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Author |
Mustikkamaki, U.-P. |
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Metallipitoisten vesien biologisesta kasittelysta Outokummun kaivoksilla. Metal content treated with biological methods at the Outokummun operation |
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2000 |
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Vuoriteollisuus = Bergshanteringen |
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58 |
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1 |
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44-47 |
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acid mine drainage anaerobic environment bacteria biodegradation environmental analysis Europe filters Finland metals Outokummun Mine peat pollutants pollution reduction Scandinavia sediments sulfate ion Western Europe zinc 22, Environmental geology |
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Acid mine drainage (AMD) is one of the most serious environmental problems in the metal-mining industry. AMD is formed by the chemical and bacterial oxidation of sulphide minerals, and it is characterized by low pH values and high sulphate and metals content. The most common method to treat AMD is chemical neutralization. The chemical treatment requires high capital and operating costs and its use is problematic at the closed mines sites. Outokumpu has studied and used sulphate reducing bacteria (SRB) as an alternative method for the treatment of AMD. SRB existing in many natural anaerobic aqueous environments can reduce sulphate to sulphide which precipitates metals as extremely insoluble metal sulphides. Full scale experiments were begun in summer 1995 in the Ruostesuo open pit (depth 46 m) by adding liquid manure as a source of bacteria and press-juice as a growth substrate. The average Zn content of the whole column has decreased from 3,5 mg/l to 0,8 mg/l and below 25 m zinc is 0 mg/l. Similar results have been reached with nickel in the Kotalahti old nickel mine, where bacteria were brought in 1996. We have found that the same bacterial mechanism acts in peat-limestone filters, which Outokumpu has built at several mine sites since 1993. |
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0042-9317 |
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Metallipitoisten vesien biologisesta kasittelysta Outokummun kaivoksilla. Metal content treated with biological methods at the Outokummun operation; 2001-069868; illus. incl. 3 tables Finland (FIN); GeoRef; Finnish |
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CBU @ c.wolke @ 16560 |
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291 |
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Murdock, D.J.; Fox, J.R.W.; Bensley, J.G. |
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Title |
Treatment of acid mine drainage by the high density sludge process |
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Book Chapter |
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Year |
1994 |
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Special Publication – United States. Bureau of Mines, Report: BUMINES-SP-06A-94 |
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241-249 |
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acid mine drainage; concentration; oxidation; pollutants; pollution; remediation; solute transport; sulfides; waste water; water quality 22, Environmental geology |
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Proceedings of the International land reclamation and mine drainage conference and Third international conference on The abatement of acidic drainage; Volume 1 of 4; Mine drainage |
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Treatment of acid mine drainage by the high density sludge process; GeoRef; English; 2007-045177; International land reclamation and mine drainage conference and Third international conference on The abatement of acidic drainage, Pittsburgh, PA, United States, April 24-29, 1994 References: 10; illus. incl. 2 tables |
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CBU @ c.wolke @ 6584 |
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292 |
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Mosher, J. |
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Heavy-metal sludges as smelter feedstock |
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Journal Article |
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1994 |
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Engineering and Mining Journal |
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195 |
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9 |
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25-30 |
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Metals Mining Groundwater Pollution USA Colorado California Gulch 3 Geology |
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Many industries produce a waste-water stream high in heavy metals. Disposal of sludge from these wastewater treatment plants has become increasingly difficult and expensive in the US due to passage of the Resource Conservation and Recovery Act's 'land disposal ban' for hazardous wastes. Innovative methods can be found for dealing with such wastes. For example, in performing a mandated clean-up under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), Asarco's California Gulch water-treatment plant in Colorado meets CERCLA clean-up goals while using a waste water treatment sludge as a smelter feedstock, recovering incidental saleable metals, and producing non-hazardous products. In this plant, Asarco treats acidic mine-drainage water having high metal concentrations and uses the waste sludge generated as a lime replacement in lead smelting operations. -Author |
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Heavy-metal sludges as smelter feedstock; (1084960); 95t-4357; Using Smart Source Parsing pp; Geobase |
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Call Number |
CBU @ c.wolke @ 17563 |
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293 |
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Author |
Mitchell, P.; Wheaton, A. |
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Title |
From environmental burden to natural resource; new reagents for cost-effective treatment of, and metal recovery from, acid rock drainage |
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1999 |
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Sudbury '99; Mining and the environment II; Conference proceedings |
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acid mine drainage Bunker Hill Mine cost decontamination Idaho metal ores mines mitigation natural resources pollution reagents recovery Shoshone County Idaho sludge United States zinc ores 22 Environmental geology 27A Economic geology, geology of ore deposits |
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Acid rock drainage remains the greatest environmental issue faced by the mining sector and as the new millennium approaches, low capital/operating cost treatments remain elusive. Therefore as part of an ongoing process to develop a leading edge, innovative and cost-effective approach, pilot trials were conducted by KEECO in collaboration with the New Bunker Hill Mining Company on a substantial and problematic metal-contaminated acid flow, emanating from underground workings at the Bunker Hill Mine, Idaho. The aims of the work were fourfold. First to assess the capacity of KEECO's unique Silica Micro Encapsulation (SME) reagents and associated dosing systems to cost-effectively decontaminate the acid flow to stringent standards set by the U.S. Environmental Protection Agency (USEPA), where alternative and standard technologies had failed. Second, to demonstrate that treatment using a compact system suitable for underground installation. Third, to demonstrate that the treatment sludge had enhanced chemical stability in absolute terms and relative to standard approaches. Fourth, to examine the potential for resource recovery via sequential precipitation. Although the focus to date has been the development of a cost-effective treatment technology, the latter aim was considered essential in light of the growing pressure on all industrial sectors to develop tools for environmentally sustainable economic growth and the growing demands of stakeholders for improved resource usage and recycling. Two phases of work were undertaken: a laboratory-based scoping exercise followed by installation within the mine workings of a compact reagent delivery/shear mixing unit capable of treating the full flow of 31 L s (super -1) . At a dose rate of 2.0 g L (super -1) (equivalent to a final treated water pH range of 7-9), the SME reagent KB-1 reduced metal concentrations to levels approaching the U.S. Drinking Water Standards, which no other treatment piloted at the site had achieved. Based on the USEPA's Toxicity Characteristic Leaching Procedure, the sludge arising from the treatment was classified as non-hazardous. Operating costs compared favourably with those of lime use, while estimated capital costs were considerably lower due to the compact nature of the reagent delivery system and the rapid settling characteristics of the treatment sediment. Resource recovery was attempted using a two-stage selective precipitation approach. The first stage involved pH adjustment to 5.5 (by addition of 1.5 g L (super -1) of KB-1) to produce a sludge enriched in aluminium, iron and manganese, with lesser amounts of arsenic, nickel, lead and zinc. Further KB-1 addition to a total of 2.1 g L (super -1) generated sludge enriched in zinc (33% by dry weight), demonstrating that resource recovery is theoretically feasible. Further work on downstream processing is required, although it is considered that the most likely route for zinc metal recovery will be high temperature/pressure due to the chemically inert nature of the zinc-rich sediment. |
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Goldsack, D.E.; Belzile, N.; Yearwood, P.; Hall, G.J. |
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0886670470 |
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From environmental burden to natural resource; new reagents for cost-effective treatment of, and metal recovery from, acid rock drainage; GeoRef; English; 2000-048642; Sudbury '99; Mining and the environment II, Sudbury, ON, Canada, Sept. 13-17, 1999 References: 3; illus. incl. 5 tables |
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CBU @ c.wolke @ 16593 |
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296 |
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Mitchell, P.; Rybock, J.; Wheaton, A. |
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Title |
Treatment and prevention of ARID using silica micro encapsulation |
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Book Chapter |
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1999 |
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Proceedings of the 16th annual National meeting of the American Society for Surface Mining and Reclamation; Mining and reclamation for the next millennium |
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657-661 |
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acid mine drainage Bunker Hill Mine Idaho mines pollution Shoshone County Idaho United States water treatment 22, Environmental geology |
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In response to the known drawbacks of liming and the ever-increasing regulatory demands on the mining industry, KEECO has developed a silica micro encapsulation (SME) process. SME is a cost-effective, high performance reagent that is utilized in conjunction with simple chemical delivery systems. By encapsulating metals in a silica matrix formation and rapidly precipitating them into a sand-like sludge, it offers all the advantages of liming without the negative drawbacks. Utilizing an injection technique via a high shear mixing device, a slurry from of the SME product called KB-1 (super TM) was applied to ARD at the Bunker Hill Mine in Idaho and to ARD pumped from collection ponds at a remote mine site in the Sierra Nevada Mountains. Flow rates at both sites ranged from 500 to 800 gallons per minute. Treated water from the Bunker Hill Mine operation achieved the site's NPDES criteria for all evaluated metals and U.S. Drinking Water quality for arsenic, cadmium, chromium, lead and zinc with a dosage rate of 1.34 grams KB-1 (super TM) per liter. Treated water from the Sierra Nevada project focused on the control of aluminum, arsenic, copper, iron and nickel. All water samples displayed a >99.5% reduction in these metals, as well as an 84%-87% reduction in the concentration of sulfate. Testing on sludge generated from both operations achieved TCLP Action Limits. The SME process is currently under evaluation as a means to coat the pyrite surfaces of newly generated mine tailings to prevent oxidation and future acid generation. |
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Bengson, S.A.; Bland, D.M. |
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Treatment and prevention of ARID using silica micro encapsulation; GeoRef; English; 2001-047986; 16th annual National meeting of the American Society for Surface Mining and Reclamation, Scottsdale, AZ, United States, Aug. 13-19, 1999 2 tables |
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CBU @ c.wolke @ 16602 |
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297 |
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