Records |
Author |
Barton, C.D.; Karathanasis, A.D. |
Title |
Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage |
Type |
Book Chapter |
Year |
1997 |
Publication |
AAPG Eastern Section and the Society for Organic Petrology joint meeting; abstracts |
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Issue |
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Pages |
1545 |
Keywords |
acid mine drainage aerobic environment air-water interface anaerobic environment attenuation buffers constructed wetlands controls diffusion iron manganese metals mineral composition pollution precipitation processes SEM data solubility solution sulfate ion sulfur wetlands X-ray diffraction data 22, Environmental geology |
Abstract |
The use of constructed wetlands for acid mine drainage amelioration has become a popular alternative to conventional treatment methods, however, the metal attenuation processes of these systems are poorly understood. Precipitates from biotic and abiotic zones of a staged constructed wetland treating high metal load (approx. equal to 1000 mg L (super -1) ) and low pH (approx. 3.0) acid mine drainage were characterized by chemical dissolution, x-ray diffraction, thermal analysis and scanning electron microscopy. Characterization of abiotic/aerobic zones within the treatment system suggest the presence of crystalline iron oxides and hydroxides such as hematite, lepidocrocite, goethite, and jarosite. At the air/water interface of initial abiotic treatment zones, SO (sub 4) /Fe ratios were low enough (<2.0) for the formation of jarosite and goethite, but as the ratio increased due to treatment and subsequent reductions in iron concentration, jarosite was transformed to other Fe-oxyhydroxysulfates and goethite formation was inhibited. In addition, elevated pH conditions occurring in the later stages of treatment promoted the formation of amorphous iron oxyhydroxides. Biotic wetland cell substrate characterizations suggest the presence of amorphous iron minerals such as ferrihydrite and Fe(OH) (sub 3) . Apparently, high Fe (super 3+) activity, low Eh and low oxygen diffusion rates in the anaerobic subsurface environment inhibit the kinetics of crystalline iron precipitation. Some goethite, lepidocrocite and hematite, however, were observed near the surface in biotic areas and are most likely attributable to increased oxygen levels from surface aeration and/or oxygen transport by plant roots. Alkalinity generation from limestone dissolution within the substrate and bacterially mediated sulfate reduction also has a significant role on the mineral retention process. The formation of gypsum, rhodochrocite and siderite are by-products of alkalinity generating reactions in this system and may have an impact on S, Mn, and Fe solubility controls. Moreover, the buffering of acidity through excess alkalinity appears to facilitate the precipitation and retention of metals within the system. |
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AAPG Bulletin |
Place of Publication |
81 |
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Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage; GeoRef; English; 1997-067790; AAPG Eastern Section and the Society for Organic Petrology joint meeting, Lexington, KY, United States, Sep. 27-30, 1997 |
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CBU @ c.wolke @ 16630 |
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70 |
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Author |
Stewart, B.R. |
Title |
The influence of fly ash additions on acid mine drainage production from coarse coal refuse |
Type |
Book Whole |
Year |
1996 |
Publication |
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Issue |
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Pages |
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Keywords |
acid mine drainage; acidic composition; alkalic composition; alkalinity; ash; coal; controls; copper; diffusion; dissolved materials; experimental studies; geologic hazards; hydraulic conductivity; iron; leachate; leaching; manganese; metals; organic residues; oxidation; oxygen; pH; pollutants; pollution; sedimentary rocks; soil treatment; soils; sorption; sulfate ion; waste disposal; water quality 22, Environmental geology |
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Ph.D. thesis |
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Virginia Polytechnic Institute and State University, |
Place of Publication |
Blacksburg |
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The influence of fly ash additions on acid mine drainage production from coarse coal refuse; GeoRef; English |
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CBU @ c.wolke @ 6351 |
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230 |
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Author |
Schwartz, M.O.; Ploethner, D. |
Title |
From mine water to drinking water; heavy-metal removal by carbonate precipitation in the Grootfontein-Omatako Canal, Namibia |
Type |
Book Chapter |
Year |
1999 |
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Keywords |
Africa; aluminum; cadmium; canals; carbonates; copper; drinking water; geochemistry; Grootfontein-Omatako Canal; heavy metals; hydrochemistry; iron; lead; manganese; metallogenic provinces; metals; mine drainage; mineral deposits, genesis; mines; Namibia; policy; precipitation; purification; Southern Africa; transport; water management; water treatment 22, Environmental geology |
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Bundesanst. fuer Geowiss. und Rohstoffe |
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Hanover |
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From mine water to drinking water; heavy-metal removal by carbonate precipitation in the Grootfontein-Omatako Canal, Namibia; GeoRef; English; 2002-033925; International congress on Mine, water and environment, Seville, Spain, Sept. 13, 1999 References: 7; 2 tables, sketch maps |
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CBU @ c.wolke @ 5929 |
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250 |
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Author |
Rabenhorst, M.C.; James, B.R. |
Title |
Acid mine drainage remediation via sulfidization in wetlands Fiscal year 1992 annual report |
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RPT |
Year |
1993 |
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acid mine drainage; anaerobic environment; Appalachians; concentration; decontamination; ferric iron; iron; manganese; marshes; Maryland; metals; mires; North America; oxidation; pollutants; pollution; pore water; remediation; sulfidization; transport; United States; water quality; water treatment; wetlands 22, Environmental geology |
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University of Maryland, W.R.R.C.C.P.M.D.U.S. |
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Acid mine drainage remediation via sulfidization in wetlands Fiscal year 1992 annual report; 1998-034327; GeoRef; English; illus. incl. 1 table University of Maryland, Water Resources Research Center, College Park, MD, United States |
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CBU @ c.wolke @ 6684 |
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267 |
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Author |
Hellier, W.W.; Giovannitti, E.F.; Slack, P.T. |
Title |
Best professional judgement analysis for constructed wetlands as a best available technology for the treatment of post-mining groundwater seeps |
Type |
Book Chapter |
Year |
1994 |
Publication |
Special Publication – United States. Bureau of Mines, Report: BUMINES-SP-06A-94 |
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Pages |
60-69 |
Keywords |
acid mine drainage; coal mines; geochemistry; ground water; iron; manganese; metals; mines; mining; mining geology; open-pit mining; pH; pollution; reclamation; remediation; seepage; surface mining; tailings; waste disposal; wetlands 22, Environmental geology |
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Proceedings of the International land reclamation and mine drainage conference and Third international conference on The abatement of acidic drainage; Volume 1 of 4; Mine drainage |
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Best professional judgement analysis for constructed wetlands as a best available technology for the treatment of post-mining groundwater seeps; GeoRef; English; 2007-045158; International land reclamation and mine drainage conference and Third international conference on The abatement of acidic drainage, Pittsburgh, PA, United States, April 24-29, 1994 References: 9; illus. incl. 2 tables |
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no |
Call Number |
CBU @ c.wolke @ 6568 |
Serial |
353 |
Permanent link to this record |