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Author |
Barton, C.D.; Karathanasis, A.D. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage |
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Journal Article |
Year |
1998 |
Publication |
Environ Geosci |
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Volume |
5 |
Issue |
2 |
Pages |
43-56 |
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acid mine drainage aerobic environment anaerobic environment attenuation chemical fractionation chemical properties concentration constructed wetlands controls degradation detection environmental analysis ferric iron goethite heavy metals iron jarosite Kentucky McCreary County Kentucky metals oxides pollutants pollution seepage soils solubility sulfates surface water United States water treatment wetlands X-ray diffraction data 22, Environmental geology |
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1075-9565 |
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Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage; 2001-034195; References: 41; illus. incl. 1 table United States (USA); GeoRef; English |
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CBU @ c.wolke @ 16623 |
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61 |
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Author |
Barton, C.D.; Karathanasis, A.D. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage |
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Book Chapter |
Year |
1997 |
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AAPG Eastern Section and the Society for Organic Petrology joint meeting; abstracts |
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1545 |
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acid mine drainage aerobic environment air-water interface anaerobic environment attenuation buffers constructed wetlands controls diffusion iron manganese metals mineral composition pollution precipitation processes SEM data solubility solution sulfate ion sulfur wetlands X-ray diffraction data 22, Environmental geology |
Abstract |
The use of constructed wetlands for acid mine drainage amelioration has become a popular alternative to conventional treatment methods, however, the metal attenuation processes of these systems are poorly understood. Precipitates from biotic and abiotic zones of a staged constructed wetland treating high metal load (approx. equal to 1000 mg L (super -1) ) and low pH (approx. 3.0) acid mine drainage were characterized by chemical dissolution, x-ray diffraction, thermal analysis and scanning electron microscopy. Characterization of abiotic/aerobic zones within the treatment system suggest the presence of crystalline iron oxides and hydroxides such as hematite, lepidocrocite, goethite, and jarosite. At the air/water interface of initial abiotic treatment zones, SO (sub 4) /Fe ratios were low enough (<2.0) for the formation of jarosite and goethite, but as the ratio increased due to treatment and subsequent reductions in iron concentration, jarosite was transformed to other Fe-oxyhydroxysulfates and goethite formation was inhibited. In addition, elevated pH conditions occurring in the later stages of treatment promoted the formation of amorphous iron oxyhydroxides. Biotic wetland cell substrate characterizations suggest the presence of amorphous iron minerals such as ferrihydrite and Fe(OH) (sub 3) . Apparently, high Fe (super 3+) activity, low Eh and low oxygen diffusion rates in the anaerobic subsurface environment inhibit the kinetics of crystalline iron precipitation. Some goethite, lepidocrocite and hematite, however, were observed near the surface in biotic areas and are most likely attributable to increased oxygen levels from surface aeration and/or oxygen transport by plant roots. Alkalinity generation from limestone dissolution within the substrate and bacterially mediated sulfate reduction also has a significant role on the mineral retention process. The formation of gypsum, rhodochrocite and siderite are by-products of alkalinity generating reactions in this system and may have an impact on S, Mn, and Fe solubility controls. Moreover, the buffering of acidity through excess alkalinity appears to facilitate the precipitation and retention of metals within the system. |
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AAPG Bulletin |
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81 |
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Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage; GeoRef; English; 1997-067790; AAPG Eastern Section and the Society for Organic Petrology joint meeting, Lexington, KY, United States, Sep. 27-30, 1997 |
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CBU @ c.wolke @ 16630 |
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70 |
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Kleinmann, R.L.P. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Acid Mine Water Treatment using Engineered Wetlands |
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Journal Article |
Year |
1990 |
Publication |
Int. J. Mine Water |
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9 |
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1-4 |
Pages |
269-276 |
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wetlands AMD passive treatment pollution control water treatment abandoned mines biological treatment pH bacterial oxidation wetland sizing sphagnum |
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400 systems installed within 4 years During the last two decades, the United States mining industry has greatly increased the amount it spends on pollution control. The application of biotechnology to mine water can reduce the industry's water treatment costs (estimated at over a million dollars a day) and improve water quality in streams and rivers adversely affected by acidic mine water draining from abandoned mines. Biological treatment of mine waste water is typically conducted in a series of small excavated ponds that resemble, in a superficial way, a small marsh area. The ponds are engineered to first facilitate bacterial oxidation of iron; ideally, the water then flows through a composted organic substrate that supports a population of sulfate-reducing bacteria. The latter process raises the pH. During the past four years, over 400 wetland water treatment systems have been built on mined lands as a result of research by the U.S. Bureau of Mines. In general, mine operators find that the wetlands reduce chemical treatment costs enough to repay the cost of wetland construction in less than a year. Actual rates of iron removal at field sites have been used to develop empirical sizing criteria based on iron loading and pH. If the pH is 6 or above, the wetland area (in2) required is equivalent to the iron. load (grams/day) divided by 10. Theis requirement doubles at a pH of 4 to 5. At a pH below 4, the iron load (grams/day) should be divided by 2 to estimate the area required (in2). |
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0255-6960 |
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Acid Mine Water Treatment using Engineered Wetlands; 1; Fg; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 17368 |
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328 |
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Rabenhorst, M.C.; James, B.R. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Acid mine drainage remediation via sulfidization in wetlands Fiscal year 1992 annual report |
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RPT |
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1993 |
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acid mine drainage; anaerobic environment; Appalachians; concentration; decontamination; ferric iron; iron; manganese; marshes; Maryland; metals; mires; North America; oxidation; pollutants; pollution; pore water; remediation; sulfidization; transport; United States; water quality; water treatment; wetlands 22, Environmental geology |
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University of Maryland, W.R.R.C.C.P.M.D.U.S. |
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Acid mine drainage remediation via sulfidization in wetlands Fiscal year 1992 annual report; 1998-034327; GeoRef; English; illus. incl. 1 table University of Maryland, Water Resources Research Center, College Park, MD, United States |
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CBU @ c.wolke @ 6684 |
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267 |
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Johnson, D.B.; Hallberg, K.B. |
Title ![sorted by Title field, descending order (down)](img/sort_desc.gif) |
Acid mine drainage remediation options: a review |
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Journal Article |
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2005 |
Publication |
Science of the Total Environment |
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338 |
Issue |
1-2 |
Pages |
3-14 |
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Wetlands and estuaries Pollution and waste management non radioactive geographical abstracts: physical geography hydrology (71 6 8) geological abstracts: environmental geology (72 14 2) biological method pollutant removal water treatment wastewater bioremediation constructed wetland acid mine drainage Cornwall England England United Kingdom Western Europe Europe Eurasia Eastern Hemisphere World Acid mine drainage Bioreactors Bioremediation Sulfidogenesis Wetlands Wheal Jane |
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Acid mine drainage (AMD) causes environmental pollution that affects many countries having historic or current mining industries. Preventing the formation or the migration of AMD from its source is generally considered to be the preferable option, although this is not feasible in many locations, and in such cases, it is necessary to collect, treat, and discharge mine water. There are various options available for remediating AMD, which may be divided into those that use either chemical or biological mechanisms to neutralise AMD and remove metals from solution. Both abiotic and biological systems include those that are classed as “active” (i.e., require continuous inputs of resources to sustain the process) or “passive” (i.e., require relatively little resource input once in operation). This review describes the current abiotic and bioremediative strategies that are currently used to mitigate AMD and compares the strengths and weaknesses of each. New and emerging technologies are also described. In addition, the factors that currently influence the selection of a remediation system, and how these criteria may change in the future, are discussed. |
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0048-9697 |
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Feb. 01; Acid mine drainage remediation options: a review; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10052.pdf; Science Direct |
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CBU @ c.wolke @ 17464 |
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47 |
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