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Author |
Brooks, R.P.; Unz, R.F.; Davis, L.K.; Tarutis, W.J.; Yanchunas, J. |
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Title |
Long-term removal and retention of iron and manganese from acidic mine drainage by wetlands |
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Journal Article |
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Year |
1990 |
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147 |
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Acid mine drainage Wetlands Biological treatment Iron removal Manganese removal |
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Abstract |
A promising low-technology solution for treating acidic mine drainage (AMD) emanating from coal mined lands involves the use of constructed wetlands.^The research was directed at addressing questions about retention mechanisms for the long-term storage of iron and manganese in constructed wetlands dominated by broad-leaved cattails (Typha latifolia).^Three sites in central Pennsylvania spanning the range of water chemistry parameters found in AMD were investigated.^When the AMD was circumneutral, and metal loadings were low, 79% of the iron, and 48% of the manganese were retained on average.^In the highly acidic site (pH approx.^= 3), < 10% of the metal loadings were retained.^The primary retention mechanism appears to be the formation of metal oxides in the aerobic zones of the sediments.^Although most microbial isolates extracted from sediment cores originated in the aerobic portions of the sediments, there was no evidence that they were transforming metals.^When AMD is circumneutral and metal loadings are low, constructed wetlands can be an effective approach to treating mine drainage.^At sites with highly acidic waters and high metal loadings, the use of constructed wetlands to treat AMD may be ineffectual, and should be implemented with caution. |
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Long-term removal and retention of iron and manganese from acidic mine drainage by wetlands; Springfield, Va. : NTIS; Opac |
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CBU @ c.wolke @ 7082 |
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435 |
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Author |
Banks, S.B. |
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Title |
The Coal Authority Minewater Treatment Programme: An update on the performance of operational schemes |
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Journal Article |
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2003 |
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Land Contam. Reclam. |
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11 |
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2 |
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161-164 |
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Wetlands and estuaries Groundwater problems and environmental effects Pollution and waste management non radioactive geographical abstracts: physical geography hydrology (71 6 8) geomechanics abstracts: excavations (77 10 10) geological abstracts: environmental geology (72 14 2) constructed wetland mine drainage water treatment pollutant removal United Kingdom |
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The performance of mine water treatment schemes, operated under the Coal Authority's national Minewater Treatment Programme, is summarised. Most schemes for which data are available perform successfully and remove over 90% iron. Mean area-adjusted iron removal rates for reedbed components of treatment schemes, range from 1.5 to 5.5 g Fe/m2, with percentage iron removal rates ranging from 68% to 99%. In the majority of cases, calculated area-adjusted removal rates are limited by influent iron loadings, and the empirical sizing criterion for aerobic wetlands, based on American removal rates of 10 g Fe/m2day, remains a valuable tool in the initial stages of treatment system design and estimation of land area requirements. Where a number of schemes have required modification after becoming operational, due consideration must always be given to the potential for dramatic increases in influent iron loadings, and to how the balance between performance efficiency and aesthetic appearance can best be achieved. Continual review and feedback on the performance of treatment systems, and the problems encountered during design implementation, will enhance the efficiency and effectiveness of the Minewater Treatment Programme within the UK. |
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S.B. Banks, Scott Wilson Kirkpatrick/Co. Ltd., Rose Hill West, Chesterfield S40 1JF, United Kingdom |
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0967-0513 |
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The Coal Authority Minewater Treatment Programme: An update on the performance of operational schemes; 2530421; United-Kingdom 4; Geobase |
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CBU @ c.wolke @ 17519 |
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467 |
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Barton, C.D.; Karathanasis, A.D. |
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Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage |
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Book Chapter |
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1997 |
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AAPG Eastern Section and the Society for Organic Petrology joint meeting; abstracts |
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1545 |
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acid mine drainage aerobic environment air-water interface anaerobic environment attenuation buffers constructed wetlands controls diffusion iron manganese metals mineral composition pollution precipitation processes SEM data solubility solution sulfate ion sulfur wetlands X-ray diffraction data 22, Environmental geology |
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The use of constructed wetlands for acid mine drainage amelioration has become a popular alternative to conventional treatment methods, however, the metal attenuation processes of these systems are poorly understood. Precipitates from biotic and abiotic zones of a staged constructed wetland treating high metal load (approx. equal to 1000 mg L (super -1) ) and low pH (approx. 3.0) acid mine drainage were characterized by chemical dissolution, x-ray diffraction, thermal analysis and scanning electron microscopy. Characterization of abiotic/aerobic zones within the treatment system suggest the presence of crystalline iron oxides and hydroxides such as hematite, lepidocrocite, goethite, and jarosite. At the air/water interface of initial abiotic treatment zones, SO (sub 4) /Fe ratios were low enough (<2.0) for the formation of jarosite and goethite, but as the ratio increased due to treatment and subsequent reductions in iron concentration, jarosite was transformed to other Fe-oxyhydroxysulfates and goethite formation was inhibited. In addition, elevated pH conditions occurring in the later stages of treatment promoted the formation of amorphous iron oxyhydroxides. Biotic wetland cell substrate characterizations suggest the presence of amorphous iron minerals such as ferrihydrite and Fe(OH) (sub 3) . Apparently, high Fe (super 3+) activity, low Eh and low oxygen diffusion rates in the anaerobic subsurface environment inhibit the kinetics of crystalline iron precipitation. Some goethite, lepidocrocite and hematite, however, were observed near the surface in biotic areas and are most likely attributable to increased oxygen levels from surface aeration and/or oxygen transport by plant roots. Alkalinity generation from limestone dissolution within the substrate and bacterially mediated sulfate reduction also has a significant role on the mineral retention process. The formation of gypsum, rhodochrocite and siderite are by-products of alkalinity generating reactions in this system and may have an impact on S, Mn, and Fe solubility controls. Moreover, the buffering of acidity through excess alkalinity appears to facilitate the precipitation and retention of metals within the system. |
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AAPG Bulletin |
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81 |
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Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage; GeoRef; English; 1997-067790; AAPG Eastern Section and the Society for Organic Petrology joint meeting, Lexington, KY, United States, Sep. 27-30, 1997 |
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CBU @ c.wolke @ 16630 |
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70 |
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Author |
Kleinmann, R.L.P. |
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Title |
Biological treatment of acid mine water using engineered wetlands |
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Journal Article |
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1990 |
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acid mine drainage; biodegradation; natural resources; reclamation; surface water; wetlands 22, Environmental geology |
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Annual Meeting - Association of Engineering Geologists |
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Engineering geology for the 90's |
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1991-006081; Association of Engineering Geologists, 33rd annual meeting; Engineering geology for the 90's, Pittsburgh, PA, United States, Oct. 1-5; GeoRef; English |
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CBU @ c.wolke @ 6736 |
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329 |
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Author |
Gusek, J.J.; Wildeman, T.R. |
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Title |
New developments in passive treatment of acid rock drainage Pollution prevention for process engineering |
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Book Chapter |
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Year |
1995 |
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acid mine drainage; aerobic environment; alkalinity; bioaccumulation; bioremediation; constructed wetlands; decontamination; disposal barriers; geomembranes; heavy metals; hydroxides; nutrients; oxides; pH; physical properties; pollution; reclamation; remediation; soils; tailings; techniques; toxic materials; vegetation; waste disposal; water quality; wetlands 22, Environmental geology |
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Engineering Foundation |
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New York |
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Richardson, P.E.; Scheiner, B.J.; Lanzetta, F., Jr. |
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0939204533 |
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New developments in passive treatment of acid rock drainage Pollution prevention for process engineering; GeoRef; English; 2000-063657; Engineering Foundation conference on Technical solution for pollution prevention in the mining and mineral processing industries, Palm Coast, FL, United States, Jan. 22-27, 1995 References: 3; illus. incl. 1 table |
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CBU @ c.wolke @ 6447 |
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363 |
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