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Conca, J.L.; Wright, J. |
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Title |
An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd |
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Journal Article |
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Year |
2006 |
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Appl. Geochem. |
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21 |
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12 |
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2188-2200 |
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Pollution and waste management non radioactive Groundwater quality apatite groundwater remediation zinc lead cadmium acid mine drainage copper sulfate nitrate permeability water treatment precipitation chemistry |
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Phosphate-induced metal stabilization involving the reactive medium Apatite II(TM) [Ca10-xNax(PO4)6-x(CO3)x(OH)2], where x < 1, was used in a subsurface permeable reactive barrier (PRB) to treat acid mine drainage in a shallow alluvial groundwater containing elevated concentrations of Zn, Pb, Cd, Cu, SO4 and NO3. The groundwater is treated in situ before it enters the East Fork of Ninemile Creek, a tributary to the Coeur d'Alene River, Idaho. Microbially mediated SO4 reduction and the subsequent precipitation of sphalerite [ZnS] is the primary mechanism occurring for immobilization of Zn and Cd. Precipitation of pyromorphite [Pb10(PO4)6(OH,Cl)2] is the most likely mechanism for immobilization of Pb. Precipitation is occurring directly on the original Apatite II. The emplaced PRB has been operating successfully since January of 2001, and has reduced the concentrations of Cd and Pb to below detection (2 μg L-1), has reduced Zn to near background in this region (about 100 μg L-1), and has reduced SO4 by between 100 and 200 mg L-1 and NO3 to below detection (50 μg L-1). The PRB, filled with 90 tonnes of Apatite II, has removed about 4550 kg of Zn, 91 kg of Pb and 45 kg of Cd, but 90% of the immobilization is occurring in the first 20% of the barrier, wherein the reactive media now contain up to 25 wt% Zn. Field observations indicate that about 30% of the Apatite II material is spent (consumed). |
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0883-2927 |
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Dec.; An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd; Science Direct |
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CBU @ c.wolke @ 17248 |
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44 |
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Ye, Z.H.; Whiting, S.N.; Qian, J.H.; Lytle, C.M.; Lin, Z.Q.; Terry, N. |
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Title |
Trace element removal from coal ash leachate by a 10-year-old constructed wetland |
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Journal Article |
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Year |
2001 |
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J. Environ. Qual. |
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30 |
Issue |
5 |
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1710-1719 |
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Keywords |
acid mine drainage; Alabama; ash; bioaccumulation; boron; cadmium; constructed wetlands; environmental analysis; environmental effects; iron; Jackson County Alabama; Juncus effusus; leachate; manganese; metals; pH; pollutants; pollution; remediation; soils; sulfur; trace elements; Typha latifolia; United States; vegetation; waste water; wetlands; Widows Creek; Widows Creek Steam Plant; zinc; Typha; Juncus 22, Environmental geology |
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This study investigated the ability of a 10-yr-old constructed wetland to treat metal-contaminated leachate emanating from a coal ash pile at the Widows Creek electric utility, Alabama (USA). The two vegetated cells, which were dominated by cattail (Typha latifolia L.) and soft rush (Juncus effusus L.), were very effective at removing Fe and Cd from the wastewater, but less efficient for Zn, S, B, and Mn. The concentrations were decreased by up to 99% for Fe, 91% for Cd, 63% for Zn, 61% for S, 58% for Mn, and 50% for B. Higher pH levels (>6) in standing water substantially improved the removing efficiency of the wetland for Mn only. The belowground tissues of both cattail and soft rush had high concentrations of all elements; only for Mn, however, did the concentration in the shoots exceed those in the belowground tissues. The concentrations of trace elements in fallen litter were higher than in the living shoots, but lower than in the belowground tissues. ne trace element accumulation in the plants accounted for less than 2.5% of the annual loading of each trace element into the wetland. The sediments were the primary sinks for the elements removed from the wastewater. Except for Mn, the concentrations of trace elements in the upper layer (0-5 cm) of the sediment profile tended to be higher than the lower layers (5-10 and 10-15 cm). We conclude that constructed wetlands are still able to efficiently remove metals in the long term (i.e., >10 yr after construction). |
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0047-2425 |
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Aug 1; Trace element removal from coal ash leachate by a 10-year-old constructed wetland; 2002-017274; References: 33; illus. incl. 2 tables United States (USA); file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/5703.pdf; GeoRef; English |
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CBU @ c.wolke @ 5703 |
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76 |
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Schwartz, M.O.; Ploethner, D. |
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From mine water to drinking water; heavy-metal removal by carbonate precipitation in the Grootfontein-Omatako Canal, Namibia |
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Book Chapter |
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1999 |
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Africa; aluminum; cadmium; canals; carbonates; copper; drinking water; geochemistry; Grootfontein-Omatako Canal; heavy metals; hydrochemistry; iron; lead; manganese; metallogenic provinces; metals; mine drainage; mineral deposits, genesis; mines; Namibia; policy; precipitation; purification; Southern Africa; transport; water management; water treatment 22, Environmental geology |
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Bundesanst. fuer Geowiss. und Rohstoffe |
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Hanover |
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From mine water to drinking water; heavy-metal removal by carbonate precipitation in the Grootfontein-Omatako Canal, Namibia; GeoRef; English; 2002-033925; International congress on Mine, water and environment, Seville, Spain, Sept. 13, 1999 References: 7; 2 tables, sketch maps |
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CBU @ c.wolke @ 5929 |
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250 |
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Kuyucak, N. |
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Title |
Acid mine drainage; treatment options for mining effluents |
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Journal Article |
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2001 |
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Mining Environmental Management |
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9 |
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2 |
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12-15 |
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acid mine drainage; alkalinity; cadmium; chemical reactions; copper; cyanides; decontamination; degradation; effluents; flotation; heavy metals; lead; lime; metals; mines; nickel; oxidation; pH; physicochemical properties; pollution; reagents; reduction; remediation; seepage; sludge; solid waste; solvents; stability; tailings; toxic materials; toxicity; waste disposal; water quality; zinc |
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0969-4218 |
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Acid mine drainage; treatment options for mining effluents; 2001-050827; References: 23; illus. United Kingdom (GBR); GeoRef; English |
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CBU @ c.wolke @ 5723 |
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324 |
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Boonstra, J.; van Lier, R.; Janssen, G.; Dijkman, H.; Buisman, C.J.N. |
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Title |
Biological treatment of acid mine drainage |
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Book Chapter |
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1999 |
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Process Metallurgy, vol.9, Part B |
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559-567 |
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acid mine drainage adsorption alkaline earth metals arsenic Bingham Canyon Mine bioremediation Budelco Zinc Refinery cadmium copper Cornwall England England Europe Great Britain heavy metals iron magnesium manganese metals Netherlands pH phase equilibria pollution remediation sulfate ion United Kingdom United States Utah Western Europe Wheal Jane Mine zinc 22, Environmental geology |
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Amils, R.; Ballester, A. |
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Biohydrometallurgy and the environment toward the mining of the 21st century; proceedings of the International biohydrometallurgy symposium IBS'99, Part B, Molecular biology, biosorption, bioremediation |
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0444501932 |
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Biological treatment of acid mine drainage; GeoRef; English; 2000-049809; International biohydrometallurgy symposium IBS'99, Madrid, Spain, June 20-23, 1999 References: 11; illus. incl. 5 tables |
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CBU @ c.wolke @ 16595 |
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442 |
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