Ocean Interaction Study (LOIS); river basins research, the first two years |
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Journal Article |
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Year |
1997 |
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The Science of the Total Environment |
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194-195 |
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457-466 |
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acid mine drainage; acidic composition; acidification; Cornwall England; decision-making; degradation; discharge; England; Europe; Great Britain; hydrolysis; mines; planning; pollutants; pollution; remediation; retention; Scotland; soils; surface water; United Kingdom; Wales; waste disposal; water quality; Western Europe 22, Environmental geology |
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0048-9697 |
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The longevity of minewater pollution; a basis for decision-making U.K. fluxes to the North Sea; Land Ocean Interaction Study (LOIS); river basins research, the first two years; 1997-078352; Special issue References: 30; illus. Netherlands (NLD); GeoRef; English |
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CBU @ c.wolke @ 6259 |
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193 |
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