Blowes, D. W., Ptacek, C. J., Benner, S. G., McRae, C. W. T., & Puls, R. W. (1998). Treatment of dissolved metals using permeable reactive barriers. Groundwater Quality: Remediation and Protection, (250), 483–490.
Abstract: Permeable reactive barriers are a promising new approach to the treatment of dissolved contaminants in aquifers. This technology has progressed rapidly from laboratory studies to full-scale implementation over the past decade. Laboratory treatability studies indicate the potential for treatment of a large number of inorganic contaminants, including As, Cd, Cr, Cu, Hg, Fe, Mn, Mo, Ni, Pb, Se, Tc, U, V, NO3, PO4, and SO4. Small scale field studies have indicated the potential for treatment of Cd, Cr, Cu, Fe, Ni, Pb, NO3, PO4, and SO4. Permeable reactive barriers have been used in full-scale installations for the treatment of hexavalent chromium, dissolved constituents associated with acid-mine drainage, including SO4, Fe, Ni, Co and Zn, and dissolved nutrients, including nitrate and phosphate. A full-scale barrier designed to prevent the release of contaminants associated with inactive mine tailings impoundment was installed at the Nickel Rim mine site in Canada in August 1995. This reactive barrier removes Fe, SO,, Ni and other metals. The effluent from the barrier is neutral in pH and contains no acid-generating potential, and dissolved metal concentrations are below regulatory guidelines. A full-scale reactive barrier was installed to treat Cr(VI) and halogenated hydrocarbons at the US Coast Guard site in Elizabeth City, North Carolina, USA in June 1996. This barrier removes Cr(VI) from >8 mg l(-1) to <0.01 mg l(-1).
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Younger, P. L., & Cornford, C. (2002). Mine water pollution from Kernow to Kwazulu-Natal; geochemical remedial options and their selection in practice.
Abstract: Pollution by mine drainage is a major problem in many parts of the world. The most frequent contaminants are Fe, Mn, Al and SO (sub 4) with locally important contributions by other metals/metalloids including (in order of decreasing frequency) Zn, Cu, As, Ni, Cd and Pb. Remedial options for such polluted drainage include monitored natural attenuation, physical intervention to minimise pollutant release, and active and passive water treatment technologies. Based on the assessment of the key hydrological and geochemical attributes of mine water discharges, a rational decision-making framework has now been developed for deciding which (or which combinations) of these options to implement in a specific case. Five case studies illustrate the application of this decision-making process in practice: Wheal Jane and South Crofty (Cornwall), Quaking Houses (Co Durham), Hlobane Colliery (South Africa) and Milluni Tin Mine (Bolivia). In many cases, particularly where the socio-environmental stakes are particularly high, the economic, political and ecological issues will prove even more challenging than the technical difficulties involved in implementing remedial interventions which will be robust in the long term. Hence truly “holistic” mine water remediation is a multi-dimensional business, involving teamwork by a range of geoscientific, hydroecological and socio-economic specialists.
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