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Author |
Herbert, R.B., Jr.; Benner, S.G.; Blowes, D.W. |
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Title |
Reactive barrier treatment of groundwater contaminated by acid mine drainage; sulphur accumulation and sulphide formation |
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Book Chapter |
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Year |
1998 |
Publication |
Groundwater Quality: Remediation and Protection |
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451-457 |
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Keywords |
acid mine drainage Canada chemical analysis contaminant plumes Eastern Canada ground water hydraulic conductivity hydrolysis Nickel Rim Mine Ontario pH pollution porosity pyrrhotite remediation sample preparation Sudbury Basin sulfides sulfur tailings water pollution 22, Environmental geology |
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Abstract |
A permeable reactive barrier was installed in August 1995 at the Nickel Rim Mine near Sudbury, Ontario, Canada, for the passive remediation of groundwater contaminated with acid mine drainage. The reactive component of the barrier consists of a mixture of municipal and leaf compost and wood chips: the organic material promotes bacterially-mediated sulphate reduction. Hydrogen sulphide, a product of sulphate reduction, may then complex with aqueous ferrous iron and precipitate as iron sulphide. This study presents the solid phase sulphur chemistry of the reactive wall after two years of operation, and discusses the formation and accumulation of iron sulphide minerals in the reactive material. The results from the solid-phase chemical analysis of core samples indicate that there is an accumulation of reduced inorganic sulphur in the reactive wall, with levels reaching 190 mu mol g (super -1) (dry weight) by July 1997. |
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IAHS-AISH Publication, vol.250 |
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Herbert, M.; Kovar, K. |
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1901502554 |
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Reactive barrier treatment of groundwater contaminated by acid mine drainage; sulphur accumulation and sulphide formation; GeoRef; English; 1999-065115; GQ 98 conference, Tubingen, Federal Republic of Germany, Sept. 21-24, 1998 References: 15; illus. |
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Call Number |
CBU @ c.wolke @ 16621 |
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65 |
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Author |
Barton, C.D.; Karathanasis, A.D. |
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Title |
Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage |
Type |
Book Chapter |
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Year |
1997 |
Publication |
AAPG Eastern Section and the Society for Organic Petrology joint meeting; abstracts |
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Pages |
1545 |
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Keywords |
acid mine drainage aerobic environment air-water interface anaerobic environment attenuation buffers constructed wetlands controls diffusion iron manganese metals mineral composition pollution precipitation processes SEM data solubility solution sulfate ion sulfur wetlands X-ray diffraction data 22, Environmental geology |
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Abstract |
The use of constructed wetlands for acid mine drainage amelioration has become a popular alternative to conventional treatment methods, however, the metal attenuation processes of these systems are poorly understood. Precipitates from biotic and abiotic zones of a staged constructed wetland treating high metal load (approx. equal to 1000 mg L (super -1) ) and low pH (approx. 3.0) acid mine drainage were characterized by chemical dissolution, x-ray diffraction, thermal analysis and scanning electron microscopy. Characterization of abiotic/aerobic zones within the treatment system suggest the presence of crystalline iron oxides and hydroxides such as hematite, lepidocrocite, goethite, and jarosite. At the air/water interface of initial abiotic treatment zones, SO (sub 4) /Fe ratios were low enough (<2.0) for the formation of jarosite and goethite, but as the ratio increased due to treatment and subsequent reductions in iron concentration, jarosite was transformed to other Fe-oxyhydroxysulfates and goethite formation was inhibited. In addition, elevated pH conditions occurring in the later stages of treatment promoted the formation of amorphous iron oxyhydroxides. Biotic wetland cell substrate characterizations suggest the presence of amorphous iron minerals such as ferrihydrite and Fe(OH) (sub 3) . Apparently, high Fe (super 3+) activity, low Eh and low oxygen diffusion rates in the anaerobic subsurface environment inhibit the kinetics of crystalline iron precipitation. Some goethite, lepidocrocite and hematite, however, were observed near the surface in biotic areas and are most likely attributable to increased oxygen levels from surface aeration and/or oxygen transport by plant roots. Alkalinity generation from limestone dissolution within the substrate and bacterially mediated sulfate reduction also has a significant role on the mineral retention process. The formation of gypsum, rhodochrocite and siderite are by-products of alkalinity generating reactions in this system and may have an impact on S, Mn, and Fe solubility controls. Moreover, the buffering of acidity through excess alkalinity appears to facilitate the precipitation and retention of metals within the system. |
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AAPG Bulletin |
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Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage; GeoRef; English; 1997-067790; AAPG Eastern Section and the Society for Organic Petrology joint meeting, Lexington, KY, United States, Sep. 27-30, 1997 |
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Call Number |
CBU @ c.wolke @ 16630 |
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70 |
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Author |
Ziemkiewicz, P.F.; Meek, F.A., Jr.; Skousen, J.G.; Ziemkiewicz, P.F. |
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Title |
Long term behavior of acid forming rock; results of 11-year field studies |
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Book Chapter |
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Year |
1996 |
Publication |
Acid mine drainage control and treatment |
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Keywords |
acid mine drainage; acid rock drainage; alkaline earth metals; alkalinity; calcium; chemical composition; clastic rocks; coal mines; leachate; metals; mines; pH; pollution; prediction; reclamation; remediation; sandstone; sedimentary rocks; shale; spoils; sulfate ion; sulfur; United States; Upshur County West Virginia; waste disposal; waste rock; weathered materials; weathering; West Virginia 22, Environmental geology |
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West Virginia University and the National Mine Land Reclamation Center |
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Morgantown |
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Long term behavior of acid forming rock; results of 11-year field studies; GeoRef; English; 2004-051147; Edition: 2 References: 9; illus. incl. 1 table |
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CBU @ c.wolke @ 6357 |
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190 |
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Author |
Noss, R.R.; Crago, R.W.; Gable, J.; Kerber, B.; Mafi, S. |
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Title |
Use of flue gas desulfurization sludge in abandoned mine land reclamation |
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Journal Article |
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Year |
1997 |
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abandoned mines; acid mine drainage; flue gas desulfurization sludge; land management; land use; liquid waste; mines; mining; mining geology; moisture; pH; pollution; reclamation; remediation; soils; strip mining; surface mining; waste disposal 22, Environmental geology |
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The Ohio Journal of Science |
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Ohio Academy of Science 106th annual meeting; progress toward water quality in the Lake Erie basin; abstracts |
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1999-043696; Ohio Academy of Science 106th annual meeting, Bowling Green, OH, United States, April 4-6, 1997; GeoRef; English |
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Call Number |
CBU @ c.wolke @ 6302 |
Serial |
282 |
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Author |
Benzaazoua, M.; Bussiere, B. |
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Title |
Desulphurization of tailings with low neutralizing potential; kinetic study and flotation modeling |
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Book Chapter |
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Year |
1999 |
Publication |
Sudbury '99; Mining and the environment II; conference proceedings |
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acid mine drainage chemical properties chemical reactions environmental analysis environmental effects experimental studies flotation geochemistry kinetics laboratory studies mathematical models neutralization pH pollution sulfur tailings 22 Environmental geology 02A General geochemistry |
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Abstract |
Environmental desulphurization is an attractive alternative for acid generating tailings management as demonstrated during the last few years. In fact, such process placed at the end of the primary treatment circuit allows to reduce greatly the amount of problematic tailings by concentrating the sulphidic fraction. Moreover, the desulphurized tailings (non-acid generating) have the geotechnical and environmental properties for being used as fine material in a cover with capillary barrier effects. To produce desulphurized tailings, non selective froth flotation is the most adapted method as shown in many previous works. Desulphurization level is fixed by tailings sulphur content (or sulphide content) and neutralization potential NP. The final residue should have enough NP to compensate for his acid generating potential AP. In this paper, the authors present the results of laboratory tests conducted in Denver cells for studying the sulphide flotation kinetics of four mine tailings which are characterized by a weak neutralization potential (under 37 kg CaCO (sub 3) /t). Tailings 1, 2, 3 and 4 contain respectively 5.27, 10, 4.25 and 16.9 sulphur Wt. %. Tailings 1 and 2 are cyanide free and are well floated at pH around 11 by using amyl xanthate as collector. Collector dosage was optimized for these tailings and the results show that Tailing 2 need more collector. However, Tailings 3 and 4, which come from a gold cyanidation process, could not provide good sulphide recovery with xanthate collector because of the pyrite depression. To overcome this problem, amine acetate was used successfully but induces important entrainment. The consumption of this collector was also optimized. The results of kinetic tests and collector dosage were combined and modeled to establish relationships which allow to estimate the desulphurization performances. |
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Goldsack, D.; Belzile, N.; Yearwood, P.; Hall, G. |
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0886670470 |
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Notes |
Desulphurization of tailings with low neutralizing potential; kinetic study and flotation modeling; GeoRef; English; 2002-060841; Sudbury '99; Mining and the environment II--Sudbury '99; L'exploitation miniere et l'environnement, Sudbury, ON, Canada, Sept. 13-17, 1999 References: 26; illus. incl. 5 tables |
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Call Number |
CBU @ c.wolke @ 16572 |
Serial |
452 |
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