| Records |
| Author |
Conca, J.L.; Wright, J. |
| Title |
An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd |
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Journal Article |
| Year |
2006 |
Publication |
Appl. Geochem. |
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| Volume |
21 |
Issue |
12 |
Pages |
2188-2200 |
| Keywords |
Pollution and waste management non radioactive Groundwater quality apatite groundwater remediation zinc lead cadmium acid mine drainage copper sulfate nitrate permeability water treatment precipitation chemistry |
| Abstract |
Phosphate-induced metal stabilization involving the reactive medium Apatite II(TM) [Ca10-xNax(PO4)6-x(CO3)x(OH)2], where x < 1, was used in a subsurface permeable reactive barrier (PRB) to treat acid mine drainage in a shallow alluvial groundwater containing elevated concentrations of Zn, Pb, Cd, Cu, SO4 and NO3. The groundwater is treated in situ before it enters the East Fork of Ninemile Creek, a tributary to the Coeur d'Alene River, Idaho. Microbially mediated SO4 reduction and the subsequent precipitation of sphalerite [ZnS] is the primary mechanism occurring for immobilization of Zn and Cd. Precipitation of pyromorphite [Pb10(PO4)6(OH,Cl)2] is the most likely mechanism for immobilization of Pb. Precipitation is occurring directly on the original Apatite II. The emplaced PRB has been operating successfully since January of 2001, and has reduced the concentrations of Cd and Pb to below detection (2 μg L-1), has reduced Zn to near background in this region (about 100 μg L-1), and has reduced SO4 by between 100 and 200 mg L-1 and NO3 to below detection (50 μg L-1). The PRB, filled with 90 tonnes of Apatite II, has removed about 4550 kg of Zn, 91 kg of Pb and 45 kg of Cd, but 90% of the immobilization is occurring in the first 20% of the barrier, wherein the reactive media now contain up to 25 wt% Zn. Field observations indicate that about 30% of the Apatite II material is spent (consumed). |
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0883-2927 |
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Dec.; An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd; Science Direct |
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CBU @ c.wolke @ 17248 |
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44 |
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Hulshof, A.H.M.; Blowes, D.W.; Douglas Gould, W. |
| Title |
Evaluation of in situ layers for treatment of acid mine drainage: A field comparison |
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Journal Article |
| Year |
2006 |
Publication |
Water Res |
Abbreviated Journal |
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| Volume |
40 |
Issue |
9 |
Pages |
1816-1826 |
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mine water Pollution and waste management non radioactive Groundwater problems and environmental effects acid mine drainage organic carbon oxidation microbial activity drainage groundwater pollution Bacteria microorganisms Contamination Groundwater Barriers Drainage Treatment |
| Abstract |
Reactive treatment layers, containing labile organic carbon, were evaluated to determine their ability to promote sulfate reduction and metal sulfide precipitation within a tailings impoundment, thereby treating tailings effluent prior to discharge. Organic carbon materials, including woodchips and pulp waste, were mixed with the upper meter of tailings in two separate test cells, a third control cell contained only tailings. In the woodchip cell sulfate reduction rates were 500 mg L-1 a-1, (5.2 mmol L-1 a-1) this was coupled with the gradual removal of 350 mg L-1 Zn (5.4 mmol L-1). Decreased δ13CDIC values from -3‰ to as low as -12‰ indicated that sulfate reduction was coupled with organic carbon oxidation. In the pulp waste cell the most dramatic change was observed near the interface between the pulp waste amended tailings and the underlying undisturbed tailings. Sulfate reduction rates were 5000 mg L-1 a-1 (52 mmol L-1 a-1), Fe concentrations decreased by 80–99.5% (148 mmol L-1) and Zn was consistently <5 mg L-1. Rates of sulfate reduction and metal removal decreased as the pore water migrated upward into the shallower tailings. Increased rates of sulfate reduction in the pulp waste cell were consistent with decreased δ13CDIC values, to as low as -22‰, and increased populations of sulfate reducing bacteria. Lower concentrations of the nutrients, phosphorus, organic carbon and nitrogen in the woodchip material contribute to the lower sulfate reduction rates observed in the woodchip cell. |
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0043-1354 |
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May; Evaluation of in situ layers for treatment of acid mine drainage: A field comparison; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10040.pdf; Science Direct |
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CBU @ c.wolke @ 10040 |
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49 |
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Fisher, T.S.R.; Lawrence, G.A. |
| Title |
Treatment of acid rock drainage in a meromictic mine pit lake |
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Journal Article |
| Year |
2006 |
Publication |
Journal of environmental engineering |
Abbreviated Journal |
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| Volume |
132 |
Issue |
4 |
Pages |
515-526 |
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Pollution and waste management non radioactive Groundwater problems and environmental effects geological abstracts: environmental geology (72 14 2) geomechanics abstracts: excavations (77 10 10) meromictic lake acid mine drainage mine waste copper water pollution Bacteria microorganisms Canada Vancouver Island British Columbia North America |
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The Island Copper Mine pit near Port Hardy, Vancouver Island, B.C., Canada, was flooded in 1996 with seawater and capped with fresh water to form a meromictic (permanently stratified) pit lake of maximum depth 350 m and surface area 1.72 km2. The pit lake is being developed as a treatment system for acid rock drainage. The physical structure and water quality has developed into three distinct layers: a brackish and well-mixed upper layer; a plume stirred intermediate layer; and a thermally convecting lower layer. Concentrations of dissolved metals have been maintained well below permit limits by fertilization of the surface waters. The initial mine closure plan proposed removal of heavy metals by metal-sulfide precipitation via anaerobic sulfate-reducing bacteria, once anoxic conditions were established in the intermediate and lower layers. Anoxia has been achieved in the lower layer, but oxygen consumption rates have been less than initially predicted, and anoxia has yet to be achieved in the intermediate layer. If anoxia can be permanently established in the intermediate layer then biogeochemical removal rates may be high enough that fertilization may no longer be necessary. < copyright > 2006 ASCE. |
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Prof. G.A. Lawrence, Univ. of British Columbia, Vancouver, BC V6T 1Z4, Canada lawrence@civil.ubc.ca |
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0733-9372 |
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Apr.; Treatment of acid rock drainage in a meromictic mine pit lake; 2873922; United-States 38; Geobase |
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CBU @ c.wolke @ 17494 |
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72 |
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| Author |
Sasaki, K. |
| Title |
Immobilization of Mn(II) ions by a Mn-oxidizing fungus – Paraconiothyrium sp.-like strain at neutral pHs |
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Journal Article |
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2006 |
Publication |
Mater. Trans. |
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47 |
Issue |
10 |
Pages |
2457-2461 |
| Keywords |
mine water treatment |
| Abstract |
A Mn-oxidizing fungus was isolated from a constructed wetland of Hokkaido (Japan), which is receiving the Mn-impacted drainage, and genetically and morphologically identified as Paraconiothyrium sp.-like strain. The optimum pHs were 6.45-6.64, where is more acidic than those of previously reported Mn-oxidizing fungi. Too much nutrient inhibited fungal Mn-oxidation, and too little nutrient also delayed Mn oxidation even at optimum pH. In order to achieve the oxidation of high concentrations of Mn like mine drainage containing several hundreds g-m(-3) of Mn, it is important to find the best mix ratio among the initial Mn concentrations, inocolumn size and nutrient concentration. The strain has still Mn-tolerance with more than 380 g-m(-3) of Mn, but high Mn(II) oxidation was limited by pH control and supplied nutrient amounts. The biogenic Mn deposit was poorly crystallized birnessite. The strain is an unique Mn-oxidizing fungus having a high Mn tolerance and weakly acidic tolerance, since there has been no record about the property of the strain. There is a potentiality to apply the strain to the environmental bioremediation. |
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Immobilization of Mn(II) ions by a Mn-oxidizing fungus – Paraconiothyrium sp.-like strain at neutral pHs; Wos:000242429300002; Times Cited: 0; ISI Web of Science |
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no |
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CBU @ c.wolke @ 16940 |
Serial |
103 |
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| Author |
Bearcock, J.M. |
| Title |
Accelerated precipitation of ochre for mine water remediation |
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Journal Article |
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2006 |
Publication |
Geochim. Cosmochim. Acta |
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70 |
Issue |
18 |
Pages |
A42-A42 |
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mine water treatment |
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Accelerated precipitation of ochre for mine water remediation; Wos:000241374200094; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 16919 |
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104 |
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