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Author Rabenhorst, M.C.; James, B.R.
Title Acid mine drainage remediation via sulfidization in wetlands Fiscal year 1992 annual report Type RPT
Year (up) 1993 Publication Abbreviated Journal
Volume Issue Pages
Keywords acid mine drainage; anaerobic environment; Appalachians; concentration; decontamination; ferric iron; iron; manganese; marshes; Maryland; metals; mires; North America; oxidation; pollutants; pollution; pore water; remediation; sulfidization; transport; United States; water quality; water treatment; wetlands 22, Environmental geology
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Series Editor University of Maryland, W.R.R.C.C.P.M.D.U.S. Series Title Abbreviated Series Title
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Notes Acid mine drainage remediation via sulfidization in wetlands Fiscal year 1992 annual report; 1998-034327; GeoRef; English; illus. incl. 1 table University of Maryland, Water Resources Research Center, College Park, MD, United States Approved no
Call Number CBU @ c.wolke @ 6684 Serial 267
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Author Kepler, D.A.; Mc Cleary, E.C.
Title Successive Alkalinity-Producing Systems (SAPS) for the Treatment of Acid Mine Drainage Type Journal Article
Year (up) 1994 Publication Proceedings, International Land Reclamation and Mine Drainage Conference Abbreviated Journal
Volume 1 Issue Pages 195-204
Keywords acid mine drainage; alkalinity; anaerobic environment; calcium carbonate; chemical reactions; experimental studies; pH; pollutants; pollution; remediation; water quality SAPS mine water RAPS
Abstract Constructed wetland treatment system effectiveness has been limited by the alkalinity-producing, or acidity-neutralizing, capabilities of systems. Anoxic limestone drains (ALD's) have allowed for the treatment of approximately 300 mg/L net acidic mine drainage, but current design guidance precludes using successive ALD's to generate alkalinity in excess of 300 mg/L because of concerns with dissolved oxygen. “Compost” wetlands designed to promote bacterially mediated sulfate reduction are suggested as a means of generating alkalinity required in excess of that produced by ALD's. Compost wetlands create two basic needs of sulfate reducing bacteria; anoxic conditions resulting from the inherent oxygen demand of the organic substrate, and quasi-circumneutral pH values resulting from the dissolution of the carbonate fraction of the compost. However, sulfate reduction treatment area needs are generally in excess of area availability and/or cost effectiveness. Second generation alkalinity-producing systems demonstrate that a combination of existing treatment mechanisms has the potential to overcome current design concerns and effectively treat acidic waters ad infinitum. Successive alkalinity-producing systems (SAPS) combine ALD technology with sulfate reduction mechanisms. SAPS promote vertical flow through rich organic wetland substrates into limestone beds beneath the organic compost, discharging the pore waters. SAPS allow for conservative wetland treatment sizing calculations to be made as a rate function based on pH and alkalinity values and associated contaminant loadings. SAPS potentially decrease treatment area requirements and have the further potential to generate alkalinity in excess of acidity regardless od acidity concentrations.
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Notes Successive Alkalinity-Producing Systems (SAPS) for the Treatment of Acid Mine Drainage; Cn, Kj, Aj; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/9722.pdf; AMD ISI | Wolkersdorfer Approved no
Call Number CBU @ c.wolke @ 9722 Serial 55
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Author Gusek, J.J.; Wildeman, T.R.
Title New developments in passive treatment of acid rock drainage Pollution prevention for process engineering Type Book Chapter
Year (up) 1995 Publication Abbreviated Journal
Volume Issue Pages
Keywords acid mine drainage; aerobic environment; alkalinity; bioaccumulation; bioremediation; constructed wetlands; decontamination; disposal barriers; geomembranes; heavy metals; hydroxides; nutrients; oxides; pH; physical properties; pollution; reclamation; remediation; soils; tailings; techniques; toxic materials; vegetation; waste disposal; water quality; wetlands 22, Environmental geology
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Publisher Engineering Foundation Place of Publication New York Editor Richardson, P.E.; Scheiner, B.J.; Lanzetta, F., Jr.
Language Summary Language Original Title
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ISSN ISBN 0939204533 Medium
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Notes New developments in passive treatment of acid rock drainage Pollution prevention for process engineering; GeoRef; English; 2000-063657; Engineering Foundation conference on Technical solution for pollution prevention in the mining and mineral processing industries, Palm Coast, FL, United States, Jan. 22-27, 1995 References: 3; illus. incl. 1 table Approved no
Call Number CBU @ c.wolke @ 6447 Serial 363
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Author Barton, C.D.; Karathanasis, A.D.
Title Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage Type Book Chapter
Year (up) 1997 Publication AAPG Eastern Section and the Society for Organic Petrology joint meeting; abstracts Abbreviated Journal
Volume Issue Pages 1545
Keywords acid mine drainage aerobic environment air-water interface anaerobic environment attenuation buffers constructed wetlands controls diffusion iron manganese metals mineral composition pollution precipitation processes SEM data solubility solution sulfate ion sulfur wetlands X-ray diffraction data 22, Environmental geology
Abstract The use of constructed wetlands for acid mine drainage amelioration has become a popular alternative to conventional treatment methods, however, the metal attenuation processes of these systems are poorly understood. Precipitates from biotic and abiotic zones of a staged constructed wetland treating high metal load (approx. equal to 1000 mg L (super -1) ) and low pH (approx. 3.0) acid mine drainage were characterized by chemical dissolution, x-ray diffraction, thermal analysis and scanning electron microscopy. Characterization of abiotic/aerobic zones within the treatment system suggest the presence of crystalline iron oxides and hydroxides such as hematite, lepidocrocite, goethite, and jarosite. At the air/water interface of initial abiotic treatment zones, SO (sub 4) /Fe ratios were low enough (<2.0) for the formation of jarosite and goethite, but as the ratio increased due to treatment and subsequent reductions in iron concentration, jarosite was transformed to other Fe-oxyhydroxysulfates and goethite formation was inhibited. In addition, elevated pH conditions occurring in the later stages of treatment promoted the formation of amorphous iron oxyhydroxides. Biotic wetland cell substrate characterizations suggest the presence of amorphous iron minerals such as ferrihydrite and Fe(OH) (sub 3) . Apparently, high Fe (super 3+) activity, low Eh and low oxygen diffusion rates in the anaerobic subsurface environment inhibit the kinetics of crystalline iron precipitation. Some goethite, lepidocrocite and hematite, however, were observed near the surface in biotic areas and are most likely attributable to increased oxygen levels from surface aeration and/or oxygen transport by plant roots. Alkalinity generation from limestone dissolution within the substrate and bacterially mediated sulfate reduction also has a significant role on the mineral retention process. The formation of gypsum, rhodochrocite and siderite are by-products of alkalinity generating reactions in this system and may have an impact on S, Mn, and Fe solubility controls. Moreover, the buffering of acidity through excess alkalinity appears to facilitate the precipitation and retention of metals within the system.
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Publisher AAPG Bulletin Place of Publication 81 Editor
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Notes Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage; GeoRef; English; 1997-067790; AAPG Eastern Section and the Society for Organic Petrology joint meeting, Lexington, KY, United States, Sep. 27-30, 1997 Approved no
Call Number CBU @ c.wolke @ 16630 Serial 70
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Author Barton, C.D.; Karathanasis, A.D.
Title Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage Type Journal Article
Year (up) 1998 Publication Environ Geosci Abbreviated Journal
Volume 5 Issue 2 Pages 43-56
Keywords acid mine drainage aerobic environment anaerobic environment attenuation chemical fractionation chemical properties concentration constructed wetlands controls degradation detection environmental analysis ferric iron goethite heavy metals iron jarosite Kentucky McCreary County Kentucky metals oxides pollutants pollution seepage soils solubility sulfates surface water United States water treatment wetlands X-ray diffraction data 22, Environmental geology
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ISSN 1075-9565 ISBN Medium
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Notes Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage; 2001-034195; References: 41; illus. incl. 1 table United States (USA); GeoRef; English Approved no
Call Number CBU @ c.wolke @ 16623 Serial 61
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