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Boonstra, J., van Lier, R., Janssen, G., Dijkman, H., & Buisman, C. J. N. (1999). Biological treatment of acid mine drainage. In R. Amils, & A. Ballester (Eds.), Process Metallurgy, vol.9, Part B (pp. 559–567). Biohydrometallurgy and the environment toward the mining of the 21st century; proceedings of the International biohydrometallurgy symposium IBS'99, Part B, Molecular biology, biosorption, bioremediation.
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Bolzicco, J., Carrera, J., & Ayora, C. (2004). Eficiencia de la barrera permeable reactiva de Aznalcollar (Sevilla, Espana) como remedio de aguas acidas de mina. Reactive permeable disposal barrier at Aznalcollar Mine, Seville, Spain; as remediation for acid mine drainage. Revista Latino-Americana de Hidrogeologia, 4, 27–34.
Abstract: As a result of the collapse of a mine tailing dam in april 1998 about 40 km of the Agrio and Guadiamar valleys were covered with a layer of pyrite sludge. Although most of the sludge was removed, a small amount remains in the soil of the Agrio valley and the aquifer remains polluted with acid water (ph<4) and metals (10 mg/L Zn, 5 mg/L Cu and Al). A permeable reactive barrier was build across the aquifer to increase the alcalinity and retain the metals. The barrier is made up of three sections of 30 m longX1.4 m thickX5 m deep (average) containing different proportions of limestone gravel, organic compost and zero-valent iron. The residence time of the water in the barrier is about two days. Within the barrier, the pH values increase to near neutral mainly due to calcite dissolution. Metals co-precipitate as oxyhydroxides, and they are also adsorbed on the organic matter surface. Down-stream the barrier, the total pollution removal is around 60-90% for Zn and Cu, and from 50 to 90% for Al and acidity.
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Adam, K. (2003). Solid wastes management in sulphide mines: From waste characterisation to safe closure of disposal sites. Minerals and Energy Raw Materials Report, 18(4), 25–35.
Abstract: Environmentally compatible Waste Management schemes employed by the European extractive industry for the development of new projects, and applied in operating sulphide mines, are presented in this study. Standard methodologies used to assess the geotechnical and geochemical properties of the solid wastes stemming from mining and processing of sulphidic metal ores are firstly given. Based on waste properties, the measures applied to ensure the environmentally safe recycling and disposal of sulphidic wastes are summarised. Emphasis is given on the novel techniques developed to effectively prevent and mitigate the acid drainage phenomenon from sulphidic mine wastes and tailings. Remediation measures taken to minimise the impact from waste disposal sites in the post-closure period are described.
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Younger, P. L. (2000). Holistic remedial strategies for short- and long-term water pollution from abandoned mines. Transactions of the Institution of Mining and Metallurgy Section a-Mining Technology, 109, A210–A218.
Abstract: Where mining proceeds below the water-table-as it has extensively in Britain and elsewhere-water ingress is not only a hindrance during mineral extraction but also a potential liability after abandonment. This is because the cessation of dewatering that commonly follows mine closure leads to a rise in the water-table and associated, often rapid, changes in the chemical regime of the subsurface. Studies over the past two decades have provided insights into the nature and time-scales of these changes and provide a basis for rational planning of mine-water management during and after mine abandonment. The same insights into mine-water chemistry provide hints for the efficient remediation of pollution (typically due to Fe, Mn and Al and, in some cases, Zn, Cd, Pb and other metals). Intensive treatment (by chemical dosing with enhanced sedimentation or alternative processes, such as sulphidization or reverse osmosis) is often necessary only during the first few years following complete flooding of mine voids. Passive treatment (by the use of gravity-flow geochemical reactors and wetlands) may be both more cost-effective and ecologically more responsible in the long term. By the end of 1999 a total of 28 passive systems had been installed at United Kingdom mine sites, including examples of system types currently unique to the United Kingdom. Early performance data for all the systems are summarized and shown to demonstrate the efficacy of passive treatment when appropriately applied.
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Wingenfelder, U., Hansen, C., Furrer, G., & Schulin, R. (2005). Removal of heavy metals from mine waters by natural zeolites. Environ Sci Technol, ES & T, 39(12), 4606–4613.
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