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Author Boonstra, J.; van Lier, R.; Janssen, G.; Dijkman, H.; Buisman, C.J.N.
Title (up) Biological treatment of acid mine drainage Type Book Chapter
Year 1999 Publication Process Metallurgy, vol.9, Part B Abbreviated Journal
Volume Issue Pages 559-567
Keywords acid mine drainage adsorption alkaline earth metals arsenic Bingham Canyon Mine bioremediation Budelco Zinc Refinery cadmium copper Cornwall England England Europe Great Britain heavy metals iron magnesium manganese metals Netherlands pH phase equilibria pollution remediation sulfate ion United Kingdom United States Utah Western Europe Wheal Jane Mine zinc 22, Environmental geology
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Corporate Author Thesis
Publisher Place of Publication Editor Amils, R.; Ballester, A.
Language Summary Language Original Title
Series Editor Series Title Biohydrometallurgy and the environment toward the mining of the 21st century; proceedings of the International biohydrometallurgy symposium IBS'99, Part B, Molecular biology, biosorption, bioremediation Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN 0444501932 Medium
Area Expedition Conference
Notes Biological treatment of acid mine drainage; GeoRef; English; 2000-049809; International biohydrometallurgy symposium IBS'99, Madrid, Spain, June 20-23, 1999 References: 11; illus. incl. 5 tables Approved no
Call Number CBU @ c.wolke @ 16595 Serial 442
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Author Cravotta, C.A., III; Trahan, M.K.
Title (up) Limestone drains to increase pH and remove dissolved metals from acidic mine drainage Type Journal Article
Year 1999 Publication Appl. Geochem. Abbreviated Journal
Volume 14 Issue 5 Pages 581-606
Keywords manganese oxide redox processes sulfate waters iron-oxides adsorption ions oxidation surfaces environments aluminum
Abstract Despite encrustation by Fe and Al hydroxides, limestone can be effective for remediation of acidic mine drainage (AMD). Samples of water and limestone (CaCO3) were collected periodically for 1 a at 3 identical limestone-filled drains in Pennsylvania to evaluate the attenuation of dissolved metals and the effects of pH and Fe- and Al-hydrolysis products on the rate of CaCO3 dissolution. The influent was acidic and relatively dilute (pH < 4; acidity < 90 mg) but contained 1-4 mg . L-1 of O-2, Fe3+, Al3+ and Mn2+. The total retention time in the oxic limestone drains (OLDs) ranged from 1.0 to 3.1 hr. Effluent remained oxic (O-2 > 1 mg . L-1) but was near neutral (pH = 6.2-7.0); Fe and Al decreased to less than 5% of influent concentrations. As pH increased near the inflow, hydrous Fe and Al oxides precipitated in the OLDs, The hydrous oxides, nominally Fe(OH)(3) and Al(OH)(3), were visible as loosely bound, orange-yellow coatings on limestone near the inflow. As time elapsed, Fe(OH)(3) and Al(OH)(3) particles were transported downflow. The accumulation of hydrous oxides and elevated pH (> 5) in the downflow part of the OLDs promoted sorption and coprecipitation of dissolved Mn, Cu, Co, Ni and Zn as indicated by decreased concentrations of the metals in effluent and their enrichment relative to Fe in hydrous-oxide particles and coatings on limestone. Despite thick (similar to 1 mm) hydrous-oxide coatings on limestone near the inflow, CaCO3 dissolution was more rapid near the inflow than at downflow points within and the OLD where the limestone was not coated. The high rates of CaCO3 dissolution and Fe(OH3) precipitation were associated with the relatively low pH and high Fe3+ concentration near the inflow. The rate of CaCO3 dissolution decreased with increased pH and concentrations of Ca2+ and HCO3- and decreased Pco(2). Because overall efficiency is increased by combining neutralization and hydrolysis reactions, an OLD followed by a settling pond requires less land area than needed for a two-stagetreatment system consisting of an anoxic limestone drain and oxidation-settling pond or wetland. To facilitate removal of hydrous-oxide sludge, a perforated-pipe subdrain can be installed within an OLD. (C) 1999 Elsevier Science Ltd.
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Publisher Place of Publication Editor
Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0883-2927 ISBN Medium
Area Expedition Conference
Notes Jul; Limestone drains to increase pH and remove dissolved metals from acidic mine drainage; Isi:000080043300004; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10102.pdf; AMD ISI | Wolkersdorfer Approved no
Call Number CBU @ c.wolke @ 17470 Serial 22
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Author Eriksson, P.K.; Lien, L.A.; Green, D.H.; Kyburz, M.
Title (up) Nanofiltration für die Aufkonzentrierung von Kupfersulfat von Auslaugewässern und die Rückgewinnung von Schwefelsäure Type Conference Article
Year 1997 Publication 6. Aachener Membran Kolloquium, Preprints, Aachen, DE, 3. 5. Mar, 1997 Abbreviated Journal
Volume Issue Pages 113-121
Keywords Abwasserbehandlung Abraum Auslaugen=Mineralogie Ausfällung Membranfilter Adsorption Biomasse Konzentration Kupfer Porenweite Querströmung Schwermetalle Soda Investitionskosten Betriebskosten Kolonne=Apparat Pilotanlage Schwefelsäure Wiederverwertung Metallsalz Nanofiltration Kupfermine Biomassekolonne Entkrustungsmittel
Abstract In einem US-amerikanischen Minenbetrieb fallen bei der Auslaugung von Abraum zur Gewinnung von Restkupfer Abwässer an, die höhere Konzentrationen aufweisen als für Abwässer erlaubt ist. Eine bislang angewandte chemische Fällung erforderte erhebliche Kosten. Mit der Nanofiltration (NF), verbunden mit einer Biomasse-Adsorptionsstufe, erhält man ein weniger problematisches Abwasser, das direkt eingeleitet werden darf. Dieses Wasser kann im Betrieb sogar als Frischwasser dort eingesetzt werden, wo höhere Anteile an Silikaten toleriert werden können. Ein weiterer Vorteil der NF-Technik ist die Aufkonzentration der Metallsalze und die Rückgewinnung von Schwefelsäure. Kupfer liegt z.B. nach der ersten Stufe in solcher Konzentration vor, daß die Extraktionskapazität der existierenden Anlage stark erhöht wird. Die Nanofiltration ist ein Membranprozeß, bei dem Membranen mit Porengrößen von ca. 1 nm eingesetzt werden. Die Porengröße ist kleiner als bei Ultrafiltrationsverfahren und nur wenig größer als bei Umkehrosmosemembranen. Gearbeitet wird mit dem Prinzip der Queranströmung (Crossflow). Zur Entfernung der relativ geringen Anteile an Schwermetallen wird zusätzlich eine Biomasse-Kolonne eingesetzt. Beschrieben wird der Aufbau bzw. das Fließschema einer Pilotanlage. Untersuchungen mit dieser Anlage bestätigten die Wirksamkeit der NF- Abwasserbehandlung mit anschließender Adsorption an Biomasse. Die zugeführten Chemikalien bestehen lediglich aus relativ harmlosen Stoffen wie Entkrustungsmittel und Soda. Das Entkrustungsmittel wird benötigt, um Ablagerungen von Anorganika auf den Membranen zu verhindern. Das Soda neutralisiert das aufbereitete Wasser. Beide Chemikalien verhalten sich im Prozeß ansonsten neutral. Hauptsächliche Ausgaben entstehen für Kapitalkosten. Betriebskosten entstehen für den Membranersatz und die Energie. Die Versuchsresultate und Erkenntnisse aus den Versuchen konnten weitgehend für die Auslegung einer NF-Anlage in einer Kupfermine in Mexiko übernommen werden, die im Frühjahr 1997 in Betrieb genommen werden soll.
Address Escondido, US; Harrison Western Environ Services, Lakewood, US; Osmonics- Desal, Aarau, CH
Corporate Author Thesis
Publisher Place of Publication Editor
Language Summary Language Original Title
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Notes Nanofiltration für die Aufkonzentrierung von Kupfersulfat von Auslaugewässern und die Rückgewinnung von Schwefelsäure; BERG, Copyright FIZ Technik e.V.; DE Deutsch; Csn=00011; M9705 0920 570; 13759, BERG , 11.06.97; Words: 592; 9 Seiten, 4 Bilder 3PAB *Aufbereitung anorganischer, mineralischer Rohstoffe* 3PH *Trennen fest/flüssig/gasförm. Stoffe, dispers. Stoffsysteme* 3UXX *Belastung von Wasser, Wasserreinhaltung, Abwasser* 3KEM *Nichteisenmetalle/ legierungen/ gußwerkstoffe* Approved no
Call Number CBU @ c.wolke @ 17600 Serial 388
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Author Mohan, D.; Chander, S.
Title (up) Removal and recovery of metal ions from acid mine drainage using lignite-A low cost sorbent Type Journal Article
Year 2006 Publication J. Hazard. Mater. Abbreviated Journal
Volume 137 Issue 3 Pages 1545-1553
Keywords Geobase: Related Topics geobase: related topics (901) acid mine drainage adsorption ion iron sulfide lignite wastewater water treatment
Abstract Acid mine drainage (AMD), has long been a significant environmental problem resulting from the microbial oxidation of iron pyrite in presence of water and air, affording an acidic solution that contains toxic metal ions. The main objective of this study was to remove and recover metal ions from acid mine drainage (AMD) by using lignite, a low cost sorbent. Lignite has been characterized and used for the AMD treatment. Sorption of ferrous, ferric, manganese, zinc and calcium in multi-component aqueous systems was investigated. Studies were performed at different pH to find optimum pH. To simulate industrial conditions for acid mine wastewater treatment, all the studies were performed using single and multi-columns setup in down flow mode. The empty bed contact time (EBCT) model was used for minimizing the sorbent usage. Recovery of the metal ions as well as regeneration of sorbent was achieved successfully using 0.1 M nitric acid without dismantling the columns. < copyright > 2006 Elsevier B.V. All rights reserved.
Address D. Mohan, Department of Energy and Geo-Environmental Engineering, The Pennsylvania State University, University Park, PA 16802, United States dm_1967@hotmail.com
Corporate Author Thesis
Publisher Place of Publication Editor
Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0304-3894 ISBN Medium
Area Expedition Conference
Notes Oct 11; Removal and recovery of metal ions from acid mine drainage using lignite-A low cost sorbent; 2919875; Netherlands 56; Geobase Approved no
Call Number CBU @ c.wolke @ 17634 Serial 295
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Author Aytas, S.O.; Akyil, S.; Aslani, M.A.A.; Aytekin, U.
Title (up) Removal of uranium from aqueous solutions by diatomite (Kieselguhr) Type Journal Article
Year 1999 Publication Journal of Radioanalytical and Nuclear Chemistry Abbreviated Journal
Volume 240 Issue 3 Pages 973-976
Keywords acid mine drainage; actinides; adsorption; aqueous solutions; clastic rocks; concentration; decontamination; diatomite; experimental studies; isotherms; laboratory studies; metals; pH; physicochemical properties; pollution; remediation; sedimentary rocks; solutes; sorption; techniques; uranium; uranyl ion; waste disposal; waste water 22, Environmental geology
Abstract
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Publisher Place of Publication Editor
Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
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ISSN 0236-5731 ISBN Medium
Area Expedition Conference
Notes Removal of uranium from aqueous solutions by diatomite (Kieselguhr); 2000-058980; References: 18; illus. incl. 3 tables International (III); GeoRef; English Approved no
Call Number CBU @ c.wolke @ 5964 Serial 471
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