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Fischer, R., Reissig, H., Gockel, G., Seidel, K. H., & Guderitz, T. (1998). Direkte Neutralisation und Untergrundwasserbehandlung des Restwassers im Tagebaurestsee Heide VI. Direct neutralization and treatment of deep subsoil water of the residual water in the open-pit relic lake Heide VI. Braunkohle, Surface Mining, 50(3), 273–278.
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Sasaki, K. (2006). Immobilization of Mn(II) ions by a Mn-oxidizing fungus – Paraconiothyrium sp.-like strain at neutral pHs. Mater. Trans., 47(10), 2457–2461.
Abstract: A Mn-oxidizing fungus was isolated from a constructed wetland of Hokkaido (Japan), which is receiving the Mn-impacted drainage, and genetically and morphologically identified as Paraconiothyrium sp.-like strain. The optimum pHs were 6.45-6.64, where is more acidic than those of previously reported Mn-oxidizing fungi. Too much nutrient inhibited fungal Mn-oxidation, and too little nutrient also delayed Mn oxidation even at optimum pH. In order to achieve the oxidation of high concentrations of Mn like mine drainage containing several hundreds g-m(-3) of Mn, it is important to find the best mix ratio among the initial Mn concentrations, inocolumn size and nutrient concentration. The strain has still Mn-tolerance with more than 380 g-m(-3) of Mn, but high Mn(II) oxidation was limited by pH control and supplied nutrient amounts. The biogenic Mn deposit was poorly crystallized birnessite. The strain is an unique Mn-oxidizing fungus having a high Mn tolerance and weakly acidic tolerance, since there has been no record about the property of the strain. There is a potentiality to apply the strain to the environmental bioremediation.
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Gusek, J. J. (1995). Passive-treatment of acid rock drainage: what is the potential bottom line? Min. Eng., 47(3), 250–253.
Abstract: Passive-treatment systems that mitigate acid-rock drainage from coal mines have been operating since the mid-1980s. Large systems at metal mines are being contemplated. A typical man-made passive-treatment-system can mimic a natural wetland by employing the same geochemical principles. Passive-treatment systems, however, are engineered to optimize the biogeochemical processes occurring in a natural wetland ecosystem. The passive-treatment methodology holds promise over chemical neutralization because large volumes of sludge are not generated. Metals may be precipitated as oxides, sulfides or carbonates in the passive-treatment system substrate. The key goal of a passive-treatment system is the long-term immobilization of metals in the substrate materials. The passive-treatment technique may not be applicable in all mine-drainage situations. -from Author
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Blowes, D. W., Ptacek, C. J., Benner, S. G., McRae, C. W. T., Bennett, T. A., & Puls, R. W. (2000). Treatment of inorganic contaminants using permeable reactive barriers. J Contam Hydrol, 45(1-2), 123–137.
Abstract: Permeable reactive barriers are an emerging alternative to traditional pump and treat systems for groundwater remediation. This technique has progressed rapidly over the past decade from laboratory bench-scale studies to full-scale implementation. Laboratory studies indicate the potential for treatment of a large number of inorganic contaminants, including As, Cd, Cr, Cu, Hg, Fe, Mn, Mo, Ni, Pb, Se, Tc, U, V, NO3, PO4 and SO4. Small-scale field studies have demonstrated treatment of Cd, Cr, Cu, Fe, Ni, Pb, NO3, PO4 and SO4. Permeable reactive barriers composed of zero-valent iron have been used in full-scale installations for the treatment of Cr, U, and Tc. Solid-phase organic carbon in the form of municipal compost has been used to remove dissolved constituents associated with acid-mine drainage, including SO4, Fe, Ni, Co and Zn. Dissolved nutrients, including NO3 and PO4, have been removed from domestic septic-system effluent and agricultural drainage.
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Larsen, H. P. (1973). Chemical Treatment Of Metal-Bearing Mine Drainage. J. Water Poll. Control Fed., 45(8), 1682–1695.
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