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Author |
Evangelou, V.P. |
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Title  |
Pyrite microencapsulation technologies: Principles and potential field application |
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Journal Article |
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Year |
2001 |
Publication |
Ecological Engineering |
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17 |
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2-3 |
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165-178 |
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Keywords |
mine water treatment Acid mine drainage Acidity Alkalinity Amelioration Coating Oxidation Surface reactions |
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Abstract |
In nature, pyrite is initially oxidized by atmospheric O2, releasing acidity and Fe2+. At pH below 3.5, Fe2+ is rapidly oxidized by T. ferrooxidans to Fe3+, which oxidizes pyrite at a much faster rate than O2. Commonly, limestone is used to prevent pyrite oxidation. This approach, however, has a short span of effectiveness because after treatment the surfaces of pyrite particles remain exposed to atmospheric O2 and oxidation continuous abiotically. Currently, a proposed mechanism for explaining non-microbial pyrite oxidation in high pH environments is the involvement of OH- in an inner-sphere electron-OH exchange between pyrite/surface-exposed disulfide and pyrite/surface-Fe(III)(OH)n3-n complex and/or formation of a weak electrostatic pyrite/surface-CO3 complex which enhances the chemical oxidation of Fe2+. The above infer that limestone application to pyritic geologic material treats only the symptoms of pyrite oxidation through acid mine drainage neutralization but accelerates non-microbial pyrite oxidation. Therefore, only a pyrite/surface coating capable of inhibiting O2 diffusion is expected to control long-term oxidation and acid drainage production. The objective of this study was to examine the feasibility in controlling pyrite oxidation by creating, on pyrite surfaces, an impermeable phosphate or silica coating that would prevent either O2 or Fe3+ from further oxidizing pyrite. The mechanism underlying this coating approach involves leaching mine waste with a coating solution composed of H2O2 or hypochlorite, KH2PO4 or H4SiO4, and sodium acetate (NaAC) or limestone. During the leaching process, H2O2 or hypochlorite oxidizes pyrite and produces Fe3+ so that iron phosphate or iron silicate precipitates as a coating on pyrite surfaces. The purpose of NaAC or limestone is to eliminate the inhibitory effect of the protons (produced during pyrite oxidation) on the precipitation of iron phosphate or silicate and to generate iron-oxide pyrite coating, which is also expected to inhibit pyrite oxidation. The results showed that iron phosphate or silicate coating could be established on pyrite by leaching it with a solution composed of: (1) H2O2 0.018-0.16 M; (2) phosphate or silicate 10-3 to 10-2 M; (3) coating-solution pH [approximate]5-6; and (4) NaAC as low as 0.01 M. Leachates from column experiments also showed that silicate coatings produced the least amount of sulfate relative to the control, limestone and phosphate treatments. On the other hand, limestone maintained the leachate near neutral pH but produced more sulfate than the control. |
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0925-8574 |
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July 01; Pyrite microencapsulation technologies: Principles and potential field application; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10063.pdf; Science Direct |
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CBU @ c.wolke @ 10063 |
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37 |
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Berg, G.J.; Arthur, B. |
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Title |
Proposed mine water treatment in Wisconsin |
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Book Chapter |
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1999 |
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Sudbury '99; mining and the environment II; Conference proceedings |
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metals mines pollutants pollution remediation tailings United States waste water water water management water quality water resources water treatment Wisconsin 22, Environmental geology |
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Water quality standards are driving wastewater effluent limits to ultra-low levels in the nanogram/L range. Standards are proposed that require discharges to match background water quality. The new ultra-low level standards require cautious sampling techniques, super clean laboratory methods and more advanced treatment technologies. This paper follows a case history through water quality standards for ultra-low metals, laboratory selection, and the design of a wastewater treatment system that can meet the water quality standards which are required to permit a proposed copper and zinc mine in Northern Wisconsin. A high degree of care must be taken when sampling for ultra-low level metals. Both surface water and treated effluent samples present new challenges. Sampling methods used must assure that there are no unwanted contaminants being introduced to the samples. The selection of a laboratory is as critical as the construction of a state of the art wastewater treatment system. Treatment methods such as lime and sulfide precipitation have had a high degree of success, but they do have limitations. Given today's ultra-low standards, it is necessary to assess the ability of reverse osmosis, deionization, and evaporation to provide the high level of treatment required. |
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Sudbury Environmental |
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Sudbury |
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Goldsack, D.; Belzile, N.; Yearwood, P.; Hall, G.J. |
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0886670470 |
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Proposed mine water treatment in Wisconsin; GeoRef; English; 2000-043747; Sudbury '99; Mining and the environment II--Sudbury '99; L'exploitation miniere et l'environnement II, Sudbury, ON, Canada, Sept. 13-17, 1999 illus. incl. 5 tables |
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CBU @ c.wolke @ 16588 |
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451 |
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Chua, A.S.M.; Takabatake, H.; Satoh, H.; Mino, T. |
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Production of polyhydroxyalkanoates (PHA) by activated sludge treating municipal wastewater: effect of pH, sludge retention time (SRT), and acetate concentration in influent |
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2003 |
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Water Res |
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37 |
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15 |
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3602-3611 |
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0043-1354 |
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Production of polyhydroxyalkanoates (PHA) by activated sludge treating municipal wastewater: effect of pH, sludge retention time (SRT), and acetate concentration in influent; 1647413788; UB Bayreuth <703> TU Berlin <83> UB Braunschweig <84> SUB Bremen <46> UB Cottbus <Co 1> SLUB Dresden <14> SUB Goettingen <7> SUB+Uni Hamburg <18> TUB Hamburg <830> TIB/UB Hannover <89> UB Ilmenau <Ilm 1> UB Karlsruhe <90> ULB + FH Merseburg <3/55> BSB München <12> UB Stuttgart <93> UB Hohenheim <100> UB Trier <385> Österreichische ZB Physik, Wie; OLC-SSG Technik – Online Contents-Sondersammelgebiete |
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CBU @ c.wolke @ 2160 |
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417 |
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Author |
Godard, M. |
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Principes d'exhaure et de traitement des eaux chargees aux houilleres du bassin de Lorraine. Darstellung der Verfahren zur Wasserhaltung und zur Wasseraufbereitung in den Steinkohlengruben des Lothringer Beckens. Draining principles and treatment of water used in the Lorraine mining basin |
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1997 |
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Mines et Carrieres |
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Feb |
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42-45 |
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Steinkohlenbergbau Frankreich Industrieabwasser Kläranlage Absetzbecken Schlammabscheidung Schlammpumpe Versatz=Bergbau Kolbenpumpe Kreiselpumpe Wasserhaltungspumpe Kohlenschlammpumpe Kosteneinsparung Systemoptimierung Abwasserbehandlung Stoffführung Untertagebau Grubenwasserhaltung |
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Im lothringischen Steinkohlenbergbau werden bis 3 m(exp 3)/min Wasser bei den Gewinnungsarbeiten zur Staubbekämpfung benötigt, die anschließend einer mehrstufigen Wasseraufbereitung zugeführt werden müssen. Die Abscheidung der Feststoffe aus dem Grubenwasser erfolgt teilweise in der Nähe der Gewinnungsbereiche in untertägigen Absetzbecken. Die dort anfallenden Schlämme werden in Zyklonieranlagen entwässert und als Versatzmaterial verwendet. Die so gereinigten Wässer werden der Hauptwasserhaltung zugeführt. In den meisten Fällen ist eine derartige Reinigung der Abwässer im Vorortbereich jedoch nicht möglich, und die mit Feststoffen belasteten Wässer müssen dann durch Schlammpumpen (leistungsfähige Kolbenpumpen) zu zentralen untertägigen Absetzbecken gefördert werden, wo sich die Schlämme absetzen und die geklärten Wässer der Wasserhaltung zugeführt werden. Es werden die unterschiedlichen Verfahren zur Behandlung der Schlämme aus den Absetzbecken beschrieben. Im Rahmen einer Rekonstruktion wurden die ursprünglich vorhandenen 43 Kreiselpumpen zur Schlammförderung (installierte Leistung von 2365 kW) durch 3 leistungsfähige Kolbenpumpen (installierte Leistung 960 kW) ersetzt, was sich günstig auf die Kosten auswirkte. Die von der Hauptwasserhaltung gehobenen Grubenwässer werden im Übertagebereich nochmals in Absetzbecken geklärt bzw. in einer neuen Zyklonanlage gereinigt. |
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Principes d'exhaure et de traitement des eaux chargees aux houilleres du bassin de Lorraine. Darstellung der Verfahren zur Wasserhaltung und zur Wasseraufbereitung in den Steinkohlengruben des Lothringer Beckens. Draining principles and treatment of water used in the Lorraine mining basin; 13311, BERG , 30.04.97; Words: 498; U9705 0026 586; 4 Seiten, 7 Bilder 3MZ *Bergbau, Tunnelbau, Erdöl /Erdgasförderung, Bohrtechnik* 3UXX *Belastung von Wasser, Wasserreinhaltung, Abwasser* 3MGK *Pumpen*; BERG, Copyright FIZ Technik e.V.; FR Französisch |
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CBU @ c.wolke @ 17602 |
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371 |
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Author |
Dugan, P.R. |
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Prevention of formation of acid drainage from high-sulfur coal refuse by inhibition of iron- and sulfur-oxidizing microorganisms. II. Inhibition in run of mine refuse under simulated field conditions |
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1987 |
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Biotechnol. Bioeng. |
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29 |
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1 |
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6 |
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mine water treatment Chemistry Biochemistry and Biotechnology |
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0006-3592 |
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Jan; Prevention of formation of acid drainage from high-sulfur coal refuse by inhibition of iron- and sulfur-oxidizing microorganisms. II. Inhibition in run of mine refuse under simulated field conditions; New York, NY [u.a.] : Wiley; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/7028.pdf; Opac |
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CBU @ c.wolke @ 7028 |
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80 |
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