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Author |
Benner, S.G. |
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Title |
Geochemistry of a permeable reactive barrier for metals and acid mine drainage |
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Journal Article |
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Year |
1999 |
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Environmental Science & Technology |
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33 |
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16 |
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2793-2799 |
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mine water treatment |
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Abstract |
A permeable reactive barrier, designed to remove metals and generate alkalinity by promoting sulfate reduction and metal sulfide precipitation, was installed in August 1995 into an aquifer containing effluent from mine tailings. Passage of groundwater through the barrier results in striking improvement in water quality. Dramatic changes in concentrations of SO4 (decrease of 2000-3000 mg/L), Fe (decrease of 270-1300 mg/L), trace metals (e.g., Ni decreases 30 mg/L), and alkalinity (increase of (800-2700 mg/L) are observed. Populations of sulfate reducing bacteria are 10 000 times greater, and bacterial activity, as measured by dehydrogenase activity, is 10 rimes higher within the barrier compared to the up-gradient aquifer. Dissolved sulfide concentrations increase by 0.2-120 mg/ L, and the isotope S-34 is enriched relative to S-32 in the dissolved phase SO42- within the barrier. Water chemistry, coupled with geochemical speciation modeling, indicates the pore water in the barrier becomes supersaturated with respect to amorphous Fe sulfide. Solid phase analysis of the reactive mixture indicates the accumulation of Fe monosulfide precipitates. Shifts in the saturation states of carbonate, sulfate, and sulfide minerals and most of the observed changes in water chemistry in the barrier and down-gradient aquifer can be attributed, either directly or indirectly, to bacterially mediated sulfate reduction. |
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Geochemistry of a permeable reactive barrier for metals and acid mine drainage; Wos:000082074500017; Times Cited: 57; ISI Web of Science |
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CBU @ c.wolke @ 17115 |
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132 |
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Barton, C.D. |
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Title |
Renovation of a failed constructed wetland treating acid mine drainage |
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Journal Article |
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Year |
1999 |
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Environmental Geology |
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39 |
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1 |
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39-50 |
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mine water treatment |
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Acid mine drainage (AMD) from abandoned underground mines significantly impairs water quality in the Tones Branch watershed in McCreary Co., Kentucky, USA. A 1022-m(2) surface-flow wetland was constructed in 1989 to reduce the I AMD effects, however, the system failed after six months due to insufficient utilization of the treatment area, inadequate alkalinity production and metal overloading. In an attempt to improve treatment efficiencies, a renovation project was designed incorporating two anoxic limestone drains (ALDs) and a series of anaerobic subsurface drains that promote vertical now or mine water through a successive alkalinity producing system (SAPS) of limestone beds overlain by organic compost. Analytical results from the 19-month post-renovation period are very encouraging. Mean iron concentrations have decreased from 787 to 39 mg l(-1), pH increased from 3.38 to 6.46 and acidity has been reduced from 2244 to 199 mg l(-1) (CaCO3 equivalent). Mass removal rates averaged 98% for Al, 95% for Fe, 94% for acidity, 55% for sulfate and 49% for Mn during the study period. The results indicate increased alkalinity production from limestone dissolution and longer residence time have contributed to sufficient buffering and metal retention. The combination of ALDs and SAPS technologies used in the renovation and the sequence in which they were implemented within the wetland system proved to be an adequate and very promising design for the treatment of this and other sources of high metal load AMD. |
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Renovation of a failed constructed wetland treating acid mine drainage; Wos:000084081400004; Times Cited: 5; ISI Web of Science |
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CBU @ c.wolke @ 17114 |
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129 |
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Swayze, G.A. |
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Imaging spectroscopy: A new screening tool for mapping acidic mine waste |
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Journal Article |
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2000 |
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ICARD 2000, Vols I and II, Proceedings |
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1531-+ |
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mine water treatment |
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Imaging spectroscopy is a relatively new remote sensing tool that provides a rapid method to screen entire mining districts for potential sources of surface acid drainage. An imaging spectrometer known as the Airborne Visible/InfraRed Imaging Spectrometer (AVIRIS) measures light reflected from the surface in 224 spectral channels from 0.4 – 2.5 mum. Spectral data from this instrument were used to evaluate mine waste at the California Gulch Superfund Site near Leadville, Colorado. Here, the process of pyrite oxidation at the surface produces acidic water that is gradually neutralized as it drains away from mine waste, depositing a central jarosite zone surrounded by a jarosite + goethite zone, in turn surrounded by a goethite zone with a discontinuous hematite rim zone. Leaching tests show that pH is most acidic in the jarosite and jarosite+goethite zones and is near-neutral in the goethite zone. Measurements indicate that metals leach from minerals and amorphous materials in the jarosite + goethite and jarosite zones at concentrations 10 – 50 times higher than from goethite zone minerals. Goethite zones that fully encircle mine waste may indicate some attenuation of leachate metals and thus reduced metal loading to streams. The potential for impact by acidic drainage is highest where streams intersect the jarosite and jarosite + goethite zones. In these areas, metal-rich acidic surface runoff may flow directly into streams. The U.S. Environmental Protection Agency estimates (U.S. EPA, 1998) that mineral maps made from AVIRIS data at Leadville have accelerated remediation efforts by two years and saved over $2 million in cleanup costs. |
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Imaging spectroscopy: A new screening tool for mapping acidic mine waste; Isip:000169875500152; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 17111 |
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164 |
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Campbell, A. |
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Mitigation of acid rock drainage at the Summitville Mine Superfund Site, Colorado, USA |
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Journal Article |
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2000 |
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ICARD 2000, Vols I and II, Proceedings |
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1243-1250 |
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mine water treatment |
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Numerous techniques for treating, controlling, and preventing acid rock drainage have been applied at the Summitville Mine Superfund Site. Challenging aspects of the remote mine site include the wide-spread occurrence of acid-generating soils and rocks, extensive surface and underground mine workings, and a cold and wet climate. Water treatment was an immediate necessity when the Government took control of the abandoned site in December of 1992. Subsequent reclamation activities have emphasized prevention and control of ARD to minimize future water treatment requirements. A combination of conventional, innovative, and experimental methods are being applied to successfully mitigate ARD at Summitville. |
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Mitigation of acid rock drainage at the Summitville Mine Superfund Site, Colorado, USA; Isip:000169875500124; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 17110 |
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165 |
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Author |
McGregor, R. |
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Title |
The use of an in-situ porous reactive wall to remediate a heavy metal plume |
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Journal Article |
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Year |
2000 |
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ICARD 2000, Vols I and II, Proceedings |
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1227-1232 |
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mine water treatment |
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The oxidation of sulfide minerals at an ore transfer location in Western Canada has resulted in widespread contamination of underlying soil and groundwater. The oxidation of sulfide minerals has released sulfate [SO4] and heavy metals including cadmium [Cd], copper [Cu], nickel [Ni], lead [Pb], and zinc [Zn] into the groundwater. A compost-based sulfate-reducing reactive wall was installed in the path of the plume in an attempt to reduce the potential impact of the heavy metals on a down-gradient marine inlet. Monitoring of the reactive wall over a 21-month period has shown that Cu concentrations decrease from over 4000 mug/L to less than 5 mug/L. Cadmium, Ni, Pb, and Zn concentrations also show similar decreases with treated concentrations generally being observed near or below detection limits. |
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The use of an in-situ porous reactive wall to remediate a heavy metal plume; Isip:000169875500122; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 17109 |
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166 |
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