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Eger, P.; Melchert, G.; Wagner, J. |
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Title |
Using passive treatment systems for mine closure – A good approach or a risky alternative? |
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Journal Article |
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Year |
2000 |
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Min. Eng. |
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52 |
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9 |
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78-83 |
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Pollution and waste management non radioactive Groundwater problems and environmental effects geological abstracts: environmental geology (72 14 2) geomechanics abstracts: excavations (77 10 10) acid mine drainage decommissioning mine waste open pit mine pH remediation |
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In 1991, LTV Steel Mining decided to close an open-pit taconite mine in northeastern Minnesota using a passive-treatment approach consisting of limiting infiltration into the stockpiles and wetland treatment to remove metals. More than 50 Mt (55 million st) of sulfide-containing waste had been stockpiled adjacent to the mine during its 30 years of operation. Drainage from the stockpiles contained elevated levels of copper, nickel, cobalt and zinc. Nickel is the major trace metal in the drainages. Before the closure, the annual median concentrations ranged from 1.5 to 50 mg/L. Copper, cobalt and zinc are also present but they are generally less than 5% of the nickel values. Median pH levels range from 5 to 7.5, but most of the stockpile drainages have pH levels greater than 6.5. Based on the chemical composition of each stockpile, a cover material was selected. The higher the potential that a stockpile had to produce acid drainage, the lower the permeability of the capping material required. Covers ranged from overburden soil removed at the mine to a flexible plastic liner. Predictions of the reduction in infiltration ranged from 40% for the native soil to more than 90% for the plastic liner. Five constructed wetlands have been installed since 1992. They have removed 60% to 90% of the nickel in the drainages. Total capital costs for all the infiltration reduction and wetlands exceeded $6.5 million, but maintenance costs are less than 1% of those for an active treatment plant. Because mine-drainage problems can continue for more than 100 years, the lower annual operating costs should pay for the construction of the wetland-treatment systems within seven years. |
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P. Eger, Minnesota Dept. of Natural Rsrces., St. Paul, MN, United States |
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0026-5187 |
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Using passive treatment systems for mine closure – A good approach or a risky alternative?; 2285715; United-States 19; Geobase |
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CBU @ c.wolke @ 17539 |
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392 |
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Author |
Eger, P.; Melchert, G.; Antonson, D.; Wagner, J. |
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Title |
Magnesium hydroxide as a treatment for acid mine drainage in northern Minnesota |
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Book Chapter |
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Year |
1993 |
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Proceedings of the Annual National Meeting – American Society for Surface Mining and Reclamation, vol.10 |
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204-217 |
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acid mine drainage acidification alkaline earth metals chemical properties cobalt copper drainage experimental studies hydroxides laboratory studies lime magnesium magnesium hydroxide metals Minnesota nickel northern Minnesota oxides pH pollution porous materials reagents remediation residence time trace metals United States waste disposal zinc 22, Environmental geology |
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Abstract |
Three alkaline materials were investigated for their suitability to treat acid mine drainage generated by a research facility located at a remote site in northern Minnesota. The materials investigated were hydrated lime, sodium hydroxide, and magnesium hydroxide. All three reagents were successful at raising pH and removing trace metals from the drainage, but the magnesium hydroxide had the added benefit of producing a maximum pH of approximately 9.5, while the other two reagents resulted in pH values of 12 and greater. In addition, the magnesium hydroxide was available as a high solid content slurry (58%) which simplified application and handling, and which produced the lowest volume of sludge of the materials tested. |
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Zamora, B.A.; Connolly, R.E. |
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The challenge of integrating diverse perspectives in reclamation |
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Magnesium hydroxide as a treatment for acid mine drainage in northern Minnesota; GeoRef; English; 2002-028930; 10th annual national meeting of the American Society for Surface Mining and Reclamation, Spokane, WA, United States, May 16, 1993 References: 7; illus. incl. 4 tables |
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CBU @ c.wolke @ 16743 |
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393 |
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Chironis, N.P. |
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Title |
Mine-built ponds economically clear acid mine waters |
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1987 |
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Coal Age |
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1 |
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58-61 |
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Biologische-Abwasserreinigung Waessrige-Loesung Industrieabwasser Pflanze Gewaesser Ph-Wert Abwasserbehandlung Saeure Buntmetalle Grubenwasser |
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Bestimmte Wasserpflanzen in Teichen können Metalle aus sauren Grubenwässern binden durch Adsorption, Filtration und Einlagerung in Wurzeln und Blättern. Algen und oxydierende Bakterien unterstützen diesen Reinigungsprozeß. Angaben zur Anlage der Teiche: Durchflußkapazität 20 l/min bis 38 l/min, Spülung von 18 m(exp 2) pro 4 l Durchflußmenge, Wasserhöhe 5 cm bis 10 cm, der pH-Wert des austretenden Wassers ist größer als 4,0. |
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Mine-built ponds economically clear acid mine waters; 316, BERG , 01.01.87; Words: 257; U8712 3772 586; 3 Bilder, 3 Quellen 3UXX *Belastung von Wasser, Wasserreinhaltung, Abwasser* 3UMB *Abfallstoffe, behandlung, vermeidung, verwertung, wirtschaft* 3PZ *Bioverfahrenstechnik, Biotechnologie*; BERG, Copyright FIZ Technik e.V.; EN Englisch |
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CBU @ c.wolke @ 17616 |
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418 |
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Carlson, L.; Kumpulainen, S. |
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Retention of harmful elements by ochreous precipitates of iron |
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2001 |
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Tutkimusraportti Geologian Tutkimuskeskus |
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154 |
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30-33 |
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Surface water quality Pollution and waste management non radioactive geographical abstracts: physical geography hydrology (71 6 9) geological abstracts: environmental geology (72 14 2) iron oxide precipitation chemistry sulfate arsenate heavy metal pH water pollution remediation |
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The capability of soil fines to fix harmful elements, e.g. heavy metals and arsenic, depends on specific surface area and other characteristics, such as surface charge. In the pH-range typical of natural waters (pH 5,5-7,5), the surfaces of fine-grained silicate particles and manganese oxides are negatively charged; consequently cations, such as heavy metals, fix effectively to them. The iron oxide surfaces are usually positively charged and typically fix anions, such as sulphate and arsenate. Retention of anions is especially extensive to precipitates formed from acid mine drainage (pH 2,5-5,0). For example, precipitates found at Paroistenjarvi mine, Finland, contain more than 70 g/kg of arsenic (dry matter). Adsorbed anions, e.g. sulphate, enhance the capacity of precipitate to fix heavy metal cations in low-pH environments. |
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L. Carlson, Tehtaankatu 25 A 4, Helsinki FIN-00150, Finland liisa.carlson@kolumbus.fi |
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0781-4240 |
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Retention of harmful elements by ochreous precipitates of iron; 2392974; Oksidiset rautasaostumat haitallisten aineiden pidattajina. Finland 7; Geobase |
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CBU @ c.wolke @ 17533 |
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421 |
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Author |
Camus, M. |
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Le traitement des eaux de mine desaffectees. Die Aufbereitung von Wässern aus stillgelegten Bergwerken. Treating water from closed mines |
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1997 |
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Mines et Carrieres |
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Feb |
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38-39 |
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Erzbergbau Frankreich Blei Silber Zink Eisen pH-Wert Quellwasser Flusswasserverschmutzung Wasseraufbereitungsanlage chemische- Abwasserreinigung chemische-Reaktion Kennziffer Wirkungsgrad chemische-Analyse Fließbild Belüftung Ausflocken Neutralisation=chemische-Reaktion Grubenwasserreinigung |
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In einem alten französischen Bergwerk, in dem früher Blei und Silber abgebaut wurden, kam es nach dem Wiederanstieg des Grundwassers zu einer erhöhten Schwermetallbelastung von Quellgebieten, die einen Fluß mit Forellenbesatz schädigten. Zur Beseitigung dieser Grundwasserverunreinigung wurde das saure Grubenwasser mit erhöhten Eisen- und Zinkgehalten übertage gefaßt und einer Wasseraufbereitung unterzogen. In der für einen Durchsatz von 100 m(exp 3)/h konzipierten Wasseraufbereitung wurden die Schadstoffbestandteile durch Oxidation und anschließende Neutralisation mit Kalk (Anhebung des pH-Wertes auf 8,2 bis 8,3) gefällt, durch Zugabe eines Flockungsmittels gebunden und die Schlammbestandteile anschließend einem Eindicker und Filterpressen zugeführt. Der Kalkverbrauch wird mit 240 kg/d angegeben. Die tabellarisch zusammengestellten Analysenergebnisse zeigen, daß die Wasseraufbereitung einen sehr guten Wirkungsgrad hatte. Neben einer Anhebung des pH-Wertes von 6,5 auf 8,2 konnten die Schwermetallgehalte bei Fe von 22 mg/l auf 0,09 mg/l und bei Zn von 38 mg/l auf 0,4 mg/l abgesenkt werden. |
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Le traitement des eaux de mine desaffectees. Die Aufbereitung von Wässern aus stillgelegten Bergwerken. Treating water from closed mines; 13313, BERG , 30.04.97; Words: 501; U9705 0024 586; 2 Seiten, 1 Bild, 1 Tabelle 3UM *Umweltschadstoffe, toxikologie* 3UX *Umweltbelastung, technik* 3MZ *Bergbau, Tunnelbau, Erdöl /Erdgasförderung, Bohrtechnik* 3PL *chemische Verfahrenstechnik, chemische Reaktionstechnik*; BERG, Copyright FIZ Technik e.V.; FR Französisch |
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CBU @ c.wolke @ 17601 |
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424 |
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