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Author Benner, S.G. url  openurl
  Title (up) Geochemistry of a permeable reactive barrier for metals and acid mine drainage Type Journal Article
  Year 1999 Publication Environmental Science & Technology Abbreviated Journal  
  Volume 33 Issue 16 Pages 2793-2799  
  Keywords mine water treatment  
  Abstract A permeable reactive barrier, designed to remove metals and generate alkalinity by promoting sulfate reduction and metal sulfide precipitation, was installed in August 1995 into an aquifer containing effluent from mine tailings. Passage of groundwater through the barrier results in striking improvement in water quality. Dramatic changes in concentrations of SO4 (decrease of 2000-3000 mg/L), Fe (decrease of 270-1300 mg/L), trace metals (e.g., Ni decreases 30 mg/L), and alkalinity (increase of (800-2700 mg/L) are observed. Populations of sulfate reducing bacteria are 10 000 times greater, and bacterial activity, as measured by dehydrogenase activity, is 10 rimes higher within the barrier compared to the up-gradient aquifer. Dissolved sulfide concentrations increase by 0.2-120 mg/ L, and the isotope S-34 is enriched relative to S-32 in the dissolved phase SO42- within the barrier. Water chemistry, coupled with geochemical speciation modeling, indicates the pore water in the barrier becomes supersaturated with respect to amorphous Fe sulfide. Solid phase analysis of the reactive mixture indicates the accumulation of Fe monosulfide precipitates. Shifts in the saturation states of carbonate, sulfate, and sulfide minerals and most of the observed changes in water chemistry in the barrier and down-gradient aquifer can be attributed, either directly or indirectly, to bacterially mediated sulfate reduction.  
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  Notes Geochemistry of a permeable reactive barrier for metals and acid mine drainage; Wos:000082074500017; Times Cited: 57; ISI Web of Science Approved no  
  Call Number CBU @ c.wolke @ 17115 Serial 132  
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Author Swayze, G.A. url  openurl
  Title (up) Imaging spectroscopy: A new screening tool for mapping acidic mine waste Type Journal Article
  Year 2000 Publication ICARD 2000, Vols I and II, Proceedings Abbreviated Journal  
  Volume Issue Pages 1531-+  
  Keywords mine water treatment  
  Abstract Imaging spectroscopy is a relatively new remote sensing tool that provides a rapid method to screen entire mining districts for potential sources of surface acid drainage. An imaging spectrometer known as the Airborne Visible/InfraRed Imaging Spectrometer (AVIRIS) measures light reflected from the surface in 224 spectral channels from 0.4 – 2.5 mum. Spectral data from this instrument were used to evaluate mine waste at the California Gulch Superfund Site near Leadville, Colorado. Here, the process of pyrite oxidation at the surface produces acidic water that is gradually neutralized as it drains away from mine waste, depositing a central jarosite zone surrounded by a jarosite + goethite zone, in turn surrounded by a goethite zone with a discontinuous hematite rim zone. Leaching tests show that pH is most acidic in the jarosite and jarosite+goethite zones and is near-neutral in the goethite zone. Measurements indicate that metals leach from minerals and amorphous materials in the jarosite + goethite and jarosite zones at concentrations 10 – 50 times higher than from goethite zone minerals. Goethite zones that fully encircle mine waste may indicate some attenuation of leachate metals and thus reduced metal loading to streams. The potential for impact by acidic drainage is highest where streams intersect the jarosite and jarosite + goethite zones. In these areas, metal-rich acidic surface runoff may flow directly into streams. The U.S. Environmental Protection Agency estimates (U.S. EPA, 1998) that mineral maps made from AVIRIS data at Leadville have accelerated remediation efforts by two years and saved over $2 million in cleanup costs.  
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  Notes Imaging spectroscopy: A new screening tool for mapping acidic mine waste; Isip:000169875500152; Times Cited: 0; ISI Web of Science Approved no  
  Call Number CBU @ c.wolke @ 17111 Serial 164  
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Author Chung, I.J. url  openurl
  Title (up) Immobilization of arsenic in tailing by using iron and hydrogen peroxide Type Journal Article
  Year 2001 Publication Environ. Technol. Abbreviated Journal  
  Volume 22 Issue 7 Pages 831-835  
  Keywords mine water treatment  
  Abstract Under environmental conditions, arsenic (As) reveals anionic behavior and is converted into various forms in accordance with the Eh/pH condition. This causes the difficulty of treating As with other heavy metals in tailing. This study was carried out to develop the immobilization method of arsenic in tailing as ferric arsenate (FeAsO4) using hydrogen peroxide. According to experimental results, the extracted concentrations of arsenic and iron (Fe) from tailing were reduced up to 84% and 93%, respectively. In the experiment using pure Pyrite (FeS2) and As solution, As concentration decreased with an increase of hydrogen peroxide dosage. The experimental results of re-extraction showed that only 10% of As and 20% of Fe were extracted in the case of using hydrogen peroxide. As a result, the long-term stability of this method was clarified.  
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  Notes Immobilization of arsenic in tailing by using iron and hydrogen peroxide; Wos:000170195000008; Times Cited: 0; ISI Web of Science Approved no  
  Call Number CBU @ c.wolke @ 17046 Serial 123  
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Author Sasaki, K. url  openurl
  Title (up) Immobilization of Mn(II) ions by a Mn-oxidizing fungus – Paraconiothyrium sp.-like strain at neutral pHs Type Journal Article
  Year 2006 Publication Mater. Trans. Abbreviated Journal  
  Volume 47 Issue 10 Pages 2457-2461  
  Keywords mine water treatment  
  Abstract A Mn-oxidizing fungus was isolated from a constructed wetland of Hokkaido (Japan), which is receiving the Mn-impacted drainage, and genetically and morphologically identified as Paraconiothyrium sp.-like strain. The optimum pHs were 6.45-6.64, where is more acidic than those of previously reported Mn-oxidizing fungi. Too much nutrient inhibited fungal Mn-oxidation, and too little nutrient also delayed Mn oxidation even at optimum pH. In order to achieve the oxidation of high concentrations of Mn like mine drainage containing several hundreds g-m(-3) of Mn, it is important to find the best mix ratio among the initial Mn concentrations, inocolumn size and nutrient concentration. The strain has still Mn-tolerance with more than 380 g-m(-3) of Mn, but high Mn(II) oxidation was limited by pH control and supplied nutrient amounts. The biogenic Mn deposit was poorly crystallized birnessite. The strain is an unique Mn-oxidizing fungus having a high Mn tolerance and weakly acidic tolerance, since there has been no record about the property of the strain. There is a potentiality to apply the strain to the environmental bioremediation.  
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  Notes Immobilization of Mn(II) ions by a Mn-oxidizing fungus – Paraconiothyrium sp.-like strain at neutral pHs; Wos:000242429300002; Times Cited: 0; ISI Web of Science Approved no  
  Call Number CBU @ c.wolke @ 16940 Serial 103  
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Author Kuyucak, N. url  openurl
  Title (up) Improved lime neutralization process Type Journal Article
  Year 1995 Publication Sudbury '95 – Mining and the Environment, Conference Proceedings, Vols 1-3 Abbreviated Journal  
  Volume Issue Pages 129-137  
  Keywords mine water treatment  
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  Notes Improved lime neutralization process; Isip:A1995bg39j00014; Times Cited: 0; ISI Web of Science Approved no  
  Call Number CBU @ c.wolke @ 8882 Serial 143  
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