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Bowell, R.J.; Connelly, R.J.; Ellis, J.; Cowan, J.; Wood, A.; Barta, J.; Edwards, P. |
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Title |
A review of sulfate removal options from mine waters |
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Journal Article |
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1997 |
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acid mine drainage; bacteria; bioremediation; decontamination; effluents; ground water; legislation; osmosis; oxidation; pollutants; pollution; remediation; reverse osmosis; selenites; sulfate ion; toxic materials; USGS; water treatment 22 Environmental geology; 02A General geochemistry |
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Open-File Report - U. S. Geological Survey, Report: OF 97-0496 |
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4th International symposium on Environmental geochemistry; proceedings |
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1998-068727; 4th International symposium on Environmental geochemistry, Vail, CO, United States, Oct. 5-10, 1997 U. S. Geol. Surv., Denver, CO, United States; GeoRef; English |
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CBU @ c.wolke @ 6287 |
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438 |
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Author |
Skousen, J. |
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Title |
Overview of passive systems for treating acid mine drainage |
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Journal Article |
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1997 |
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Green Lands |
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27 |
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4 |
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34-43 |
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acid mine drainage; anoxic limestone drains; bioremediation; constructed wetlands; diversion wells; limestone ponds; mitigation; open limestone channels; passive systems; pollution; remediation; successive alkalinity producing systems; technology; wetlands 22, Environmental geology |
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0271-0110 |
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Overview of passive systems for treating acid mine drainage; 2000-019214; References: 59; illus. United States (USA); GeoRef; English |
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CBU @ c.wolke @ 6309 |
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247 |
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Younger, P.L.; Neal, C.; House, W.A.; Leeks, G.J.L.; Marker, A.H. |
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The longevity of minewater pollution; a basis for decision-making U.K. fluxes to the North Sea; Land Ocean Interaction Study (LOIS); river basins research, the first two years |
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Journal Article |
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1997 |
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The Science of the Total Environment |
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194-195 |
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457-466 |
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acid mine drainage; acidic composition; acidification; Cornwall England; decision-making; degradation; discharge; England; Europe; Great Britain; hydrolysis; mines; planning; pollutants; pollution; remediation; retention; Scotland; soils; surface water; United Kingdom; Wales; waste disposal; water quality; Western Europe 22, Environmental geology |
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0048-9697 |
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The longevity of minewater pollution; a basis for decision-making U.K. fluxes to the North Sea; Land Ocean Interaction Study (LOIS); river basins research, the first two years; 1997-078352; Special issue References: 30; illus. Netherlands (NLD); GeoRef; English |
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CBU @ c.wolke @ 6259 |
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193 |
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Benner, S.G.; Blowes, D.W.; Ptacek, C.J. |
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A full-scale porous reactive wall for prevention of acid mine drainage |
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1997 |
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Ground Water Monitoring and Remediation |
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17 |
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4 |
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99-107 |
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acid mine drainage alkalinity bacteria Canada case studies concentration dissolved materials drainage Eastern Canada ground water mines observation wells Ontario permeability pH pollution porous materials recharge reduction remediation site exploration Sudbury District Ontario sulfate ion surface water waste disposal water pollution Groundwater quality Groundwater problems and environmental effects Pollution and waste management non radioactive geographical abstracts: physical geography hydrology (71 6 11) geomechanics abstracts: excavations (77 10 10) geological abstracts: environmental geology (72 14 2) groundwater protection permeable barrier acid mine drainage aquifer groundwater acid min drainage contamination permeable barrier groundwater protection permeable barrier acid mine drainage aquifer Canada, Ontario, Sudbury, Nickel Rim |
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Abstract |
The generation and release of acidic drainage containing high concentrations of dissolved metals from decommissioned mine wastes is an environmental problem of international scale. A potential solution to many acid drainage problem is the installation of permeable reactive walls into aquifers affected by drainage water derived from mine waste materials. A permeable reactive wall installed into an aquifer impacted by low-quality mine drainage waters was installed in August 1995 at the Nickel Rim mine site near Sudbury, Ontario. The reactive mixture, containing organic matter, was designed to promote bacterially mediated sulfate reduction and subsequent metal sulfide precipitation. The reactive wall is installed to an average depth of 12 feet (3.6 m) and is 49 feet (15 m) long perpendicular to ground water flow. The wall thickness (flow path length) is 13 feet (4 m). Initial results, collected nine months after installation, indicate that sulfate reduction and metal sulfide precipitation is occurring. Comparing water entering the wall to treated water existing the wall, sulfate concentrations decrease from 2400 to 4600 mg/L to 200 to 3600 mg/L; Fe concentration decrease from 250 to 1300 mg/L to 1.0 to 40 mg/L, pH increases from 5.8 to 7.0; and alkalinity (as CaCO<inf>3</inf>) increases from 0 to 50 mg/L to 600 to 2000 mg/L. The reactive wall has effectively removed the capacity of the ground water to generate acidity on discharge to the surface. Calculations based on comparison to previously run laboratory column experiments indicate that the reactive wall has potential to remain effective for at least 15 years. |
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Dr. S.G. Benner, Earth Sciences Department, University of Waterloo, Waterloo, Ont. N2L 3G1, Canada |
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1069-3629 |
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Review; A full-scale porous reactive wall for prevention of acid mine drainage; 0337197; United-States 46; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10621.pdf; Geobase |
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CBU @ c.wolke @ 17555 |
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67 |
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Author |
Barton, C.D.; Karathanasis, A.D. |
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Title |
Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage |
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Book Chapter |
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Year |
1997 |
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AAPG Eastern Section and the Society for Organic Petrology joint meeting; abstracts |
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1545 |
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acid mine drainage aerobic environment air-water interface anaerobic environment attenuation buffers constructed wetlands controls diffusion iron manganese metals mineral composition pollution precipitation processes SEM data solubility solution sulfate ion sulfur wetlands X-ray diffraction data 22, Environmental geology |
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Abstract |
The use of constructed wetlands for acid mine drainage amelioration has become a popular alternative to conventional treatment methods, however, the metal attenuation processes of these systems are poorly understood. Precipitates from biotic and abiotic zones of a staged constructed wetland treating high metal load (approx. equal to 1000 mg L (super -1) ) and low pH (approx. 3.0) acid mine drainage were characterized by chemical dissolution, x-ray diffraction, thermal analysis and scanning electron microscopy. Characterization of abiotic/aerobic zones within the treatment system suggest the presence of crystalline iron oxides and hydroxides such as hematite, lepidocrocite, goethite, and jarosite. At the air/water interface of initial abiotic treatment zones, SO (sub 4) /Fe ratios were low enough (<2.0) for the formation of jarosite and goethite, but as the ratio increased due to treatment and subsequent reductions in iron concentration, jarosite was transformed to other Fe-oxyhydroxysulfates and goethite formation was inhibited. In addition, elevated pH conditions occurring in the later stages of treatment promoted the formation of amorphous iron oxyhydroxides. Biotic wetland cell substrate characterizations suggest the presence of amorphous iron minerals such as ferrihydrite and Fe(OH) (sub 3) . Apparently, high Fe (super 3+) activity, low Eh and low oxygen diffusion rates in the anaerobic subsurface environment inhibit the kinetics of crystalline iron precipitation. Some goethite, lepidocrocite and hematite, however, were observed near the surface in biotic areas and are most likely attributable to increased oxygen levels from surface aeration and/or oxygen transport by plant roots. Alkalinity generation from limestone dissolution within the substrate and bacterially mediated sulfate reduction also has a significant role on the mineral retention process. The formation of gypsum, rhodochrocite and siderite are by-products of alkalinity generating reactions in this system and may have an impact on S, Mn, and Fe solubility controls. Moreover, the buffering of acidity through excess alkalinity appears to facilitate the precipitation and retention of metals within the system. |
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AAPG Bulletin |
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81 |
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Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage; GeoRef; English; 1997-067790; AAPG Eastern Section and the Society for Organic Petrology joint meeting, Lexington, KY, United States, Sep. 27-30, 1997 |
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Call Number |
CBU @ c.wolke @ 16630 |
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70 |
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