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Zhuang, J.M. |
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Title |
Lignor(TM) process for acidic rock drainage treatment |
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Journal Article |
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2004 |
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Environ. Technol. |
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25 |
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9 |
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1031-1040 |
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mine water treatment |
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The process using lignosulfonates for acidic rock drainage (ARD) treatment is referred to as the Lignor(TM) process. Lignosulfonates are waste by-products produced in the sulfite pulping process. The present study has shown lignosulfonates are able to protect lime from developing an external surface coating, and hence to favor its dissociation. Further, the addition of lignosulfonates to ARD solutions increased the clotting and settling rate of the formed sludge. The capability of lignosulfonates to form stable metal-lignin complexes makes them very useful in retaining metal ions and thus improving the long-term stability of the sludge against leaching. The Lignor(TM) process involves metal sorption with lignosulfonates, ARD neutralization by lime to about pH 7, pH adjustment with caustic soda to 9.4 – 9.6, air oxidation to lower the pH to a desired level, and addition of a minimum amount of FeCl3 for further removal of dissolved metals. The Lignor(TM) process removes all concerned metals (especially Al and Mn) from the ARD of the Britannia Mine (located at Britannia Beach, British Columbia, Canada) to a level lower than the limits of the B.C. Regulations. Compared with the high-density sludge (HDS) process, the Lignor(TM) process has many advantages, such as considerable savings in lime consumption, greatly reduced sludge volume, and improved sludge stability. |
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Lignor(TM) process for acidic rock drainage treatment; Wos:000224971800006; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 16998 |
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117 |
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Author |
Zaluski, M. |
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Title |
Design and construction of bioreactors with sulfate-reducing bacteria for acid mine drainage control |
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1999 |
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Phytoremediation and Innovative Strategies for Specialized Remedial Applications |
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205-210 |
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mine water treatment |
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At many abandoned mine sites in the Western U.S., conventional treatment of AMD is not feasible due to the of lack of power and limited site accessibility. Therefore, three bioreactors were built at an abandoned mine site in Montana to demonstrate feasibility of treating AMD using sulphate reducing bacteria (SRB) in a passive water treatment train. The SRB are capable of increasing the pH and reducing the load of dissolved metals in the effluent. The reactors, constructed in the Fall of 1998, were designed to evaluate the SRB technology applied under different environmental conditions. Each bioreactor was designed with mechanisms to enable simulation of seasonal dry and wet climatic conditions. Two bioreactors were placed in trenches and one was constructed above the ground to investigate impact of seasonal freezing and thawing on SRB activity. Two bioreactors contain a passive pretreatment section to increase pH of water before the AMD enters the bioreactor chamber. |
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Design and construction of bioreactors with sulfate-reducing bacteria for acid mine drainage control; Isip:000082416500033; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 17136 |
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177 |
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Younger, P.L.; Cornford, C. |
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Mine water pollution from Kernow to Kwazulu-Natal; geochemical remedial options and their selection in practice |
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2002 |
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Africa Bolivia case studies Cornwall England cost decision-making decontamination Durham England England Europe geochemistry Great Britain Hlobane Colliery hydrology Kernow England KwaZulu-Natal South Africa metals Milluni Mine mine drainage monitoring pollutants pollution Quaking Houses England remediation South Africa South America South Crofty Mine South-West England Southern Africa United Kingdom water treatment Western Europe Wheal Jane Mine 22, Environmental geology |
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Pollution by mine drainage is a major problem in many parts of the world. The most frequent contaminants are Fe, Mn, Al and SO (sub 4) with locally important contributions by other metals/metalloids including (in order of decreasing frequency) Zn, Cu, As, Ni, Cd and Pb. Remedial options for such polluted drainage include monitored natural attenuation, physical intervention to minimise pollutant release, and active and passive water treatment technologies. Based on the assessment of the key hydrological and geochemical attributes of mine water discharges, a rational decision-making framework has now been developed for deciding which (or which combinations) of these options to implement in a specific case. Five case studies illustrate the application of this decision-making process in practice: Wheal Jane and South Crofty (Cornwall), Quaking Houses (Co Durham), Hlobane Colliery (South Africa) and Milluni Tin Mine (Bolivia). In many cases, particularly where the socio-environmental stakes are particularly high, the economic, political and ecological issues will prove even more challenging than the technical difficulties involved in implementing remedial interventions which will be robust in the long term. Hence truly “holistic” mine water remediation is a multi-dimensional business, involving teamwork by a range of geoscientific, hydroecological and socio-economic specialists. |
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Proceedings of the Ussher Society, vol.10, Part 3 |
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40th annual meeting of the Ussher Society |
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2004-019557; 40th annual meeting of the Ussher Society, Saint Austell, United Kingdom, Jan. 3-4, 2002 Scott Simpson lecture References: 39; illus. incl. 3 tables; GeoRef; English |
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CBU @ c.wolke @ 16506 |
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194 |
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Author |
Younger, P.L. |
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Title |
Passive in situ remediation of acidic mine waste leachates: progress and prospects |
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2003 |
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Land Reclamation: Extending the Boundaries |
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253-264 |
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mine water treatment |
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The reclamation of former mining sites is a major challenge in many parts of the world. In relation to the restoration of spoil heaps (mine waste rock piles) and similar bodies of opencast backfill, key challenges include (i) the establishment of stable slopes and minimization of other geotechnical hazards (ii) developing and maintaining a healthy vegetative cover (iii) managing the hydrological behaviour of the restored ground. Significant advances have been made over the past four decades in relation to all four of these objectives. One of the most recalcitrant problems is the ongoing generation and release of acidic leachates, which typically emerge at the toes of (otherwise restored) spoil heaps in the form of springs and seepage areas. Such features are testament to the presence of a “perched” groundwater circulation system within the spoil, and their acidity reflects the continued penetration of oxygen to zones within the heaps which contain reactive pyrite (and other iron sulphide minerals). Two obvious strategies for dealing with this problem are disruption of the perched groundwater system and/or exclusion of oxygen entry. These strategies are now being pursued with considerable success where spoil is being reclaimed for the first time, by the installation of two types of physical barrier (dry covers and water covers). However, where a spoil heap has already been revegetated some decades ago, the destruction of an established sward or woodland in order to retro-fit a dry cover or water cover is rarely an attractive option for dealing with the “secondary dereliction” represented by ongoing toe seepages of acidic leachates. More attractive by far are passive treatment techniques, in which the polluted water is forced to flow through reactive media which serve to neutralize its acidity and remove toxic metals from solution. A brief historical review of the development of such systems reveals a general progression from using limestone as the key neutralizing agent, through a combined use of limestone and compost, to systems in which almost all of the neutralization is achieved by means of bacterial sulphate reduction in the saturated compost media of subsurface-flow bioreactors. In almost all cases, these passive treatment systems include an aerobic, surface flow wetland as the final “polishing” step in the treatment process. Such wetlands combine treatment functions (efficient removal of metals from the now-neutralized waters down to low residual concentrations, and re-oxygenating the water prior to discharge to receiving watercourses) with amenity value (attractive areas for recreational walking, bird-watching etc) and ecological value. |
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Passive in situ remediation of acidic mine waste leachates: progress and prospects; Isip:000183447100035; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 17016 |
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158 |
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Younger, P.L. |
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The adoption and adaptation of passive treatment technologies for mine waters in the United Kingdom |
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2000 |
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Mine Water Env. |
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19 |
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2 |
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84-97 |
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wetlands SAPS aerobic wetlands acidity aerobic anaerobic compost iron metals passive reactive barrier water treatment |
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During the 1990s, passive treatment technology was introduced to the United Kingdom (UK). Early hesitancy on the part of regulators and practitioners was rapidly overcome, at least for net-alkaline mine waters, so that passive treatment is now the technology of choice for the long-term remediation of such discharges, wherever land availability is not unduly limiting. Six types of passive systems are now being used in the UK for mine water treatment: ¨ aerobic, surface flow wetlands (reed-beds); ¨ anaerobic, compost wetlands with significant surface flow; ¨ mixed compost / limestone systems, with predominantly subsurface flow (so-called Reducing and Alkalinity Producing Systems (RAPS)); ¨ subsurface reactive barriers to treat acidic, metalliferous ground waters; ¨ closed-system limestone dissolution systems for zinc removal from alkaline waters; ¨ roughing filters for treating ferruginous mine waters where land availability is limited. Each of these technologies is appropriate for a different kind of mine water, or for specific hydraulic circumstances. The degree to which each type of system can be considered “proven technology” corresponds to the order in which they are listed above. Many of these passive systems have become foci for detailed scientific research, as part of a $1.5M European Commission project running from 2000 to 2003. |
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1025-9112 |
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The adoption and adaptation of passive treatment technologies for mine waters in the United Kingdom; 1; FG 5 Abb., 1 Tab.; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 17448 |
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198 |
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