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Author |
Chung, I.J. |
Title |
Immobilization of arsenic in tailing by using iron and hydrogen peroxide |
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Journal Article |
Year |
2001 |
Publication |
Environ. Technol. |
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Volume |
22 |
Issue |
7 |
Pages |
831-835 |
Keywords |
mine water treatment |
Abstract |
Under environmental conditions, arsenic (As) reveals anionic behavior and is converted into various forms in accordance with the Eh/pH condition. This causes the difficulty of treating As with other heavy metals in tailing. This study was carried out to develop the immobilization method of arsenic in tailing as ferric arsenate (FeAsO4) using hydrogen peroxide. According to experimental results, the extracted concentrations of arsenic and iron (Fe) from tailing were reduced up to 84% and 93%, respectively. In the experiment using pure Pyrite (FeS2) and As solution, As concentration decreased with an increase of hydrogen peroxide dosage. The experimental results of re-extraction showed that only 10% of As and 20% of Fe were extracted in the case of using hydrogen peroxide. As a result, the long-term stability of this method was clarified. |
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Immobilization of arsenic in tailing by using iron and hydrogen peroxide; Wos:000170195000008; Times Cited: 0; ISI Web of Science |
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Call Number |
CBU @ c.wolke @ 17046 |
Serial |
123 |
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Author |
Ye, Z.H.; Whiting, S.N.; Qian, J.H.; Lytle, C.M.; Lin, Z.Q.; Terry, N. |
Title |
Trace element removal from coal ash leachate by a 10-year-old constructed wetland |
Type |
Journal Article |
Year |
2001 |
Publication |
J. Environ. Qual. |
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Volume |
30 |
Issue |
5 |
Pages |
1710-1719 |
Keywords |
acid mine drainage; Alabama; ash; bioaccumulation; boron; cadmium; constructed wetlands; environmental analysis; environmental effects; iron; Jackson County Alabama; Juncus effusus; leachate; manganese; metals; pH; pollutants; pollution; remediation; soils; sulfur; trace elements; Typha latifolia; United States; vegetation; waste water; wetlands; Widows Creek; Widows Creek Steam Plant; zinc; Typha; Juncus 22, Environmental geology |
Abstract |
This study investigated the ability of a 10-yr-old constructed wetland to treat metal-contaminated leachate emanating from a coal ash pile at the Widows Creek electric utility, Alabama (USA). The two vegetated cells, which were dominated by cattail (Typha latifolia L.) and soft rush (Juncus effusus L.), were very effective at removing Fe and Cd from the wastewater, but less efficient for Zn, S, B, and Mn. The concentrations were decreased by up to 99% for Fe, 91% for Cd, 63% for Zn, 61% for S, 58% for Mn, and 50% for B. Higher pH levels (>6) in standing water substantially improved the removing efficiency of the wetland for Mn only. The belowground tissues of both cattail and soft rush had high concentrations of all elements; only for Mn, however, did the concentration in the shoots exceed those in the belowground tissues. The concentrations of trace elements in fallen litter were higher than in the living shoots, but lower than in the belowground tissues. ne trace element accumulation in the plants accounted for less than 2.5% of the annual loading of each trace element into the wetland. The sediments were the primary sinks for the elements removed from the wastewater. Except for Mn, the concentrations of trace elements in the upper layer (0-5 cm) of the sediment profile tended to be higher than the lower layers (5-10 and 10-15 cm). We conclude that constructed wetlands are still able to efficiently remove metals in the long term (i.e., >10 yr after construction). |
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0047-2425 |
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Aug 1; Trace element removal from coal ash leachate by a 10-year-old constructed wetland; 2002-017274; References: 33; illus. incl. 2 tables United States (USA); file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/5703.pdf; GeoRef; English |
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CBU @ c.wolke @ 5703 |
Serial |
76 |
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Author |
Ye, Z.H. |
Title |
Removal and distribution of iron, manganese, cobalt, and nickel within a Pennsylvania constructed wetland treating coal combustion by-product leachate |
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Journal Article |
Year |
2001 |
Publication |
Journal of Environmental Quality |
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30 |
Issue |
4 |
Pages |
1464-1473 |
Keywords |
mine water treatment |
Abstract |
A flow-through wetland treatment system was constructed to treat coal combustion by-product leachate from an electrical power station at Springdale, Pennsylvania. In a nine-compartment treatment system, four cattail (Typha latifolia L.) wetland cells (designated Cells I through 4) successfully removed iron (Fe) and manganese (Mn) from the inlet water; Fe and Mn concentrations were decreased by an average of 91% in the first year (May 1996-May 1997), and by 94 and 98% in the second year (July 1997-June 1998), respectively. Cobalt (Co) and nickel (Ni) were decreased by an average of 39 and 47% in the first year, and 98 and 63% in the second year, respectively. Most of the metal removed by the wetland cells was accumulated in sediments, which constituted the largest sink. Except for Fe, metal concentrations in the sediments tended to be greater in the top 5 em of sediment than in the 5- to 10- or 10- to 15-cm layers, and in Cell I than in Cells 2, 3, and 4. Plants constituted a much smaller sink for metals; only 0.91, 4.18, 0.19, and 0.38% of the Fe, Mn, Co, and Ni were accumulated annually in the aboveground tissues of cattail, respectively. A greater proportion of each metal (except Mn) was accumulated in cattail fallen litter and submerged Chara (a macroalga) tissues, that is, 2.81, 2.75, and 1.05% for Fe, Co, and Ni, respectively. Considerably higher concentrations of metals were associated with cattail roots than shoots, although Mn was a notable exception. |
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Removal and distribution of iron, manganese, cobalt, and nickel within a Pennsylvania constructed wetland treating coal combustion by-product leachate; Wos:000174863000040; Times Cited: 15; ISI Web of Science |
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Call Number |
CBU @ c.wolke @ 17061 |
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122 |
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Author |
Skousen, J.; Jenkins, M. |
Title |
Acid mine drainage treatment costs with calcium oxide and the Aquafix machine |
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Journal Article |
Year |
2001 |
Publication |
Green Lands |
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31 |
Issue |
3 |
Pages |
46-51 |
Keywords |
acid mine drainage; chemical composition; Clay County West Virginia; coal mines; cost; decontamination; ground water; instruments; lime; Mary Ruth Mines; mines; pollution; Preston County West Virginia; remediation; sludge; surface water; techniques; United States; water pollution; water treatment; West Virginia 22, Environmental geology |
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0271-0110 |
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Acid mine drainage treatment costs with calcium oxide and the Aquafix machine; 2002-045348; illus. United States (USA); GeoRef; English |
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CBU @ c.wolke @ 5759 |
Serial |
246 |
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Author |
Sottnik, P.; Sucha, V. |
Title |
Moznosti upravy kysleho banskeho vytoku loziska Banska Stiavnica-Sobov. Remediation of acid mine drainage from Sobov Mine, Banska Stiavnica |
Type |
Journal Article |
Year |
2001 |
Publication |
Mineralia Slovaca |
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Volume |
33 |
Issue |
1 |
Pages |
53-60 |
Keywords |
acid mine drainage aluminum Banska Stiavnica Slovakia Central Europe copper Eh Europe gangue heavy metals iron manganese metals metamorphic rocks oxidation pH pollution precipitation pyrite quartzites reduction remediation Slovakia Sobov Mine sulfides vegetation waste disposal wetlands 22, Environmental geology |
Abstract |
A waste dump formed during the exploitation of quartzite deposit in Sobov mine (Slovakia) produces large quantity of acid mine drainage (AMD) which is mainly a product of pyrite oxidation. Sulphuric acid--the most aggressive oxidation product--attacks gangue minerals, mainly clays, as well. This process lead to a sharp decrease of the pH values (2-2.5) and increase of Fe, Al and SO (super 2-) (sub 4) contents (TDS = 20-30 mg/1). Passive treatment system was designed to remediate AMD. Chemical redox reactions along with microbial activity cause a precipitation of mobile contamination into a more stable forms. The sulphides are formed in the anaerobic cell, under reducing conditions. Fe-, Al- oxyhydroxides are precipitated in the aerobic part of the system. Precipitation decreases the Fe and Al contents along with immobilization of some heavy metal closely related to oxyhydroxides. Besides oxidation, the wetland vegetation is an active part of on aerobic cell. The system has been working effectively since September 1999. The pH values of outflowing water are apparently higher (6.2-6.8) and contents of dissolved elements (Fe from 2.260 to 4.1; Al from 900 to 0.18; Mn from 51 to 23; Cu from 4.95 to 0.03 mg/l) is significantly lowers. |
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0369-2086 |
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Moznosti upravy kysleho banskeho vytoku loziska Banska Stiavnica-Sobov. Remediation of acid mine drainage from Sobov Mine, Banska Stiavnica; 2004-084366; References: 21; illus. incl. sects. Slovak Republic (SVK); GeoRef; Slovakian |
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CBU @ c.wolke @ 16534 |
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235 |
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