| |
Records |
Links |
|
Author |
Totsche, O.; Fyson, A.; Kalin, M.; Steinberg Christian, E.W. |
|
| |
Title |
Titration curves: A useful instrument for assessing the buffer systems of acidic mining waters |
Type |
Journal Article |
| |
Year |
2006 |
Publication |
ESPR Environmental Science and Pollution Research |
Abbreviated Journal |
|
|
| |
Volume |
13 |
Issue |
4 |
Pages |
215-224 |
|
| |
Keywords |
Abwasseraufbereitung Bergbau Titration Säuregehalt Grundwasser Pufferlösung Neutralisation Titrationskurve Bergbauabwasser |
|
| |
Abstract |
The acidification of mine waters is generally caused by metal sulfide oxidation, related to mining activities. These waters are characterized by low pH and high acidity due to strong buffering systems. The standard acidity parameter, the BNC (Base Neutralization Capacity), is determined by endpoint titration, and reflects a cumulative parameter of both hydrogen ions and all buffering systems, but does not give information on the individual buffer systems. It is demonstrated that a detailed interpretation of titration curves can provide information about the strength of the buffering systems. The buffering systems are of importance for environmental studies and treatment of acidic mining waters. Titrations were carried out by means of an automatic titrator using acidic mining waters from Germany and Canada. The curves were interpreted, compared with each other, to endpoint titration results and to elemental concentrations contained therein. The titration curves were highly reproducible, and contained information about the strength of the buffer systems present. Interpretations are given, and the classification and comparison of acidic mining waters, by the nature and strength of their buffering systems derived from titration curves are discussed. The BNC-values calculated from the curves were more precise than the ones determined by the standard endpoint titration method. Due to the complex buffer mechanisms in acidic mining waters, the calculation of major metal concentrations from the shape of the titration curve resulted in estimates, which should not be confused with precise elemental analysis results. Conclusion. Titration curves provide an inexpensive, valuable and versatile tool, by which to obtain sophisticated information of the acidity in acidic water. The information about the strength of the present buffer systems can help to understand and document the complex nature of acidic mining water buffer systems. Finally, the interpretation of titration curves could help to improve treatment measurements and the ecological understanding of these acidic waters. |
|
| |
Address |
Leibniz-Institut für Gewässerökologie und Binnenfischerei, Berlin, DE; Boojum Research, Toronto, CA; Humboldt-Universität Berlin, DE |
|
| |
Corporate Author |
|
Thesis |
|
|
| |
Publisher |
|
Place of Publication |
|
Editor |
|
|
| |
Language |
|
Summary Language |
|
Original Title |
|
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN  |
0944-1344 |
ISBN |
|
Medium |
|
|
| |
Area |
|
Expedition |
|
Conference |
|
|
| |
Notes |
Titration curves: A useful instrument for assessing the buffer systems of acidic mining waters; 39481, BERG , 13.11.06; Words: 519; 200610 05282; 10 Seiten, 15 Bilder, 2 Tabellen, 39 Quellen 3UXX *Belastung von Wasser, Wasserreinhaltung, Abwasser* 3BX *chemische Grundlagen* 3IFC *Messung und Prüfung chemischer Größen, chemische Analytik* 3MZ *Bergbau, Tunnelbau, Erdöl /Erdgasförderung, Bohrtechnik*; BERG, Copyright FIZ Technik e.V.; EN Englisch |
Approved |
no |
|
| |
Call Number |
CBU @ c.wolke @ 17580 |
Serial |
224 |
|
| Permanent link to this record |
| |
|
| |
|
Author |
Banks, D.; Younger, P.L.; Arnesen, R.-T.; Iversen, E.R.; Banks, S.B. |
|
| |
Title |
Mine-water chemistry: The good, the bad and the ugly |
Type |
Journal Article |
| |
Year |
1997 |
Publication |
Environ. Geol. |
Abbreviated Journal |
|
|
| |
Volume |
32 |
Issue |
3 |
Pages |
157-174 |
|
| |
Keywords |
mine water treatment mine-water chemistry acid mine drainage mine-water pollution mine-water treatment county-durham drainage movements Pollution and waste management non radioactive Groundwater problems and environmental effects mine drainage contamination hydrogeochemistry mine water drainage acid mine drainage |
|
| |
Abstract |
Contaminative mine drainage waters have become one of the major hydrogeological and geochemical problems arising from mankind's intrusion into the geosphere. Mine drainage waters in Scandinavia and the United Kingdom are of three main types: (1) saline formation waters; (2) acidic, heavy-metal-containing, sulphate waters derived from pyrite oxidation, and (3) alkaline, hydrogen-sulphide-containing, heavy-metal-poor waters resulting from buffering reactions and/or sulphate reduction. Mine waters are not merely to be perceived as problems, they can be regarded as industrial or drinking water sources and have been used for sewage treatment, tanning and industrial metals extraction. Mine-water problems may be addressed by isolating the contaminant source, by suppressing the reactions releasing contaminants, or by active or passive water treatment. Innovative treatment techniques such as galvanic suppression, application of bactericides, neutralising or reducing agents (pulverised fly ash-based grouts, cattle manure, whey, brewers' yeast) require further research. |
|
| |
Address |
D. Banks, Norges Geologiske Undersokelse, Postboks 3006 – Lade, N-7002 Trondheim, Norway |
|
| |
Corporate Author |
|
Thesis |
|
|
| |
Publisher |
|
Place of Publication |
|
Editor |
|
|
| |
Language |
|
Summary Language |
|
Original Title |
|
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
0943-0105 |
ISBN |
|
Medium |
|
|
| |
Area |
|
Expedition |
|
Conference |
|
|
| |
Notes |
Oct.; Mine-water chemistry: The good, the bad and the ugly; 0337169; Germany 78; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10620.pdf; Geobase |
Approved |
no |
|
| |
Call Number |
CBU @ c.wolke @ 10620 |
Serial |
18 |
|
| Permanent link to this record |
| |
|
| |
|
Author |
Laine, D.M.; Jarvis, A.P. |
|
| |
Title |
Design aspects of passive in situ remediation schemes for minign & industrial effluents |
Type |
Journal Article |
| |
Year |
2003 |
Publication |
Tübinger Geowissenschaftliche Arbeiten |
Abbreviated Journal |
|
|
| |
Volume |
C68 |
Issue |
|
Pages |
95-113 |
|
| |
Keywords |
mine water passive treatment |
|
| |
Abstract |
|
|
| |
Address |
|
|
| |
Corporate Author |
|
Thesis |
|
|
| |
Publisher |
|
Place of Publication |
|
Editor |
|
|
| |
Language |
|
Summary Language |
|
Original Title |
|
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
0935-4948 |
ISBN |
|
Medium |
|
|
| |
Area |
|
Expedition |
|
Conference |
|
|
| |
Notes |
Design aspects of passive in situ remediation schemes for minign & industrial effluents; 1; FG 1 Abb., 2 Tab.; AMD ISI | Wolkersdorfer |
Approved |
no |
|
| |
Call Number |
CBU @ c.wolke @ 9759 |
Serial |
319 |
|
| Permanent link to this record |
| |
|
| |
|
Author |
Tarutis Jr, W.J.; Stark, L.R.; Williams, F.M. |
|
| |
Title |
Sizing and performance estimation of coal mine drainage wetlands |
Type |
Journal Article |
| |
Year |
1999 |
Publication |
Ecological Engineering |
Abbreviated Journal |
|
|
| |
Volume |
12 |
Issue |
3-4 |
Pages |
353-372 |
|
| |
Keywords |
mine water treatment coal mine drainage constructed wetlands efficiency first-order removal loading rate removal kinetics sizing zero-order removal constructed wetlands water-quality iron kinetics removal model phosphorus retention mechanism design Wetlands and estuaries geographical abstracts: physical geography hydrology (71 6 8) acid mine drainage effluent performance assessment remediation wetland management |
|
| |
Abstract |
The effectiveness of wetland treatment of acid mine drainage (AMD) was assessed using three measures of performance: treatment efficiency, area-adjusted removal, and first-order removal. Mathematical relationships between these measures were derived from simple kinetic equations. Area-adjusted removal is independent of pollutant concentration (zero-order reaction kinetics), while first-order removal is dependent on concentration. Treatment efficiency is linearly related to area-adjusted removal and exponentially related to first-order removal at constant hydraulic loading rates (flow/area). Examination of previously published data from 35 natural AMD wetlands revealed that statistically significant correlations exist between several of the performance measures for both iron and manganese removal, but these correlations are potentially spurious because these measures are derived from, and are mathematical rearrangements of, the same operating data. The use of treatment efficiency as a measure of performance between wetlands is not recommended because it is a relative measure that does not account for influent concentration differences. Area-adjusted removal accounts for mass loading effects, but it fails to separate the flow and concentration components, which is necessary if removal is first-order. Available empirical evidence suggests that AMD pollutant removal is better described by first-order kinetics. If removal is first-order, the use of area-adjusted rates for determining the wetland area required for treating relatively low pollutant concentrations will result in undersized wetlands. The effects of concentration and flow rate on wetland area predictions for constant influent loading rates also depend on the kinetics of pollutant removal. If removal is zero-order, the wetland area required to treat a discharge to meet some target effluent concentration is a decreasing linear function of influent concentration (and an inverse function of flow rate). However, if removal is first-order, the required wetland area is a non-linear function of the relative influent concentration. Further research is needed for developing accurate first-order rate constants as a function of influent water chemistry and ecosystem characteristics in order to successfully apply the first-order removal model to the design of more effective AMD wetland treatment systems. |
|
| |
Address |
W.J. Tarutis Jr., Department of Natural Science, Lackawanna Junior College, 501 Vine Street, Scranton, PA 18509, United States |
|
| |
Corporate Author |
|
Thesis |
|
|
| |
Publisher |
|
Place of Publication |
|
Editor |
|
|
| |
Language |
|
Summary Language |
|
Original Title |
|
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
0925-8574 |
ISBN |
|
Medium |
|
|
| |
Area |
|
Expedition |
|
Conference |
|
|
| |
Notes |
Feb.; Sizing and performance estimation of coal mine drainage wetlands; 0427766; Netherlands 46; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10596.pdf; Geobase |
Approved |
no |
|
| |
Call Number |
CBU @ c.wolke @ 10596 |
Serial |
25 |
|
| Permanent link to this record |
| |
|
| |
|
Author |
Evangelou, V.P. |
|
| |
Title |
Pyrite microencapsulation technologies: Principles and potential field application |
Type |
Journal Article |
| |
Year |
2001 |
Publication |
Ecological Engineering |
Abbreviated Journal |
|
|
| |
Volume |
17 |
Issue |
2-3 |
Pages |
165-178 |
|
| |
Keywords |
mine water treatment Acid mine drainage Acidity Alkalinity Amelioration Coating Oxidation Surface reactions |
|
| |
Abstract |
In nature, pyrite is initially oxidized by atmospheric O2, releasing acidity and Fe2+. At pH below 3.5, Fe2+ is rapidly oxidized by T. ferrooxidans to Fe3+, which oxidizes pyrite at a much faster rate than O2. Commonly, limestone is used to prevent pyrite oxidation. This approach, however, has a short span of effectiveness because after treatment the surfaces of pyrite particles remain exposed to atmospheric O2 and oxidation continuous abiotically. Currently, a proposed mechanism for explaining non-microbial pyrite oxidation in high pH environments is the involvement of OH- in an inner-sphere electron-OH exchange between pyrite/surface-exposed disulfide and pyrite/surface-Fe(III)(OH)n3-n complex and/or formation of a weak electrostatic pyrite/surface-CO3 complex which enhances the chemical oxidation of Fe2+. The above infer that limestone application to pyritic geologic material treats only the symptoms of pyrite oxidation through acid mine drainage neutralization but accelerates non-microbial pyrite oxidation. Therefore, only a pyrite/surface coating capable of inhibiting O2 diffusion is expected to control long-term oxidation and acid drainage production. The objective of this study was to examine the feasibility in controlling pyrite oxidation by creating, on pyrite surfaces, an impermeable phosphate or silica coating that would prevent either O2 or Fe3+ from further oxidizing pyrite. The mechanism underlying this coating approach involves leaching mine waste with a coating solution composed of H2O2 or hypochlorite, KH2PO4 or H4SiO4, and sodium acetate (NaAC) or limestone. During the leaching process, H2O2 or hypochlorite oxidizes pyrite and produces Fe3+ so that iron phosphate or iron silicate precipitates as a coating on pyrite surfaces. The purpose of NaAC or limestone is to eliminate the inhibitory effect of the protons (produced during pyrite oxidation) on the precipitation of iron phosphate or silicate and to generate iron-oxide pyrite coating, which is also expected to inhibit pyrite oxidation. The results showed that iron phosphate or silicate coating could be established on pyrite by leaching it with a solution composed of: (1) H2O2 0.018-0.16 M; (2) phosphate or silicate 10-3 to 10-2 M; (3) coating-solution pH [approximate]5-6; and (4) NaAC as low as 0.01 M. Leachates from column experiments also showed that silicate coatings produced the least amount of sulfate relative to the control, limestone and phosphate treatments. On the other hand, limestone maintained the leachate near neutral pH but produced more sulfate than the control. |
|
| |
Address |
|
|
| |
Corporate Author |
|
Thesis |
|
|
| |
Publisher |
|
Place of Publication |
|
Editor |
|
|
| |
Language |
|
Summary Language |
|
Original Title |
|
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
0925-8574 |
ISBN |
|
Medium |
|
|
| |
Area |
|
Expedition |
|
Conference |
|
|
| |
Notes |
July 01; Pyrite microencapsulation technologies: Principles and potential field application; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10063.pdf; Science Direct |
Approved |
no |
|
| |
Call Number |
CBU @ c.wolke @ 10063 |
Serial |
37 |
|
| Permanent link to this record |
