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Wingenfelder, U.; Hansen, C.; Furrer, G.; Schulin, R. |
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Title |
Removal of heavy metals from mine waters by natural zeolites |
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Journal Article |
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2005 |
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Environ Sci Technol, ES & T |
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39 |
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12 |
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4606-4613 |
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Groundwater problems and environmental effects Pollution and waste management non radioactive remediation heavy metal mine drainage acid mine drainage; acidification; Central Europe; chemical composition; chemical fractionation; dissolved materials; Europe; framework silicates; geochemistry; grain size; heavy metals; hydrochemistry; ion exchange; lead; metals; mines; mining; mobilization; models; pH; pollutants; pollution; precipitation; remediation; samples; silicates; spectra; Switzerland; toxic materials; X-ray diffraction data; X-ray fluorescence spectra; zeolite group |
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G. Furrer, Institute of Terrestrial Ecology, Swiss Federal Institute of Technology, Zurich, Grabenstrasse 3, CH-8952 Schlieren, Switzerland gerhard.furrer@env.ethz.ch |
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0013-936x |
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Removal of heavy metals from mine waters by natural zeolites; 2006-086777; References: 42; illus. incl. 3 tables United States (USA); GeoRef; English |
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CBU @ c.wolke @ 5382 |
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71 |
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Author |
Ye, Z.H.; Whiting, S.N.; Qian, J.H.; Lytle, C.M.; Lin, Z.Q.; Terry, N. |
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Title |
Trace element removal from coal ash leachate by a 10-year-old constructed wetland |
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Journal Article |
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Year |
2001 |
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J. Environ. Qual. |
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30 |
Issue |
5 |
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1710-1719 |
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acid mine drainage; Alabama; ash; bioaccumulation; boron; cadmium; constructed wetlands; environmental analysis; environmental effects; iron; Jackson County Alabama; Juncus effusus; leachate; manganese; metals; pH; pollutants; pollution; remediation; soils; sulfur; trace elements; Typha latifolia; United States; vegetation; waste water; wetlands; Widows Creek; Widows Creek Steam Plant; zinc; Typha; Juncus 22, Environmental geology |
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This study investigated the ability of a 10-yr-old constructed wetland to treat metal-contaminated leachate emanating from a coal ash pile at the Widows Creek electric utility, Alabama (USA). The two vegetated cells, which were dominated by cattail (Typha latifolia L.) and soft rush (Juncus effusus L.), were very effective at removing Fe and Cd from the wastewater, but less efficient for Zn, S, B, and Mn. The concentrations were decreased by up to 99% for Fe, 91% for Cd, 63% for Zn, 61% for S, 58% for Mn, and 50% for B. Higher pH levels (>6) in standing water substantially improved the removing efficiency of the wetland for Mn only. The belowground tissues of both cattail and soft rush had high concentrations of all elements; only for Mn, however, did the concentration in the shoots exceed those in the belowground tissues. The concentrations of trace elements in fallen litter were higher than in the living shoots, but lower than in the belowground tissues. ne trace element accumulation in the plants accounted for less than 2.5% of the annual loading of each trace element into the wetland. The sediments were the primary sinks for the elements removed from the wastewater. Except for Mn, the concentrations of trace elements in the upper layer (0-5 cm) of the sediment profile tended to be higher than the lower layers (5-10 and 10-15 cm). We conclude that constructed wetlands are still able to efficiently remove metals in the long term (i.e., >10 yr after construction). |
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0047-2425 |
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Aug 1; Trace element removal from coal ash leachate by a 10-year-old constructed wetland; 2002-017274; References: 33; illus. incl. 2 tables United States (USA); file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/5703.pdf; GeoRef; English |
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CBU @ c.wolke @ 5703 |
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76 |
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Aytas, S.O.; Akyil, S.; Aslani, M.A.A.; Aytekin, U. |
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Removal of uranium from aqueous solutions by diatomite (Kieselguhr) |
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Journal Article |
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1999 |
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Journal of Radioanalytical and Nuclear Chemistry |
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240 |
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3 |
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973-976 |
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acid mine drainage; actinides; adsorption; aqueous solutions; clastic rocks; concentration; decontamination; diatomite; experimental studies; isotherms; laboratory studies; metals; pH; physicochemical properties; pollution; remediation; sedimentary rocks; solutes; sorption; techniques; uranium; uranyl ion; waste disposal; waste water 22, Environmental geology |
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0236-5731 |
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Removal of uranium from aqueous solutions by diatomite (Kieselguhr); 2000-058980; References: 18; illus. incl. 3 tables International (III); GeoRef; English |
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CBU @ c.wolke @ 5964 |
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471 |
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Fischer, R.; Luckner, L.; Peukert, D.; Reißig, H.; Roßbach, B. |
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Einsatz alkalischer Substanzen zur Verbesserung der Wasserqualität in Bergbaukippen. Use of alcine substances for the improvement of water quality in mining areas |
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Journal Article |
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2002 |
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Das Gas und Wasserfach. Ausgabe Wasser, Abwasser |
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143 |
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12 |
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891-898 |
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Abraum Braunkohlenbergbau Pyrit Eisensulfid Sulfidmineral Verwitterung Gewässerschutz Schadstoffbelastung Schwermetalle Sulfat pH-Wert Abwasserbehandlung Enteisenung alkalischer-Abbau chemischer-Abbau Alkalisierung Zusatzstoff Kalk Dolomit Flugasche Umweltbelastung Grundwasser Gewässergüte Eisendisulfitverwitterung Pyritverwitterung Bergbauabwasser Bergbauwasser Sulfatbelastung Undergrundwasserbehandlung alkalischer Stoff alkalische Substanz |
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Eisendisulfidminerale im Abraum von Braunkohlentagebauen können nach ihrer Verwitterung im wiederaufsteigenden Grundwasser erhebliche Güteverschlechterungen hinsichtlich pH-Wert, Schwermetall- und Sulfatgehalt verursachen. Diesen kann durch Zusätze alkalischer Substanzen zum Abraum wie Kalkstein, Dolomit und Kraftwerksasche bzw. Gemischen dieser Stoffe entgegengewirkt werden. Die Ergebnisse entsprechender Untersuchungen sowie die naturwissenschaftlichen Grundlagen der Eisendisulfidverwitterung werden im Beitrag dargestellt und ein Anwendungsbeispiel beschrieben. Grundlagen zur Berechnung der einzusetzenden Kalk- oder Aschemengen (bzw. Gemische der beiden Substanzen) sind die Bestimmung der oxidierbaren Sulfidminerale in den einzelnen geologischen Schichten sowie die Bestimmung der Pufferkapazität der Asche bzw. des Kalksteins. Besonders Vorteilhaft ist der Einsatz alkalischer Substanzen dort, wo durch vorhandene hohe Pyrit- und Markasitkonzentrationen mit einer erheblichen Versauerung des Grundwassers gerechnet und dadurch eine potentielle Beeinträchtigung von Grundwassernutzern erwartet werden muss. Solche Bedingungen sind im Rheinischen Braunkohlerevier, insbesondere im Umfeld des Tagebaus Garzweiler II (RWE Rheinbraun AG) gegeben. Derzeit werden im Tagebau Garzweiler bereits 40000 t Kalkstein dem Abraum beigemischt. Auch für das Lausitzer Braunkohlenrevier könnte ein Einsatz alkalischer Substanzen in Betracht gezogen werden. |
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TU Dresden, DE; Sächsisches Oberbergamt, Dresden, DE; RWE Rheinbraun, Köln, DE; Ingenieurbüro für Wassergütefragen, Dresden, DE; Bundesanstalt für Wasserbau (BAW), Karlsruhe, DE |
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0016-3651 |
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Einsatz alkalischer Substanzen zur Verbesserung der Wasserqualität in Bergbaukippen. Use of alcine substances for the improvement of water quality in mining areas; 27888, BERG , 03.03.03; Words: 569; 200301 05520; 8 Seiten, 3 Bilder, 34 Quellen 3UXX *Belastung von Wasser, Wasserreinhaltung, Abwasser* 3MZ *Bergbau, Tunnelbau, Erdöl /Erdgasförderung, Bohrtechnik* 3BX *chemische Grundlagen* 3PH *Trennen fest/flüssig/gasförm. Stoffe, dispers. Stoffsysteme*; BERG, Copyright FIZ Technik e.V.; DE Deutsch |
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CBU @ c.wolke @ 17587 |
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379 |
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Author |
Lin, C.; Lu, W.; Wu, Y. |
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Agricultural soils irrigated with acidic mine water: Acidity, heavy metals, and crop contamination |
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Journal Article |
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2005 |
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Australian Journal of Soil Research |
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43 |
Issue |
7 |
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819-826 |
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Contamination and remediation Irrigated agriculture Soil studies geographical abstracts: physical geography soils (71 5 14) international development abstracts: agriculture and rural development (74 1 8) ecological abstracts: terrestrial ecology (73 4 2) bioaccumulation irrigation agricultural soil acid mine drainage pH crop plant heavy metal China Far East Asia Eurasia |
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Agricultural soils irrigated with acidic mine water from the Guangdong Dabaoshan Mine, China, were investigated. The pH of the soils could be as low as 3.9. However, most of the mineral acids introduced into the soils by irrigation were transformed to insoluble forms through acid buffering processes and thus temporarily stored in the soils. Different heavy metals exhibited different fraction distribution patterns, with Zn and Cu being mainly associated with organic matter and Pb being primarily bound to oxides (statistically significant at P = 0.05). Although the mean of exchangeable Cd was greatest among the Cd fractions, there was no statistically significant difference between the exchangeable Cd and the oxide-bound Cd (the 2nd greatest fraction) or between the exchangeable Cd and the carbonate-bound Cd (the 3rd greatest fraction). It was also found that there were generally good relationships between the concentrations of various Zn, Cu, Pb, and Cd fractions and pH, suggesting that a major proportion of each heavy metal in the soils was mainly derived from the acidic irrigation water. The results also show that the crops grown in these soils were highly contaminated by heavy metals, particularly Cd. The concentration of Cd in the edible portions of most crops was far in excess of the limits set in China National Standards for Vegetables and Fruits and this can be attributable to the extremely high transfer rate of Cd from the soils to the crops under the cropping system adopted in the study area. < copyright > CSIRO 2005. |
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C. Lin, College of Resources and Environment, South China Agricultural University, Guangzhou 510642, China cxlin@scau.edu.cn |
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0004-9573 |
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Agricultural soils irrigated with acidic mine water: Acidity, heavy metals, and crop contamination; 2828050; Australia 29; Geobase |
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CBU @ c.wolke @ 17496 |
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314 |
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