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Juby, G.J.G. |
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Title |
Desalination of calcium sulphate scaling mine water: Design and operation of the SPARRO process |
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Journal Article |
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Year |
1996 |
Publication |
Water Sa |
Abbreviated Journal |
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22 |
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2 |
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161-172 |
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Keywords |
mine water treatment |
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Abstract |
The South African mining industry discharges relatively small quantities of mine service water to the environment, but these effluents contribute substantially to the salt load of the receiving waters. The poor quality of service water also has significant cost implications on the mining operations. Of the two main types of mine service water encountered in the gold mining industry, the so-called calcium sulphate scaling types is found in the majority of cases. Preliminary testwork on this type of water using membrane desalination processes revealed that only the seeded reverse osmosis type of process showed promise. To overcome certain process problems and high operating costs with this system, a novel membrane desalination technique incorporating seeded technology, called the SPARRO (slurry precipitation and recycle reverse osmosis) process, was developed. The novel features of the new process included; a lower linear slurry velocity in the membrane tubes, a lower seed slurry concentration, a dual pumping arrangement to a tapered membrane stack, a smaller reactor and a modified seed crystal and brine blow-down system. Evaluation of the SPARRO process and its novel features, over a five-year period, confirmed its technical viability for desalinating calcium sulphate-scaling mine water. The electrical power consumption of the process was approximately half that of previous designs, significantly improving its efficiency. Membrane performance was evaluated and was generally unsatisfactory with both fouling and hydrolysis dominating at times, although operating conditions for the membranes were not always ideal. The precise cause(s) for the membrane degradation was not established, but a mechanism for fouling (based upon the presence of turbidity in the mine water) and a hypothesis fora possible cause of hydrolysis (alluding to the presence of radionuclides in the mine water) were proposed. Product water from the SPARRO process has an estimated gross unit cost (including capital costs) of 383 c/m(3) (1994). |
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Desalination of calcium sulphate scaling mine water: Design and operation of the SPARRO process; Wos:A1996uh88100009; Times Cited: 5; ISI Web of Science |
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CBU @ c.wolke @ 17168 |
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86 |
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Author |
Davison, W. |
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Title |
Neutralizing Strategies For Acid Waters – Sodium And Calcium Products Generate Different Acid Neutralizing Capacities |
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Journal Article |
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Year |
1988 |
Publication |
Water Res |
Abbreviated Journal |
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22 |
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5 |
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577-583 |
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Keywords |
mine water treatment |
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Neutralizing Strategies For Acid Waters – Sodium And Calcium Products Generate Different Acid Neutralizing Capacities; Wos:A1988p420900008; Times Cited: 8; ISI Web of Science |
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CBU @ c.wolke @ 9085 |
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90 |
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Author |
Chung, I.J. |
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Title |
Immobilization of arsenic in tailing by using iron and hydrogen peroxide |
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Journal Article |
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2001 |
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Environ. Technol. |
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22 |
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7 |
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831-835 |
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mine water treatment |
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Under environmental conditions, arsenic (As) reveals anionic behavior and is converted into various forms in accordance with the Eh/pH condition. This causes the difficulty of treating As with other heavy metals in tailing. This study was carried out to develop the immobilization method of arsenic in tailing as ferric arsenate (FeAsO4) using hydrogen peroxide. According to experimental results, the extracted concentrations of arsenic and iron (Fe) from tailing were reduced up to 84% and 93%, respectively. In the experiment using pure Pyrite (FeS2) and As solution, As concentration decreased with an increase of hydrogen peroxide dosage. The experimental results of re-extraction showed that only 10% of As and 20% of Fe were extracted in the case of using hydrogen peroxide. As a result, the long-term stability of this method was clarified. |
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Immobilization of arsenic in tailing by using iron and hydrogen peroxide; Wos:000170195000008; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 17046 |
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123 |
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Ziemkiewicz, P.F.; Skousen, J.G.; Simmons, J. |
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Title |
Long-term Performance of Passive Acid Mine Drainage Treatment Systems |
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Journal Article |
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2003 |
Publication |
Mine Water Env. |
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22 |
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3 |
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118-129 |
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Keywords |
acidity acid load aerobic wetlands anaerobic wetlands anoxic limestone drains limestone leach beds open limestone channels slag leach beds successive alkalinity producing systems vertical flow wetlands |
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State and federal reclamation programs, mining operators, and citizen-based watershed organizations have constructed hundreds of passive systems in the eastern U.S. over the past 20 years to provide reliable, low cost, low maintenance mine water treatment in remote locations. While performance has been reported for individual systems, there has not been a comprehensive evaluation of the performance of each treatment type for a wide variety of conditions. We evaluated 83 systems: five types in eight states. Each system was monitored for influent and effluent flow, pH, net acidity, and metal concentrations. Performance was normalized among types by calculating acid load reductions and removals, and by converting construction cost, projected service life, and metric tonnes of acid load treated into cost per tonne of acid treated. Of the 83 systems, 82 reduced acid load. Average acid load reductions were 9.9 t/yr for open limestone channels (OLC), 10.1 t/yr for vertical flow wetlands (VFW), 11.9 t/yr for anaerobic wetlands (AnW), 16.6 t/yr for limestone leach beds (LSB), and 22.2 t/yr for anoxic limestone drains (ALD). Average costs for acid removal varied from $83/t/yr for ALDs to $527 for AnWs. Average acid removals were 25 g/m2/day for AnWs, 62 g/m2/day for VFWs, 22 g/day/t for OLCs, 28 g/day/t for LSBs, and 56 g/day/t for ALDs. It appears that the majority of passive systems are effective but there was wide variation within each system type, so improved reliability and efficiency are needed. This report is an initial step in determining passive treatment system performance; additional work is needed to refine system designs and monitoring. |
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1025-9112 |
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Long-term Performance of Passive Acid Mine Drainage Treatment Systems; 1; FG 1 Abb., 7 Tab.; AMD ISI | Wolkersdorfer |
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Call Number |
CBU @ c.wolke @ 17454 |
Serial |
187 |
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Author |
Plumlee, G.S. |
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Title |
Mine-drainage waters as potential economic resources |
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Journal Article |
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Year |
1995 |
Publication |
SEG Newsletter |
Abbreviated Journal |
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22 |
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6-7 |
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Keywords |
acid mine drainage; Colorado; concentration; geochemistry; hydrochemistry; metals; mine drainage; mineral resources; mines; remediation; Rio Grande County Colorado; Summitville Mine; United States; utilization 27A, Economic geology, geology of ore deposits |
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Mine-drainage waters as potential economic resources; 2004-033372; References: 7; 1 table United States (USA); GeoRef; English |
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Call Number |
CBU @ c.wolke @ 6428 |
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268 |
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