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Entrena, A. L., Serrano, J. R., & Villoria, A. (1988). Descontaminacion de aguas de mina con recuperacion de los metales contenidos en ellas. Decontamination of mine waters by recovering the metals contained within them VIII congreso internacional de Mineria y metalurgia; tomo 8. VIII international conference on Mining and metallurgy; Volume 8. In Congreso Internacional de Mineria y Metalurgia, vol.8 (pp. 156–173).
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Nairn, R. W., & Hedin, R. S. (1992). Designing wetlands for the treatment of polluted coal mine drainage. In M. C. Landin (Ed.), Wetlands; proceedings of the 13th annual conference; Society of Wetland Scientists (pp. 224–229).
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Fischer, R., Reissig, H., Gockel, G., Seidel, K. H., & Guderitz, T. (1998). Direkte Neutralisation und Untergrundwasserbehandlung des Restwassers im Tagebaurestsee Heide VI. Direct neutralization and treatment of deep subsoil water of the residual water in the open-pit relic lake Heide VI. Braunkohle, Surface Mining, 50(3), 273–278.
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Brunet, J. - F. (2000). Drainages miniers acides; contraintes et remedes; etat des connaissances--Acid mine drainage; problems and remediation techniques; state of the art. Principaux Resultats Scientifiques – Bureau de Recherches Geologiques et Minieres, 1999/2000, 97–98.
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Bolzicco, J., Carrera, J., & Ayora, C. (2004). Eficiencia de la barrera permeable reactiva de Aznalcollar (Sevilla, Espana) como remedio de aguas acidas de mina. Reactive permeable disposal barrier at Aznalcollar Mine, Seville, Spain; as remediation for acid mine drainage. Revista Latino-Americana de Hidrogeologia, 4, 27–34.
Abstract: As a result of the collapse of a mine tailing dam in april 1998 about 40 km of the Agrio and Guadiamar valleys were covered with a layer of pyrite sludge. Although most of the sludge was removed, a small amount remains in the soil of the Agrio valley and the aquifer remains polluted with acid water (ph<4) and metals (10 mg/L Zn, 5 mg/L Cu and Al). A permeable reactive barrier was build across the aquifer to increase the alcalinity and retain the metals. The barrier is made up of three sections of 30 m longX1.4 m thickX5 m deep (average) containing different proportions of limestone gravel, organic compost and zero-valent iron. The residence time of the water in the barrier is about two days. Within the barrier, the pH values increase to near neutral mainly due to calcite dissolution. Metals co-precipitate as oxyhydroxides, and they are also adsorbed on the organic matter surface. Down-stream the barrier, the total pollution removal is around 60-90% for Zn and Cu, and from 50 to 90% for Al and acidity.
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