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Cravotta, C.A., III; Trahan, M.K. |
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Title |
Limestone drains to increase pH and remove dissolved metals from acidic mine drainage |
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Journal Article |
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1999 |
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Appl. Geochem. |
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14 |
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5 |
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581-606 |
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manganese oxide redox processes sulfate waters iron-oxides adsorption ions oxidation surfaces environments aluminum |
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Abstract |
Despite encrustation by Fe and Al hydroxides, limestone can be effective for remediation of acidic mine drainage (AMD). Samples of water and limestone (CaCO3) were collected periodically for 1 a at 3 identical limestone-filled drains in Pennsylvania to evaluate the attenuation of dissolved metals and the effects of pH and Fe- and Al-hydrolysis products on the rate of CaCO3 dissolution. The influent was acidic and relatively dilute (pH < 4; acidity < 90 mg) but contained 1-4 mg . L-1 of O-2, Fe3+, Al3+ and Mn2+. The total retention time in the oxic limestone drains (OLDs) ranged from 1.0 to 3.1 hr. Effluent remained oxic (O-2 > 1 mg . L-1) but was near neutral (pH = 6.2-7.0); Fe and Al decreased to less than 5% of influent concentrations. As pH increased near the inflow, hydrous Fe and Al oxides precipitated in the OLDs, The hydrous oxides, nominally Fe(OH)(3) and Al(OH)(3), were visible as loosely bound, orange-yellow coatings on limestone near the inflow. As time elapsed, Fe(OH)(3) and Al(OH)(3) particles were transported downflow. The accumulation of hydrous oxides and elevated pH (> 5) in the downflow part of the OLDs promoted sorption and coprecipitation of dissolved Mn, Cu, Co, Ni and Zn as indicated by decreased concentrations of the metals in effluent and their enrichment relative to Fe in hydrous-oxide particles and coatings on limestone. Despite thick (similar to 1 mm) hydrous-oxide coatings on limestone near the inflow, CaCO3 dissolution was more rapid near the inflow than at downflow points within and the OLD where the limestone was not coated. The high rates of CaCO3 dissolution and Fe(OH3) precipitation were associated with the relatively low pH and high Fe3+ concentration near the inflow. The rate of CaCO3 dissolution decreased with increased pH and concentrations of Ca2+ and HCO3- and decreased Pco(2). Because overall efficiency is increased by combining neutralization and hydrolysis reactions, an OLD followed by a settling pond requires less land area than needed for a two-stagetreatment system consisting of an anoxic limestone drain and oxidation-settling pond or wetland. To facilitate removal of hydrous-oxide sludge, a perforated-pipe subdrain can be installed within an OLD. (C) 1999 Elsevier Science Ltd. |
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0883-2927 |
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Jul; Limestone drains to increase pH and remove dissolved metals from acidic mine drainage; Isi:000080043300004; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10102.pdf; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 17470 |
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22 |
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Barton, C.D.; Karathanasis, A.D. |
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Title |
Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage |
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Journal Article |
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Year |
1998 |
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Environ Geosci |
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5 |
Issue |
2 |
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43-56 |
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acid mine drainage aerobic environment anaerobic environment attenuation chemical fractionation chemical properties concentration constructed wetlands controls degradation detection environmental analysis ferric iron goethite heavy metals iron jarosite Kentucky McCreary County Kentucky metals oxides pollutants pollution seepage soils solubility sulfates surface water United States water treatment wetlands X-ray diffraction data 22, Environmental geology |
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1075-9565 |
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Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage; 2001-034195; References: 41; illus. incl. 1 table United States (USA); GeoRef; English |
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CBU @ c.wolke @ 16623 |
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61 |
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Karathanasis, A.D.; Barton, C.D. |
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The revival of a failed constructed wetland treating a high Fe load AMD |
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1999 |
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Proceedings; biogeochemistry of trace elements in coal and coal combustion byproducts |
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abandoned mines acid mine drainage anaerobic environment carbonate rocks characterization composting constructed wetlands design environmental analysis ferrihydrite geologic hazards hydrology hydroxides iron iron hydroxides Kentucky limestone metals minerals mines organic compounds oxides pollution remediation runoff sedimentary rocks sediments solubility sulfate ion United States water quality water treatment wetlands 22, Environmental geology |
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Kluwer Academic/Plenum Publishers |
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New York |
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Sajwan, K.S.; Alva, A.K.; Keefer, R.F. |
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0306462885 |
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The revival of a failed constructed wetland treating a high Fe load AMD; GeoRef; English; 2002-039561; Fourth international conference on the Biogeochemistry of trace elements, Berkeley, CA, United States, June 23, 1997 References: 45; illus. incl. 2 tables, sketch maps |
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CBU @ c.wolke @ 16571 |
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82 |
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Taylor, J.; Waters, J. |
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Title |
Treating ARD; how, when, where and why |
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2003 |
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Mining Environmental Management |
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11 |
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3 |
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6-9 |
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acid mine drainage; acid rock drainage; acidification; alkalinity; carbonate rocks; chemical properties; chemical reactions; coal; disposal barriers; economics; flocculation; ground water; heavy metals; human activity; ion exchange; limestone; mines; oxidation; oxides; permeability; pollution; porosity; pyrolusite; remediation; sedimentary rocks; surface water; waste disposal; waste management; water pollution; water treatment; wetlands 22, Environmental geology |
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0969-4218 |
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Treating ARD; how, when, where and why; 2004-045038; References: 8; illus. incl. 2 tables United Kingdom (GBR); GeoRef; English |
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CBU @ c.wolke @ 5528 |
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225 |
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McConchie, D.M.; Clark, M.; Hanahan, C.; Baun, R. |
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Title |
New treatments for the old problems of acid mine drainage and sulphidic mine tailings storage |
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2000 |
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acid mine drainage; ash; carbonate rocks; clastic sediments; construction materials; crushed stone; hydroxides; iron hydroxides; iron oxides; mines; mud; oxides; pH; pollution; reclamation; red mud; remediation; sea water; sedimentary rocks; sediments; storage; sulfides; tailings; waste management 22, Environmental geology |
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Programme & Abstracts - International Symposium on Environmental Geochemistry (ISEG), vol.5 |
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5th international symposium on Environmental geochemistry; conference abstracts and scientific programme |
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2006-033067; 5th international symposium on Environmental geochemistry, Cape Town, South Africa, April 2004; GeoRef; English |
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CBU @ c.wolke @ 5858 |
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304 |
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