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Author  |
Barton, C.D.; Karathanasis, A.D. |
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Title |
Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage |
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Book Chapter |
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Year |
1997 |
Publication |
AAPG Eastern Section and the Society for Organic Petrology joint meeting; abstracts |
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1545 |
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acid mine drainage aerobic environment air-water interface anaerobic environment attenuation buffers constructed wetlands controls diffusion iron manganese metals mineral composition pollution precipitation processes SEM data solubility solution sulfate ion sulfur wetlands X-ray diffraction data 22, Environmental geology |
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Abstract |
The use of constructed wetlands for acid mine drainage amelioration has become a popular alternative to conventional treatment methods, however, the metal attenuation processes of these systems are poorly understood. Precipitates from biotic and abiotic zones of a staged constructed wetland treating high metal load (approx. equal to 1000 mg L (super -1) ) and low pH (approx. 3.0) acid mine drainage were characterized by chemical dissolution, x-ray diffraction, thermal analysis and scanning electron microscopy. Characterization of abiotic/aerobic zones within the treatment system suggest the presence of crystalline iron oxides and hydroxides such as hematite, lepidocrocite, goethite, and jarosite. At the air/water interface of initial abiotic treatment zones, SO (sub 4) /Fe ratios were low enough (<2.0) for the formation of jarosite and goethite, but as the ratio increased due to treatment and subsequent reductions in iron concentration, jarosite was transformed to other Fe-oxyhydroxysulfates and goethite formation was inhibited. In addition, elevated pH conditions occurring in the later stages of treatment promoted the formation of amorphous iron oxyhydroxides. Biotic wetland cell substrate characterizations suggest the presence of amorphous iron minerals such as ferrihydrite and Fe(OH) (sub 3) . Apparently, high Fe (super 3+) activity, low Eh and low oxygen diffusion rates in the anaerobic subsurface environment inhibit the kinetics of crystalline iron precipitation. Some goethite, lepidocrocite and hematite, however, were observed near the surface in biotic areas and are most likely attributable to increased oxygen levels from surface aeration and/or oxygen transport by plant roots. Alkalinity generation from limestone dissolution within the substrate and bacterially mediated sulfate reduction also has a significant role on the mineral retention process. The formation of gypsum, rhodochrocite and siderite are by-products of alkalinity generating reactions in this system and may have an impact on S, Mn, and Fe solubility controls. Moreover, the buffering of acidity through excess alkalinity appears to facilitate the precipitation and retention of metals within the system. |
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AAPG Bulletin |
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Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage; GeoRef; English; 1997-067790; AAPG Eastern Section and the Society for Organic Petrology joint meeting, Lexington, KY, United States, Sep. 27-30, 1997 |
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Call Number |
CBU @ c.wolke @ 16630 |
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70 |
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Author |
Baskin, L. |
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Title |
Linear relationship between mine flow-acid load and influence of depositional environment |
Type |
Book Chapter |
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Year |
1979 |
Publication |
Underground coal mining symposium |
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acid mine drainage; Bell Gap Run; Blair County Pennsylvania; Cambria County Pennsylvania; environmental geology; ground water; hydrology; inorganic acids; iron; land use; Little Schuykill River; Loyalsock Creek; metals; Pennsylvania; pollution; programs; pyrite; Randolph County West Virginia; reclamation; rivers and streams; Roaring Creek; Schuylkill County Pennsylvania; statistical analysis; sulfides; sulfuric acid; Sullivan County Pennsylvania; surveys; Swatara Creek; treatment; United States; waste disposal; watersheds; West Virginia 22, Environmental geology |
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McGraw-Hill |
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New York City |
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Linear relationship between mine flow-acid load and influence of depositional environment; GeoRef; English; 1981-015370; Coal conference and expo V ; Underground coal mining symposium, Louisville, KY, United States, Oct. 23-25, 1979 References: 36; illus. incl. tables, sketch maps |
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CBU @ c.wolke @ 6819 |
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465 |
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Author |
Beck, P. |
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Title |
CL:AIRE – Providing support for remediation research |
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Journal Article |
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2003 |
Publication |
Land Contam. Reclam. |
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11 |
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2 |
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99-104 |
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Groundwater problems and environmental effects Pollution and waste management non radioactive geomechanics abstracts: excavations (77 10 10) geological abstracts: environmental geology (72 14 2) contaminated land remediation guideline acid mine drainage hydrochemistry |
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CL:AIRE (Contaminated Land: Applications in Real Environments) is a public-private partnership which was established in 1999 to encourage the demonstration of remediation research and technologies on contaminated sites throughout the UK. Project proposals are submitted to CL:AIRE and reviewed and approved by the CL:AIRE Technology & Research Group. CL:AIRE provides independent verification of its projects and plays a crucial role in the dissemination of project information. During the course of the project, progress is reported through the newsletter, CL:AIRE view, which is mailed free of charge to a database of more than 4500 stakeholders with an interest in contaminated land. Progress is also tracked on the CL:AIRE website at www.claire.co.uk. On completion of the project, a project report is published and a one page summary fact sheet is prepared. The fact sheet is distributed to our database subscribers and posted on the website. The project is also presented at the CL:AIRE Annual Project Conference. In addition, aspects of the research which have practical application will be published as CL:AIRE Research Bulletins. Acid mine waters discharging from abandoned mines represent a significant environmental problem in many parts of the UK. Considerable research has been carried out to understand the geochemical process involved, and the knowledge has been used to manage groundwater discharge through physical/chemical treatment and constructed wetlands. CL:AIRE supports the development of a national site for wetland research managed by the University of Newcastle and will encourage collaborative research projects to be submitted through CL:AIRE. CL:AIRE is currently supporting two projects which demonstrate remediation of acid mine drainage and is disseminating the results of this and other research to improve confidence in the use of these techniques. |
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P. Beck, CL:AIRE, 1 Great Cumberland Place, London W1H 7AL, United Kingdom |
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ISSN |
0967-0513 |
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CL:AIRE – Providing support for remediation research; 2530414; United-Kingdom 2; Geobase |
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Call Number |
CBU @ c.wolke @ 17524 |
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461 |
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Becker, G.; Wade, S.; Riggins, J.D.; Cullen, T.B.; Venn, C.; Hallen, C.P. |
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Title |
Effect of Bast Mine treatment discharge on Big Mine Run AMD and Mahanoy Creek in the Western Middle Anthracite Field of Pennsylvania |
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Journal Article |
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2005 |
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abandoned mines acid mine drainage anthracite Ashland Pennsylvania Bast Mine Big Mine Run coal coal fields coal mines Columbia County Pennsylvania discharge geochemistry hydrochemistry hydrology Mahanoy Creek mines Northumberland County Pennsylvania Pennsylvania pollution rivers and streams Schuylkill County Pennsylvania sedimentary rocks surface water United States water quality water treatment Western Middle Anthracite Field 22 Environmental geology 02A General geochemistry |
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The Bast Mine (reopened in 2001) and Big Mine are two anthracite coal mines near Ashland, PA, that were abandoned in the 1930's and that are now causing drastic and opposite effects on the water quality of the streams originating from them. To quantify these effects, multiple samples were taken at 5 different sites: 3 along Big Mine Run and 2 from Mahanoy Creek (1 upstream and 1 downstream of the confluence with Big Mine Run). At each site, one set of the samples was treated with nitric acid for metals survey, one set was acidified with sulfuric acid for nitrate preservation, one set was filtered for sulfate and phosphate tests, and one set was unaltered. Measurements of pH, TDS, dissolved oxygen, and temperature were made in the field. Alkalinity, acidity, hardness, nitrates, orthophosphates and sulfates were analyzed using Hach procedures. Selected metals (Fe, Ni, Mg, Ca, Cu, Zn, Hg, Pb) were analyzed utilizing flame atomic absorption spectroscopy. Drainage from the Bast Mine is actively treated with hydrated lime before the water is piped down to Big Mine Run. pH and alkalinity values were much higher at the outflow compared to those in the water with which it merged. The two waters could be visibly distinguished some distance downstream. pH values decreased, sulfate and dissolved iron increased and alkalinity was reduced to zero until the confluence with Mahanoy Creek. The high alkalinity, turbidity, TDS and calcium values in Mahanoy Creek were somewhat reduced downstream of the confluence with the much lower discharge Big Mine Run. |
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Abstracts with Programs - Geological Society of America |
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Geological Society of America, Northeastern Section, 40th annual meeting |
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2006-042616; Geological Society of America, Northeastern Section, 40th annual meeting, Saratoga Springs, NY, United States, March 14-16, 2005; GeoRef; English |
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Call Number |
CBU @ c.wolke @ 16455 |
Serial |
459 |
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Author |
Beers, W.F.; Ciolkosz, E.J.; Kardos, L.T. |
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Title |
Soil as a medium for the renovation of acid mine drainage water |
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Journal Article |
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Year |
1974 |
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acid mine drainage; coal; environmental geology; methods; mining; organic residues; pollution; rivers and streams; sedimentary rocks; soils; treatment; water 22, Environmental geology |
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0085-7068 |
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Soil as a medium for the renovation of acid mine drainage water; 1976-012550; illus. United States (USA); GeoRef; English |
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Call Number |
CBU @ c.wolke @ 6839 |
Serial |
458 |
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