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Author Groudev, S.N.
Title (down) Treatment of acid mine drainage by a natural wetland Type Journal Article
Year 2002 Publication Wetlands and Remediation Ii Abbreviated Journal
Volume Issue Pages 133-139
Keywords mine water treatment
Abstract Acid drainage waters generated in the copper ore deposit Elshitza. Central Bulgaria, were treated by a natural wetland located in the deposit. The waters had a pH in the range of about 2.5 – 3.5 and contained copper, cadmium, arsenic, iron, manganese and sulphates as main pollutants. The watercourse through the wetland covered a distance of about 100 in and the water flow rate varied in the range of about 0.5 – 2.0 1/s. The wetland was characterized by an abundant water and emergent vegetation and a diverse microflora. Phragmites communis was the prevalent plant species in the wetland but species of the genera Scirpus, Typha, Juncus, Carex and Poa as well as different algae were also well present. It was found that an efficient removal of the pollutants was achieved and their residual concentrations in the wetland effluents were decreased below the relevant permissible levels for water intended for use in the agriculture and/or industry. The removal was clue to different processes but the microbial dissimilatory sulphate reduction and the sorption of pollutants by the organic matter and clay minerals present in the wetland played the main role. Negative effects of the pollutants on the growth and activity of the indigenous plant and microbial communities were not observed.
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Notes Treatment of acid mine drainage by a natural wetland; Isip:000175585500017; Times Cited: 0; ISI Web of Science Approved no
Call Number CBU @ c.wolke @ 17039 Serial 159
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Author Foucher, S.; Battaglia-Brunet, F.; Ignatiadis, I.; Morin, D.
Title (down) Treatment by sulfate-reducing bacteria of Chessy acid-mine drainage and metals recovery Type Journal Article
Year 2001 Publication Chemical Engineering Science Abbreviated Journal
Volume 56 Issue 4 Pages 1639-1645
Keywords Acid mine drainage Sulfate-reducing bacteria Sulfide precipitation Hydrogen transfer Fixed bed column reactor
Abstract Acid-mine drainage can contain high concentrations of heavy metals and release of these contaminants into the environment is generally avoided by lime neutralization. However, this classical treatment is expensive and generates large amounts of residual sludge. The selective precipitation of metals using H2S produced biologically by sulfate-reducing bacteria has been proposed as an alternative process. Here, we report on experiments using real effluent from the disused Chessy-les-Mines mine-site at the laboratory pilot scale. A fixed-bed bioreactor, fed with an H2/CO2 mixture, was used in conjunction with a gas stripping column. The maximum rate of hydrogen transfer in the bioreactor was determined before inoculation. kLa was deduced from measurements of O2 using Higbie and Danckwert's models which predict a dependence on diffusivity. The dynamic method of physical absorption and desorption was used. The maximum rate of H2 transfer suggests that this step should not be a limiting factor. However, an increase in H2 flow rate was observed to induce an increase in sulfate reduction rate. For the precipitation step, the gas mixture from the bioreactor was bubbled into a stirred reactor fed with the real effluent. Cu and Zn could be selectively recovered at pH=2.8 and pH=3.5, respectively. Other impurities such as Ni and Fe could also be removed at pH=6 by sulfide precipitation. Part of the outlet stream from the bioreactor was used to regulate and maintain the pH during sulfide precipitation by feeding the outlet stream back into the bioreactor. The replacement of synthetic medium with real effluent had a positive effect on sulfate reduction rate which increased by 30-40%. This improvement in bacterial efficiency may be related to the large range of oligo-elements provided by the mine-water. The maximum sulfate reduction rate observed with the real effluent was 200 mgl-1 h-1, corresponding to a residence time of 0.9 day. A preliminary cost estimation based on a treatment rate of 5 m3 h-1 of a mine effluent containing 5 gl-1 SO42- is presented.
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ISSN 0009-2509 ISBN Medium
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Notes Feb.; Treatment by sulfate-reducing bacteria of Chessy acid-mine drainage and metals recovery; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10064.pdf; Science Direct Approved no
Call Number CBU @ c.wolke @ 10064 Serial 54
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Author Mitchell, P.; Rybock, J.; Wheaton, A.
Title (down) Treatment and prevention of ARID using silica micro encapsulation Type Book Chapter
Year 1999 Publication Proceedings of the 16th annual National meeting of the American Society for Surface Mining and Reclamation; Mining and reclamation for the next millennium Abbreviated Journal
Volume Issue Pages 657-661
Keywords acid mine drainage Bunker Hill Mine Idaho mines pollution Shoshone County Idaho United States water treatment 22, Environmental geology
Abstract In response to the known drawbacks of liming and the ever-increasing regulatory demands on the mining industry, KEECO has developed a silica micro encapsulation (SME) process. SME is a cost-effective, high performance reagent that is utilized in conjunction with simple chemical delivery systems. By encapsulating metals in a silica matrix formation and rapidly precipitating them into a sand-like sludge, it offers all the advantages of liming without the negative drawbacks. Utilizing an injection technique via a high shear mixing device, a slurry from of the SME product called KB-1 (super TM) was applied to ARD at the Bunker Hill Mine in Idaho and to ARD pumped from collection ponds at a remote mine site in the Sierra Nevada Mountains. Flow rates at both sites ranged from 500 to 800 gallons per minute. Treated water from the Bunker Hill Mine operation achieved the site's NPDES criteria for all evaluated metals and U.S. Drinking Water quality for arsenic, cadmium, chromium, lead and zinc with a dosage rate of 1.34 grams KB-1 (super TM) per liter. Treated water from the Sierra Nevada project focused on the control of aluminum, arsenic, copper, iron and nickel. All water samples displayed a >99.5% reduction in these metals, as well as an 84%-87% reduction in the concentration of sulfate. Testing on sludge generated from both operations achieved TCLP Action Limits. The SME process is currently under evaluation as a means to coat the pyrite surfaces of newly generated mine tailings to prevent oxidation and future acid generation.
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Publisher Place of Publication 16 Editor Bengson, S.A.; Bland, D.M.
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Notes Treatment and prevention of ARID using silica micro encapsulation; GeoRef; English; 2001-047986; 16th annual National meeting of the American Society for Surface Mining and Reclamation, Scottsdale, AZ, United States, Aug. 13-19, 1999 2 tables Approved no
Call Number CBU @ c.wolke @ 16602 Serial 297
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Author Ericsson, B.; Hallmans, B.
Title (down) Treatment and Disposal of Saline Waste-water from Coal-mines in Poland Type Journal Article
Year 1994 Publication Desalination Abbreviated Journal
Volume 98 Issue 1-3 Pages 239-248
Keywords mine water
Abstract Some Polish coal mines are reviewed with respect to the disposal of saline wastewater into rivers and its environmental impact. The drainage water from mines has a daily contribution of, in the order of magnitude, 6,500 tons chlorides (Cl-) and 0.5 tons sulphates (SO42-) to the rivers Wisla and Odra. The river Wisla contributes to about 55 % of the water resources in Poland. This report is based on a part of a commission for the Ministry of Environmental Protection, National Resources and Forestry ofPoland by COWI-VBB VIAK joint venture.Different treatment and disposal schemes are described and compared from a technical-economical point of view, out of which methods for desalination with zero discharge as well as deep well injection are the most promising ones.The desalination methods include reverse osmosis (RO) plant, thermal powered desalination and crystallization plant as well as facilities for dewatering and drying of sodium chloride (NaCl) to be sold in Poland and/or on the export market, The valuable main products are potable water, boiler feed water and sodium chloride. A special problem in this connection may be the radioactivity in the wastewater from some of the mines. Special treatment methods for radioactivity removal in the selected treatment and disposal scheme for the mine wastewater are discussed with respect to the effects of radioactivity on the saleability of the recovered salt. In addition methods for recovery of the by-products magnesium hydroxide, iodine and bromine are considered from the point of view of economy and environmental protection.Finally, the desalination project in Katowice for the coal mines Debiensko and Budryk is now in the end of the construction phase. Some modifications of the original design ace shown.
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ISSN 0011-9164 ISBN Medium
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Notes Treatment and Disposal of Saline Waste-water from Coal-mines in Poland; Isi:A1994pp05300022; AMD ISI | Wolkersdorfer Approved no
Call Number CBU @ c.wolke @ 17337 Serial 52
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Author Taylor, J.; Waters, J.
Title (down) Treating ARD; how, when, where and why Type Journal Article
Year 2003 Publication Mining Environmental Management Abbreviated Journal
Volume 11 Issue 3 Pages 6-9
Keywords acid mine drainage; acid rock drainage; acidification; alkalinity; carbonate rocks; chemical properties; chemical reactions; coal; disposal barriers; economics; flocculation; ground water; heavy metals; human activity; ion exchange; limestone; mines; oxidation; oxides; permeability; pollution; porosity; pyrolusite; remediation; sedimentary rocks; surface water; waste disposal; waste management; water pollution; water treatment; wetlands 22, Environmental geology
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ISSN 0969-4218 ISBN Medium
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Notes Treating ARD; how, when, where and why; 2004-045038; References: 8; illus. incl. 2 tables United Kingdom (GBR); GeoRef; English Approved no
Call Number CBU @ c.wolke @ 5528 Serial 225
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