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Author Burgess, J.E.; Stuetz, R.M.
Title Activated Sludge for the Treatment of Sulphur-rich Wastewaters Type (up) Journal Article
Year 2002 Publication Miner. Eng. Abbreviated Journal
Volume 15 Issue 11 Pages 839-846
Keywords acid rock drainage biooxidation biotechnology environmental waste processing acid-mine drainage sulfate-reducing bacteria biological treatment waste-water metals acclimation remediation oxidation reduction removal
Abstract The aim of this investigation was to assess the potential of activated sludge for the remediation of sulphur-rich wastewaters. A pilot-scale activated sludge plant was acclimatised to a low load of sulphide and operated as a flow-through unit. Additional sludge samples from different full-scale plants were compared with the acclimatised and unacclimatised sludges using batch absorption tests. The effects of sludge source and acclimatisation on the ability of the sludge to biodegrade high loads of sulphide were evaluated. Acclimatisation to low-sulphide concentrations enabled the sludge to degrade subsequent high loads which were toxic to unacclimatised sludge. Acclimatisation was seen to be an effect of selection pressure on the biomass, suggesting that the treatment capability of activated sludge will develop after acclimation, indicating potential for treatment of acid mine drainage (AMD) by a standard wastewater treatment process. Existing options for biological treatment of AMD are described and the potential of activated sludge treatment for AMD discussed in comparison with existing technologies. (C) 2002 Elsevier Science Ltd.
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ISSN 0892-6875 ISBN Medium
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Notes Nov.; Activated Sludge for the Treatment of Sulphur-rich Wastewaters; Isi:000179970500009; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10093.pdf; AMD ISI | Wolkersdorfer Approved no
Call Number CBU @ c.wolke @ 10093 Serial 40
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Author Gazea, B.; Adam, K.; Kontopoulos, A.
Title A review of passive systems for the treatment of acid mine drainage Type (up) Journal Article
Year 1996 Publication Minerals Engineering Abbreviated Journal
Volume 9 Issue 1 Pages 23-42
Keywords Acid rock drainage bacteria environmental pollution
Abstract This review presents the current state of development of the passive mine water treatment technologies. The background of passive treatment is reviewed and the chemical and biological processes involved in metals removal and acidity neutralisation are detailed. The types of currently existing passive treatment technologies and their applicability range as defined by the mine water chemistry are presented. Finally, the performance of passive systems constructed for the treatment of acid mine drainage from both coal and sulphide metal mines is summarised.
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ISSN 0892-6875 ISBN Medium
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Notes Jan.; A review of passive systems for the treatment of acid mine drainage; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10076.pdf; Science Direct Approved no
Call Number CBU @ c.wolke @ 17468 Serial 43
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Author Hulshof, A.H.M.; Blowes, D.W.; Douglas Gould, W.
Title Evaluation of in situ layers for treatment of acid mine drainage: A field comparison Type (up) Journal Article
Year 2006 Publication Water Res Abbreviated Journal
Volume 40 Issue 9 Pages 1816-1826
Keywords mine water Pollution and waste management non radioactive Groundwater problems and environmental effects acid mine drainage organic carbon oxidation microbial activity drainage groundwater pollution Bacteria microorganisms Contamination Groundwater Barriers Drainage Treatment
Abstract Reactive treatment layers, containing labile organic carbon, were evaluated to determine their ability to promote sulfate reduction and metal sulfide precipitation within a tailings impoundment, thereby treating tailings effluent prior to discharge. Organic carbon materials, including woodchips and pulp waste, were mixed with the upper meter of tailings in two separate test cells, a third control cell contained only tailings. In the woodchip cell sulfate reduction rates were 500 mg L-1 a-1, (5.2 mmol L-1 a-1) this was coupled with the gradual removal of 350 mg L-1 Zn (5.4 mmol L-1). Decreased δ13CDIC values from -3‰ to as low as -12‰ indicated that sulfate reduction was coupled with organic carbon oxidation. In the pulp waste cell the most dramatic change was observed near the interface between the pulp waste amended tailings and the underlying undisturbed tailings. Sulfate reduction rates were 5000 mg L-1 a-1 (52 mmol L-1 a-1), Fe concentrations decreased by 80–99.5% (148 mmol L-1) and Zn was consistently <5 mg L-1. Rates of sulfate reduction and metal removal decreased as the pore water migrated upward into the shallower tailings. Increased rates of sulfate reduction in the pulp waste cell were consistent with decreased δ13CDIC values, to as low as -22‰, and increased populations of sulfate reducing bacteria. Lower concentrations of the nutrients, phosphorus, organic carbon and nitrogen in the woodchip material contribute to the lower sulfate reduction rates observed in the woodchip cell.
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ISSN 0043-1354 ISBN Medium
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Notes May; Evaluation of in situ layers for treatment of acid mine drainage: A field comparison; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10040.pdf; Science Direct Approved no
Call Number CBU @ c.wolke @ 10040 Serial 49
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Author Tsukamoto, T.K.; Miller, G.C.
Title Methanol as a Carbon Source for Microbiological Treatment of Acid Mine Drainage Type (up) Journal Article
Year 1999 Publication Water Res. Abbreviated Journal
Volume 33 Issue 6 Pages 1365-1370
Keywords mine water treatment mining activity sulfate-reducing bacteria microbial activity acid mine drainage methanol passive treatment systems sulfate-reducing bacterium sp-nov
Abstract Sulfate reducing passive bioreactors are increasingly being used to remove metals and raise the pH of acidic waste streams from abandoned mines. These systems commonly use a variety of organic substrates (i.e. manure, wood chips) for sulfate reduction. The effectiveness of these systems decreases as easily accessible reducing equivalents are consumed in the substrate through microbial activity. Using column studies at room temperature (23-26 degrees C), we investigated the addition of lactate and methanol to a depleted manure substrate as a method to reactivate a bioreactor that had lost >95% of sulfate reduction activity. A preliminary experiment compared sulfate removal in gravity fed, flow through bioreactors in which similar masses of each substrate were added to the influent solution. Addition of 148 mg/l lactate resulted in a 69% reduction in sulfate concentration from 300 to 92 mg/l, while addition of 144 mg/l methanol resulted in an 88% reduction in sulfate concentration from 300 to 36 mg/l. Because methanol was found to be an effective sulfate reducing substrate, it was chosen for further experiments due to its inherent physical properties (cost, low freezing point and low viscosity liquid) that make it a superior substrate for remote, high elevation sites where freezing temperatures would hamper the use of aqueous solutions. In these column studies, water containing sulfate and ferrous iron was gravity-fed through the bioreactor columns, along with predetermined methanol concentrations containing reducing equivalents to remove 54% of the sulfate. Following an acclimation period for the columns, sulfate concentrations were reduced from of 900 mg/l in the influent to 454 mg/l in the effluent, that reflects a 93% efficiency of electrons from the donor to the terminal electron acceptor. Iron concentrations were reduced from 100 to 2 mg/l and the pH increased nearly 2 units. (C) 1999 Elsevier Science Ltd.
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ISSN 0043-1354 ISBN Medium
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Notes Apr; Methanol as a Carbon Source for Microbiological Treatment of Acid Mine Drainage; Isi:000079485400004; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10197.pdf; AMD ISI | Wolkersdorfer Approved no
Call Number CBU @ c.wolke @ 10197 Serial 50
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Author Foucher, S.; Battaglia-Brunet, F.; Ignatiadis, I.; Morin, D.
Title Treatment by sulfate-reducing bacteria of Chessy acid-mine drainage and metals recovery Type (up) Journal Article
Year 2001 Publication Chemical Engineering Science Abbreviated Journal
Volume 56 Issue 4 Pages 1639-1645
Keywords Acid mine drainage Sulfate-reducing bacteria Sulfide precipitation Hydrogen transfer Fixed bed column reactor
Abstract Acid-mine drainage can contain high concentrations of heavy metals and release of these contaminants into the environment is generally avoided by lime neutralization. However, this classical treatment is expensive and generates large amounts of residual sludge. The selective precipitation of metals using H2S produced biologically by sulfate-reducing bacteria has been proposed as an alternative process. Here, we report on experiments using real effluent from the disused Chessy-les-Mines mine-site at the laboratory pilot scale. A fixed-bed bioreactor, fed with an H2/CO2 mixture, was used in conjunction with a gas stripping column. The maximum rate of hydrogen transfer in the bioreactor was determined before inoculation. kLa was deduced from measurements of O2 using Higbie and Danckwert's models which predict a dependence on diffusivity. The dynamic method of physical absorption and desorption was used. The maximum rate of H2 transfer suggests that this step should not be a limiting factor. However, an increase in H2 flow rate was observed to induce an increase in sulfate reduction rate. For the precipitation step, the gas mixture from the bioreactor was bubbled into a stirred reactor fed with the real effluent. Cu and Zn could be selectively recovered at pH=2.8 and pH=3.5, respectively. Other impurities such as Ni and Fe could also be removed at pH=6 by sulfide precipitation. Part of the outlet stream from the bioreactor was used to regulate and maintain the pH during sulfide precipitation by feeding the outlet stream back into the bioreactor. The replacement of synthetic medium with real effluent had a positive effect on sulfate reduction rate which increased by 30-40%. This improvement in bacterial efficiency may be related to the large range of oligo-elements provided by the mine-water. The maximum sulfate reduction rate observed with the real effluent was 200 mgl-1 h-1, corresponding to a residence time of 0.9 day. A preliminary cost estimation based on a treatment rate of 5 m3 h-1 of a mine effluent containing 5 gl-1 SO42- is presented.
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ISSN 0009-2509 ISBN Medium
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Notes Feb.; Treatment by sulfate-reducing bacteria of Chessy acid-mine drainage and metals recovery; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10064.pdf; Science Direct Approved no
Call Number CBU @ c.wolke @ 10064 Serial 54
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