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Author |
Wolkersdorfer, C. |
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Title |
Mine water tracer tests as a basis for remediation strategies |
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Journal Article |
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Year |
2005 |
Publication |
Chemie der Erde |
Abbreviated Journal |
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65 |
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Suppl. 1 |
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65-74 |
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Mine water treatment Stratification Convection First flush Tracer tests Microspheres Reactive transport Groundwater problems and environmental effects Pollution and waste management non radioactive acid mine drainage remediation |
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Abstract |
Mining usually causes severe anthropogenic changes by which the ground- or surface water might be significantly polluted. One of the main problems in the mining industry are acid mine drainage, the drainage of heavy metals, and the prediction of mine water rebound after mine closure. Therefore, the knowledge about the hydraulic behaviour of the mine water within the flooded mine might significantly reduce the costs of mine closure and remediation. In the literature, the difficulties in evaluating the hydrodynamics of flooded mines are well described, but only few tracer tests in flooded mines have been published so far. Most tracer tests linked to mine water problems were related to either pollution of the aquifer or radioactive waste disposal and not the mine water itself. Applying the results of the test provides possibilities f or optimizing the outcome of the source-path-target methodology and therefore diminishes the costs of remediation strategies. Consequently, prior to planning of remediation strategies or numerical simulations, relatively cheap and reliable results for decision making can be obtained via a well conducted tracer test. < copyright > 2005 Elsevier GmbH. All rights reserved. |
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C. Wolkersdorfer, TU Bergakademie Freiberg, Lehrstuhl fur Hydrogeologie, 09596 Freiberg, Sachsen, Germany c.wolke@tu-freiberg.de |
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0009-2819 |
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Sep 19; Mine water tracer tests as a basis for remediation strategies; 2767887; Germany 34; Geobase |
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CBU @ c.wolke @ 17499 |
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34 |
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Conca, J.L.; Wright, J. |
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An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd |
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Journal Article |
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2006 |
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Appl. Geochem. |
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21 |
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12 |
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2188-2200 |
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Pollution and waste management non radioactive Groundwater quality apatite groundwater remediation zinc lead cadmium acid mine drainage copper sulfate nitrate permeability water treatment precipitation chemistry |
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Phosphate-induced metal stabilization involving the reactive medium Apatite II(TM) [Ca10-xNax(PO4)6-x(CO3)x(OH)2], where x < 1, was used in a subsurface permeable reactive barrier (PRB) to treat acid mine drainage in a shallow alluvial groundwater containing elevated concentrations of Zn, Pb, Cd, Cu, SO4 and NO3. The groundwater is treated in situ before it enters the East Fork of Ninemile Creek, a tributary to the Coeur d'Alene River, Idaho. Microbially mediated SO4 reduction and the subsequent precipitation of sphalerite [ZnS] is the primary mechanism occurring for immobilization of Zn and Cd. Precipitation of pyromorphite [Pb10(PO4)6(OH,Cl)2] is the most likely mechanism for immobilization of Pb. Precipitation is occurring directly on the original Apatite II. The emplaced PRB has been operating successfully since January of 2001, and has reduced the concentrations of Cd and Pb to below detection (2 μg L-1), has reduced Zn to near background in this region (about 100 μg L-1), and has reduced SO4 by between 100 and 200 mg L-1 and NO3 to below detection (50 μg L-1). The PRB, filled with 90 tonnes of Apatite II, has removed about 4550 kg of Zn, 91 kg of Pb and 45 kg of Cd, but 90% of the immobilization is occurring in the first 20% of the barrier, wherein the reactive media now contain up to 25 wt% Zn. Field observations indicate that about 30% of the Apatite II material is spent (consumed). |
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0883-2927 |
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Dec.; An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd; Science Direct |
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CBU @ c.wolke @ 17248 |
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44 |
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Johnson, D.B.; Hallberg, K.B. |
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Title |
Acid mine drainage remediation options: a review |
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Journal Article |
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2005 |
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Science of the Total Environment |
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338 |
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1-2 |
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3-14 |
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Wetlands and estuaries Pollution and waste management non radioactive geographical abstracts: physical geography hydrology (71 6 8) geological abstracts: environmental geology (72 14 2) biological method pollutant removal water treatment wastewater bioremediation constructed wetland acid mine drainage Cornwall England England United Kingdom Western Europe Europe Eurasia Eastern Hemisphere World Acid mine drainage Bioreactors Bioremediation Sulfidogenesis Wetlands Wheal Jane |
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Acid mine drainage (AMD) causes environmental pollution that affects many countries having historic or current mining industries. Preventing the formation or the migration of AMD from its source is generally considered to be the preferable option, although this is not feasible in many locations, and in such cases, it is necessary to collect, treat, and discharge mine water. There are various options available for remediating AMD, which may be divided into those that use either chemical or biological mechanisms to neutralise AMD and remove metals from solution. Both abiotic and biological systems include those that are classed as “active” (i.e., require continuous inputs of resources to sustain the process) or “passive” (i.e., require relatively little resource input once in operation). This review describes the current abiotic and bioremediative strategies that are currently used to mitigate AMD and compares the strengths and weaknesses of each. New and emerging technologies are also described. In addition, the factors that currently influence the selection of a remediation system, and how these criteria may change in the future, are discussed. |
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0048-9697 |
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Feb. 01; Acid mine drainage remediation options: a review; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10052.pdf; Science Direct |
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CBU @ c.wolke @ 17464 |
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47 |
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Hulshof, A.H.M.; Blowes, D.W.; Douglas Gould, W. |
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Title |
Evaluation of in situ layers for treatment of acid mine drainage: A field comparison |
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Journal Article |
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2006 |
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Water Res |
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40 |
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9 |
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1816-1826 |
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mine water Pollution and waste management non radioactive Groundwater problems and environmental effects acid mine drainage organic carbon oxidation microbial activity drainage groundwater pollution Bacteria microorganisms Contamination Groundwater Barriers Drainage Treatment |
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Reactive treatment layers, containing labile organic carbon, were evaluated to determine their ability to promote sulfate reduction and metal sulfide precipitation within a tailings impoundment, thereby treating tailings effluent prior to discharge. Organic carbon materials, including woodchips and pulp waste, were mixed with the upper meter of tailings in two separate test cells, a third control cell contained only tailings. In the woodchip cell sulfate reduction rates were 500 mg L-1 a-1, (5.2 mmol L-1 a-1) this was coupled with the gradual removal of 350 mg L-1 Zn (5.4 mmol L-1). Decreased δ13CDIC values from -3‰ to as low as -12‰ indicated that sulfate reduction was coupled with organic carbon oxidation. In the pulp waste cell the most dramatic change was observed near the interface between the pulp waste amended tailings and the underlying undisturbed tailings. Sulfate reduction rates were 5000 mg L-1 a-1 (52 mmol L-1 a-1), Fe concentrations decreased by 80–99.5% (148 mmol L-1) and Zn was consistently <5 mg L-1. Rates of sulfate reduction and metal removal decreased as the pore water migrated upward into the shallower tailings. Increased rates of sulfate reduction in the pulp waste cell were consistent with decreased δ13CDIC values, to as low as -22‰, and increased populations of sulfate reducing bacteria. Lower concentrations of the nutrients, phosphorus, organic carbon and nitrogen in the woodchip material contribute to the lower sulfate reduction rates observed in the woodchip cell. |
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0043-1354 |
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May; Evaluation of in situ layers for treatment of acid mine drainage: A field comparison; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10040.pdf; Science Direct |
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CBU @ c.wolke @ 10040 |
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49 |
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Author |
Coulton, R.; Bullen, C.; Hallett, C. |
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Title |
The design and optimisation of active mine water treatment plants |
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Journal Article |
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2003 |
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Land Contam. Reclam. |
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11 |
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2 |
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273-280 |
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sludge mine water treatment mine water active treatment precipitation iron manganese high density sludge sulphide Groundwater problems and environmental effects Pollution and waste management non radioactive manganese sulfide pollutant removal iron water treatment mine drainage |
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This paper provides a 'state of the art' overview of active mine water treatment. The paper discusses the process and reagent selection options commonly available to the designer of an active mine water treatment plant. Comparisons are made between each of these options, based on technical and financial criteria. The various different treatment technologies available are reviewed and comparisons made between conventional precipitation (using hydroxides, sulphides and carbonates), high density sludge processes and super-saturation precipitation. The selection of reagents (quick lime, slaked lime, sodium hydroxide, sodium carbonate, magnesium hydroxide, and proprietary chemicals) is considered and a comparison made on the basis of reagent cost, ease of use, final effluent quality and sludge settling criteria. The choice of oxidising agent (air, pure oxygen, peroxide, etc.) for conversion of ferrous to ferric iron is also considered. Whole life costs comparisons (capital, operational and decommissioning) are made between conventional hydroxide precipitation and the high density sludge process, based on the actual treatment requirements for four different mine waters. |
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R. Coulton, Unipure Europe Ltd., Wonastow Road, Monmouth NP25 5JA, United Kingdom |
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0967-0513 |
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The design and optimisation of active mine water treatment plants; 2530436; United-Kingdom 4; Geobase |
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CBU @ c.wolke @ 17513 |
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59 |
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