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Whitlock, J. L. (1990). Biological Detoxification of Precious Metal Processing Wastewaters. Geomicrobiol. J., 8(3-4), 241–249.
Abstract: A biological treatment plant is utilized at the Homestake Mine in Lead, SD, to effect detoxification of a daily discharge of 4 million gallons of wastewater. The wastewater matrix requiring treatment contains cyanide, ammonia, toxic heavy metals, anda variable component of toxic chemicals associated with extractive metallurgy and mining operations. Rotating biological contactors (RBCs) are used to attach the biofilm. Cyanides and heavy metals concentrations are reduced by 95-98%. The treated discharge makes up as much as 60% of the total flow in a cold-water trout fishery. This receiving stream, which remained lifeless for over 100 years as a mine drainage, has now become an established trout fishery and recently yielded a state record trout.
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Bolzicco, J., Carrera, J., & Ayora, C. (2004). Eficiencia de la barrera permeable reactiva de Aznalcollar (Sevilla, Espana) como remedio de aguas acidas de mina. Reactive permeable disposal barrier at Aznalcollar Mine, Seville, Spain; as remediation for acid mine drainage. Revista Latino-Americana de Hidrogeologia, 4, 27–34.
Abstract: As a result of the collapse of a mine tailing dam in april 1998 about 40 km of the Agrio and Guadiamar valleys were covered with a layer of pyrite sludge. Although most of the sludge was removed, a small amount remains in the soil of the Agrio valley and the aquifer remains polluted with acid water (ph<4) and metals (10 mg/L Zn, 5 mg/L Cu and Al). A permeable reactive barrier was build across the aquifer to increase the alcalinity and retain the metals. The barrier is made up of three sections of 30 m longX1.4 m thickX5 m deep (average) containing different proportions of limestone gravel, organic compost and zero-valent iron. The residence time of the water in the barrier is about two days. Within the barrier, the pH values increase to near neutral mainly due to calcite dissolution. Metals co-precipitate as oxyhydroxides, and they are also adsorbed on the organic matter surface. Down-stream the barrier, the total pollution removal is around 60-90% for Zn and Cu, and from 50 to 90% for Al and acidity.
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Stark, L. R., & Williams, F. M. (1994). The roles of spent mushroom substrate for the mitigation of coal mine drainage. Compost Science and Utilization, 2(4), 84–94.
Abstract: Spent mushroom substrate (SMS) has been used widely in coal mining regions of the USA as the primary substrate in constructed wetlands for the treatment of coal mine drainage. In laboratory and mesocosm studies, SMS has emerged as one of the substrates for mine water treatment. Provided the pH of the mine water does not fall below 3.0, SMS can be used in the mitigation plan. However, neither Mn nor dissolved ferric Fe appears to be treatable using reducing SMS wetlands. Since after a few years much of the nonrefractive organic carbon in SMS wil have been decomposed and metabolized, carbon supplementation can significantly extend the life of the SMS treatment wetland and improve water treatment. -from Authors
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Becker, B., Graff, M., & Näveke, R. (1997). Biological Treatment of Overburden from Lignite Opencast Mining in Order to Avoid Seepage of Acid Mine Water. Proceedings, 6th International Mine Water Association Congress, Bled, Slovenia, 2, 283–291.
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Dempsey, B. A., & Jeon, B. - H. (2001). Characteristics of sludge produced from passive treatment of mine drainage. Geochem.-Explor. Environ. Anal., 1(1), 89–94.
Abstract: In the 1994 paper by Brown, Skousen & Renton it was argued that settleability and wet-packing density were the most important physical characteristics of sludge from treatment of mine drainage. These characteristics plus zeta-potential, intrinsic viscosity, specific resistance to filtration, and coefficient of compressibility were determined for several sludge samples from passive treatment sites and for several sludge samples that were prepared in the laboratory. Sludge from passive systems had high packing density, low intrinsic viscosity, low specific resistance to filtration and low coefficient of compressibility compared to sludge that was produced after addition of NaOH.
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