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Author Ericsson, B.; Hallmans, B. url  openurl
  Title Treatment of saline wastewater for zero discharge at the Debiensko coal mines in Poland Type Journal Article
  Year 1996 Publication Desalination Abbreviated Journal  
  Volume 105 Issue 1-2 Pages 115-123  
  Keywords mine water  
  Abstract (down) The drainage water from mines in Poland has a daily contribution of, in the order of magnitude, 6,500 tons of chlorides and 0.5 ton of sulphates to the rivers Vistula (Wisla) and Oder (Odra). The largest amounts of these salts, about 78%, derive from 18 mines located mainly in the Katowice mine district. The high salt content in the water from the Vistula prevents at present its use in agriculture and causes tremendous economic losses due to corrosion attacks on pipes, machines, etc., within the industry. At present only about 4% of the river water can be classified as drinking water. To combat this problem a desalination project in Katowice has now almost been completed, including advanced treatment of wastewater for zero discharge from the two adjacent coal mines, Debiensko and Budryk. It implies elimination of 310 tons/d of salt discharge to the Odra River. The complete treatment processes are divided into three main sections: (1) pretreatment before reverse osmosis (RO) of about 12,400 m3/d drainage water from the two mines with a salinity of around 16,000 mg/l TDS on the average; (2) RO plant including post-treatment of the RO permeate; (3) a thermal plant for concentration of brine (about 4,600 m3/d) and separation of sodium chloride (NaCl) by crystallization, centrifuging and drying. The RO pretreatment includes algicide dosing in a storage tank, disinfection, flocculation/sedimentation and dual media filtration as well as granular activated carbon filtration. After a two-stage microfilter system (50 μ and 5 μ, respectively), the pretreated water is desalinated at 6-7 MPa in a RO system with spiral wound RO membranes. The RO permeate is decarbonated in a part-flow followed by addition of chemicals for disinfection and increase of the temporary hardness before distribution in the drinking water net. The flow into the thermal plant consists of the RO reject (about 2,700 m3/d) with a salinity of around 80 g/l TDS and the brine flow (about 1,870 m3/d) from the Budryk mine with about the same salinity. The first section of the thermal plant is composed of two brine concentrators, designed by Resources Conservation Company (RCC), USA. By using the seed crystal recycling technique it is possible to concentrate the feed to near the precipitation point for NaCl. The second section of the thermal plant includes one crystallizer for production of NaCl, two pusher centrifuges for salt removal from supersaturated brine and one fluidized bed dryer. The crystallizer is a forced circulation submerged-tube evaporator equipped with a mechanical vapor compressor. An additional section is also planned to be constructed for treatment of the purge from the crystallizer in order to recover other valuable chemical products and distillate. The process is fully automatic and controlled by programmable logic controllers. The plant has finally been designed by Energotechnika, Poland, after preparation of technical and economical planning of the project in coordination with Nordcap Ltd., RCC and VBB Viak-SWECO, Stockholm. In the summer 1994 the thermal plant was started up, and the RO plant is expected to be in operation during the spring 1995. The paper covers the project design with illustrations of the main parts of the plant and summarizes the results of the initial operation.  
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  ISSN 0011-9164 ISBN Medium  
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  Notes June; Treatment of saline wastewater for zero discharge at the Debiensko coal mines in Poland; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/9451.pdf; Science Direct Approved no  
  Call Number CBU @ c.wolke @ 17274 Serial 53  
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Author Tempel, R.N. url  openurl
  Title A quantitative approach to optimize chemical treatment of acid drainage using geochemical reaction path modeling methods: Climax Mine, Colorado Type Journal Article
  Year 2000 Publication ICARD 2000, Vols I and II, Proceedings Abbreviated Journal  
  Volume Issue Pages 1053-1058  
  Keywords mine water treatment  
  Abstract (down) The Climax Mine, near Leadville, Colorado treats acid drainage in a lime neutralization chemical treatment system. Chemical treatment has been successful in reducing the concentration of metals to below surface water discharge effluent limits, but lime usage has not been optimized. A geochemical modeling approach has been developed to increase the efficiency of lime neutralization. The modeling approach incorporates two steps: (1)calibration, and (2) calculation of amount of lime needed to increase pH and remove metals. Results of our work quantify the lime treatment process and improve our ability to predict overall water quality.  
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  Notes A quantitative approach to optimize chemical treatment of acid drainage using geochemical reaction path modeling methods: Climax Mine, Colorado; Isip:000169875500102; Times Cited: 0; ISI Web of Science Approved no  
  Call Number CBU @ c.wolke @ 17102 Serial 168  
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Author Carlson, L.; Kumpulainen, S. openurl 
  Title Retention of harmful elements by ochreous precipitates of iron Type Journal Article
  Year 2001 Publication Tutkimusraportti Geologian Tutkimuskeskus Abbreviated Journal  
  Volume - Issue 154 Pages 30-33  
  Keywords Surface water quality Pollution and waste management non radioactive geographical abstracts: physical geography hydrology (71 6 9) geological abstracts: environmental geology (72 14 2) iron oxide precipitation chemistry sulfate arsenate heavy metal pH water pollution remediation  
  Abstract (down) The capability of soil fines to fix harmful elements, e.g. heavy metals and arsenic, depends on specific surface area and other characteristics, such as surface charge. In the pH-range typical of natural waters (pH 5,5-7,5), the surfaces of fine-grained silicate particles and manganese oxides are negatively charged; consequently cations, such as heavy metals, fix effectively to them. The iron oxide surfaces are usually positively charged and typically fix anions, such as sulphate and arsenate. Retention of anions is especially extensive to precipitates formed from acid mine drainage (pH 2,5-5,0). For example, precipitates found at Paroistenjarvi mine, Finland, contain more than 70 g/kg of arsenic (dry matter). Adsorbed anions, e.g. sulphate, enhance the capacity of precipitate to fix heavy metal cations in low-pH environments.  
  Address L. Carlson, Tehtaankatu 25 A 4, Helsinki FIN-00150, Finland liisa.carlson@kolumbus.fi  
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  ISSN 0781-4240 ISBN Medium  
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  Notes Retention of harmful elements by ochreous precipitates of iron; 2392974; Oksidiset rautasaostumat haitallisten aineiden pidattajina. Finland 7; Geobase Approved no  
  Call Number CBU @ c.wolke @ 17533 Serial 421  
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Author Becker, G.; Wade, S.; Riggins, J.D.; Cullen, T.B.; Venn, C.; Hallen, C.P. openurl 
  Title Effect of Bast Mine treatment discharge on Big Mine Run AMD and Mahanoy Creek in the Western Middle Anthracite Field of Pennsylvania Type Journal Article
  Year 2005 Publication Abbreviated Journal  
  Volume Issue Pages  
  Keywords abandoned mines acid mine drainage anthracite Ashland Pennsylvania Bast Mine Big Mine Run coal coal fields coal mines Columbia County Pennsylvania discharge geochemistry hydrochemistry hydrology Mahanoy Creek mines Northumberland County Pennsylvania Pennsylvania pollution rivers and streams Schuylkill County Pennsylvania sedimentary rocks surface water United States water quality water treatment Western Middle Anthracite Field 22 Environmental geology 02A General geochemistry  
  Abstract (down) The Bast Mine (reopened in 2001) and Big Mine are two anthracite coal mines near Ashland, PA, that were abandoned in the 1930's and that are now causing drastic and opposite effects on the water quality of the streams originating from them. To quantify these effects, multiple samples were taken at 5 different sites: 3 along Big Mine Run and 2 from Mahanoy Creek (1 upstream and 1 downstream of the confluence with Big Mine Run). At each site, one set of the samples was treated with nitric acid for metals survey, one set was acidified with sulfuric acid for nitrate preservation, one set was filtered for sulfate and phosphate tests, and one set was unaltered. Measurements of pH, TDS, dissolved oxygen, and temperature were made in the field. Alkalinity, acidity, hardness, nitrates, orthophosphates and sulfates were analyzed using Hach procedures. Selected metals (Fe, Ni, Mg, Ca, Cu, Zn, Hg, Pb) were analyzed utilizing flame atomic absorption spectroscopy. Drainage from the Bast Mine is actively treated with hydrated lime before the water is piped down to Big Mine Run. pH and alkalinity values were much higher at the outflow compared to those in the water with which it merged. The two waters could be visibly distinguished some distance downstream. pH values decreased, sulfate and dissolved iron increased and alkalinity was reduced to zero until the confluence with Mahanoy Creek. The high alkalinity, turbidity, TDS and calcium values in Mahanoy Creek were somewhat reduced downstream of the confluence with the much lower discharge Big Mine Run.  
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  Publisher Abstracts with Programs - Geological Society of America Place of Publication Editor  
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  Series Editor Series Title Geological Society of America, Northeastern Section, 40th annual meeting Abbreviated Series Title  
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  Notes 2006-042616; Geological Society of America, Northeastern Section, 40th annual meeting, Saratoga Springs, NY, United States, March 14-16, 2005; GeoRef; English Approved no  
  Call Number CBU @ c.wolke @ 16455 Serial 459  
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Author Scholz, M. url  openurl
  Title Mature experimental constructed wetlands treating urban water receiving high metal loads Type Journal Article
  Year 2002 Publication Biotechnology Progress Abbreviated Journal  
  Volume 18 Issue 6 Pages 1257-1264  
  Keywords mine water treatment  
  Abstract (down) The aim was to assess over 2 years the treatment efficiencies of vertical-flow wetland filters containing macrophytes and granular media of different. adsorption capacities. Different concentrations of lead and copper sulfate (constant for 1 year each) were added to urban beck inflow water in order to simulate pretreated (pH adjustment assumed) mine wastewater. After 1 year of operation, the inflow concentrations for lead and copper were increased from 1.30 to 2.98 and from 0.98 to 1.93 mg/L, respectively. However, the metal mass load rates (mg/m(2)/d) were increased by a factor of approximately 4.9 for lead and 4.3 for copper. No breakthrough of metals was recorded. Lead and copper accumulated in the biomass of the litter zone and rhizomes of the macrophytes. Furthermore, microbiological activity decreased during the second year of operation. Bioindicators such as ciliated protozoa and zooplankton decreased sharply in numbers but diatoms increased. In conclusion, the use of macrophytes and, adsorption media did not significantly enhance the filtration of lead and copper. Particulate lead is removed by filtration processes including straining. Furthermore, some expensive and time-consuming water quality variables can be predicted with less expensive ones such as temperature in order to reduce sampling costs.  
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  Notes Mature experimental constructed wetlands treating urban water receiving high metal loads; Wos:000179760000018; Times Cited: 11; ISI Web of Science Approved no  
  Call Number CBU @ c.wolke @ 17032 Serial 119  
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