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Kuyucak, N. (1998). Mining, the Environment and the Treatment of Mine Effluents. Int. J. Environ. Pollut., 10(2), 315–325.
Abstract: The environmental impact of mining on the ecosystem, including land, water and air, has become an unavoidable reality. Guidelines and regulations have been promulgated to protect the environment throughout mining activities from start-up to site decommissioning. In particular, the occurrence of acid mine drainage (AMD), due to oxidation of sulfide mineral wastes, has become the major area of concern to many mining industries during operations and after site decommissioning. AMD is characterized by high acidity and a high concentration of sulfates and dissolved metals. If it cannot be prevented or controlled, it must be treated to eliminate acidity, and reduce heavy metals and suspended solids before release to the environment. This paper discusses conventional and new methods used for the treatment of mine effluents, in particular the treatment of AMD.
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Coulton, R., Bullen, C., & Hallett, C. (2003). The design and optimisation of active mine water treatment plants. Land Contam. Reclam., 11(2), 273–280.
Abstract: This paper provides a 'state of the art' overview of active mine water treatment. The paper discusses the process and reagent selection options commonly available to the designer of an active mine water treatment plant. Comparisons are made between each of these options, based on technical and financial criteria. The various different treatment technologies available are reviewed and comparisons made between conventional precipitation (using hydroxides, sulphides and carbonates), high density sludge processes and super-saturation precipitation. The selection of reagents (quick lime, slaked lime, sodium hydroxide, sodium carbonate, magnesium hydroxide, and proprietary chemicals) is considered and a comparison made on the basis of reagent cost, ease of use, final effluent quality and sludge settling criteria. The choice of oxidising agent (air, pure oxygen, peroxide, etc.) for conversion of ferrous to ferric iron is also considered. Whole life costs comparisons (capital, operational and decommissioning) are made between conventional hydroxide precipitation and the high density sludge process, based on the actual treatment requirements for four different mine waters.
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Skousen, J., & Jenkins, M. (2001). Acid mine drainage treatment costs with calcium oxide and the Aquafix machine. Green Lands, 31(3), 46–51.
Keywords: acid mine drainage; chemical composition; Clay County West Virginia; coal mines; cost; decontamination; ground water; instruments; lime; Mary Ruth Mines; mines; pollution; Preston County West Virginia; remediation; sludge; surface water; techniques; United States; water pollution; water treatment; West Virginia 22, Environmental geology
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Heal, K. V., & Salt, C. A. (1999). Treatment of acidic metal-rich drainage from reclaimed ironstone mine spoil. Water Sci. Technol., 39(12), 141–148.
Abstract: Ironstone mine spoil leaves a legacy of land contamination and diffuse water pollution with acidic, metal-rich drainage. Reclamation for woodland may exacerbate water pollution due to spoil amendment and disturbance. Constructed wetland systems (CWS) are increasingly used for treating acid mine drainage but their performance is poorly understood. A combined approach was used to reclaim the Benhar ironstone spoil heap in Central Scotland. Trees have been planted in spoil treated with dried pelleted sewage sludge, limestone and peat. Spoil drainage (pH 2.7, 247 mg l-1 total Fe) passes through a CWS. Spoil throughflow, surface water chemistry and CWS performance were monitored for 12 months after reclamation. Acidity, Fe, Mn and Al concentrations declined in throughflow after reclamation, although this effect was not uniform. Soluble reactive P has been mobilised from the sewage sludge in residual areas of spoil acidity, but losses of other nutrients were short-lived. The CWS removes on average 33 % and 20-40 % of acidity and metal inputs but removal rates decrease in winter. Spoil reclamation has been successful in enabling vegetation establishment but has also increased Fe and Mn concentrations in surface drainage from the site, even after passage through the CWS.
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Okuda, T., Ema, S., Ishizaki, C., & Fujimoto, J. (1991). Mine drainage treatment and ferrite sludge application. NEC Technical Journal, 44(5), 4–16.
Abstract: The `ferrite process' is an excellent method for treating waste water containing iron and arsenic, but cannot be directly applied to mine drainage where silicon and aluminum ions are present, because they strongly inhibit ferrite formation. As a result of the development of related technologies such as the elimination of silicon, the concentration of iron, and the oxidation of ferrous ions using iron-oxidation bacteria, a new ferrite formation process has been developed and applied to the mine drainage of the Matsuo Mine. The paper discusses the application of the ferrite sludge to magnetic marking materials, magnetic fluid for metal separation and recovery, and the semiactive magnetic damper is described. The related technologies which will be expected to play an important role in solving the environmental problems are also described. These technologies will change the ferrite sludge to beneficial materials, which can be used for carbon dioxide decomposing catalysts, reuse of dry batteries, fish gathering blocks, and cement tracer for ground improvement
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