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Van Hille, R.P.; Boshoff, G.A.; Rose, P.D.; Duncan, J.R. |
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A continuous process for the biological treatment of heavy metal contaminated acid mine water |
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Year |
1999 |
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Resour. Conserv. Recycl. |
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27 |
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1-2 |
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157-167 |
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mine water treatment biological treatment heavy metal acid mine water alkaline precipitation green-algae chlorella |
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Abstract |
Alkaline precipitation of heavy metals from acidic water streams is a popular and long standing treatment process. While this process is efficient it requires the continuous addition of an alkaline material, such as lime. In the long term or when treating large volumes of effluent this process becomes expensive, with costs in the mining sector routinely exceeding millions of rands annually. The process described below utilises alkalinity generated by the alga Spirulina sp., in a continuous system to precipitate heavy metals. The design of the system separates the algal component from the metal containing stream to overcome metal toxicity. The primary treatment process consistently removed over 99% of the iron (98.9 mg/l) and between 80 and 95% of the zinc (7.16 mg/l) and lead (2.35 mg/l) over a 14-day period (20 l effluent treated). In addition the pH of the raw effluent was increased from 1.8 to over 7 in the post-treatment stream. Secondary treatment and polishing steps depend on the nature of the effluent treated. In the case of the high sulphate effluent the treated stream was passed into an anaerobic digester at a rate of 4 l/day. The combination of the primary and secondary treatments effected a removal of over 95% of all metals tested for as well as a 90% reduction in the sulphate load. The running cost of such a process would be low as the salinity and nutrient requirements for the algal culture could be provided by using tannery effluent or a combination of saline water and sewage. This would have the additional benefit of treating either a tannery or sewage effluent as part of an integrated process. |
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0921-3449 |
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Jul; A continuous process for the biological treatment of heavy metal contaminated acid mine water; Isi:000081142100017; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/9937.pdf; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 9937 |
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26 |
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Dugan, P.R. |
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Prevention of formation of acid drainage from high-sulfur coal refuse by inhibition of iron- and sulfur-oxidizing microorganisms. II. Inhibition in run of mine refuse under simulated field conditions |
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Journal Article |
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1987 |
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Biotechnol. Bioeng. |
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29 |
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1 |
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6 |
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mine water treatment Chemistry Biochemistry and Biotechnology |
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0006-3592 |
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Jan; Prevention of formation of acid drainage from high-sulfur coal refuse by inhibition of iron- and sulfur-oxidizing microorganisms. II. Inhibition in run of mine refuse under simulated field conditions; New York, NY [u.a.] : Wiley; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/7028.pdf; Opac |
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CBU @ c.wolke @ 7028 |
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80 |
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Stewart, D.; Norman, T.; Cordery-Cotter, S.; Kleiner, R.; Sweeney, E.; Nelson, J.D. |
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Utilization of a ceramic membrane for acid mine drainage treatment |
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1997 |
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Tailings and Mine Waste '97 |
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453-460 |
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acid mine drainage; Black Hawk Colorado; Central City Colorado; ceramic materials; Colorado; cost; disposal barriers; geochemistry; Gilpin County Colorado; heavy metals; mines; organic compounds; pollution; remediation; surface water; tailings; United States; utilization; volatile organic compounds; volatiles; waste disposal mine water treatment |
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BASX Systems LLC has developed a treatment system based on ceramic membranes for the removal of heavy metals from an acid mine drainage stream. This stream also contained volatile organic compounds that were required to be removed prior to discharge to a Colorado mountain stream. The removal of heavy metals was greater than 99% in most cases. A decrease of 30% in chemicals required for treatment and a reduction by more than 75% in labor over a competing technology were achieved. These decreases were obtained for operating temperatures of less than 5 degrees C. This system of ceramic microfiltration is capable of treating many different types of acid mine waste streams for heavy metals removal. |
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90-5410-857-6 |
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Jan 13-17; Utilization of a ceramic membrane for acid mine drainage treatment; Isip:A1997bg96u00050; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 8744 |
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135 |
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Groudev, S.N.; Georgiev, P.S.; Spasova, I.I.; Nicolova, M.N. |
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Title |
In situ treatment of mine waters by means of a permeable barrier |
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2000 |
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Groundwater 2000 |
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417-418 |
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mine water treatment |
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Acid ground waters contaminated with radioactive elements (U, Ra, Th), toxic heavy metals (Cu, Zn, Cd, Mn, Fe), arsenic and sulphates were treated by means of a permeable barrier. The barrier was filled with a mixture of biodegradable solid organic substrates (spent mushroom compost, sawdust and cow manure) and was inhabited by a mixed microbial community consisting of sulphate-reducing bacteria and other metabolically interdependent microorganisms. An efficient removal of the pollutants was achieved by this barrier during the different climatic seasons, even at ambient temperatures close to degrees C. The microbial dissimilatory sulphate reduction and the sorption of pollutants by the organic matter in the barrier were the main processes involved in this removal. |
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In situ treatment of mine waters by means of a permeable barrier; Isip:000088384300185; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 8407 |
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173 |
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Author |
Harrington, J.M. |
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Title |
In situ treatment of metals in mine workings and materials |
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Journal Article |
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Year |
2002 |
Publication |
Tailings and Mine Waste '02 |
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251-261 |
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mine water treatment |
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Contact of oxygen contained in air and water with mining materials can increase the solubility of metals. In heaps leached by cyanide, metals can also be made soluble through complexation with cyanide. During closure, water in heaps, and water collected in mine workings and pit lakes may require treatment to remove these metals. In situ microbiological treatment to create reductive conditions and to precipitate metals as sulfides or elemental metal has been applied at several sites with good success. Treatment by adding organic carbon to stimulate in situ microbial reduction has been successful in removing arsenic, cadmium, chromium, copper, iron, lead, manganese, mercury, nickel, selenium, silver, tin, uranium, and zinc to a solid phase. Closure practices can affect the success of in situ treatment at mining sites, and affect the stability of treated materials. This paper defines factors that determine the cost and permanence of in situ treatment. |
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In situ treatment of metals in mine workings and materials; Isip:000175560600034; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 17037 |
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161 |
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