Records |
Author |
Herbert, R.B., Jr.; Benner, S.G.; Blowes, D.W. |
Title |
Reactive barrier treatment of groundwater contaminated by acid mine drainage; sulphur accumulation and sulphide formation |
Type |
Book Chapter |
Year |
1998 |
Publication |
Groundwater Quality: Remediation and Protection |
Abbreviated Journal |
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Volume |
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Issue |
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Pages |
451-457 |
Keywords |
acid mine drainage Canada chemical analysis contaminant plumes Eastern Canada ground water hydraulic conductivity hydrolysis Nickel Rim Mine Ontario pH pollution porosity pyrrhotite remediation sample preparation Sudbury Basin sulfides sulfur tailings water pollution 22, Environmental geology |
Abstract |
A permeable reactive barrier was installed in August 1995 at the Nickel Rim Mine near Sudbury, Ontario, Canada, for the passive remediation of groundwater contaminated with acid mine drainage. The reactive component of the barrier consists of a mixture of municipal and leaf compost and wood chips: the organic material promotes bacterially-mediated sulphate reduction. Hydrogen sulphide, a product of sulphate reduction, may then complex with aqueous ferrous iron and precipitate as iron sulphide. This study presents the solid phase sulphur chemistry of the reactive wall after two years of operation, and discusses the formation and accumulation of iron sulphide minerals in the reactive material. The results from the solid-phase chemical analysis of core samples indicate that there is an accumulation of reduced inorganic sulphur in the reactive wall, with levels reaching 190 mu mol g (super -1) (dry weight) by July 1997. |
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Thesis |
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Publisher |
IAHS-AISH Publication, vol.250 |
Place of Publication |
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Editor |
Herbert, M.; Kovar, K. |
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ISBN |
1901502554 |
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Notes |
Reactive barrier treatment of groundwater contaminated by acid mine drainage; sulphur accumulation and sulphide formation; GeoRef; English; 1999-065115; GQ 98 conference, Tubingen, Federal Republic of Germany, Sept. 21-24, 1998 References: 15; illus. |
Approved |
no |
Call Number |
CBU @ c.wolke @ 16621 |
Serial |
65 |
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Author |
Barton, C.D.; Karathanasis, A.D. |
Title |
Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage |
Type |
Book Chapter |
Year |
1997 |
Publication |
AAPG Eastern Section and the Society for Organic Petrology joint meeting; abstracts |
Abbreviated Journal |
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Volume |
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Issue |
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Pages |
1545 |
Keywords |
acid mine drainage aerobic environment air-water interface anaerobic environment attenuation buffers constructed wetlands controls diffusion iron manganese metals mineral composition pollution precipitation processes SEM data solubility solution sulfate ion sulfur wetlands X-ray diffraction data 22, Environmental geology |
Abstract |
The use of constructed wetlands for acid mine drainage amelioration has become a popular alternative to conventional treatment methods, however, the metal attenuation processes of these systems are poorly understood. Precipitates from biotic and abiotic zones of a staged constructed wetland treating high metal load (approx. equal to 1000 mg L (super -1) ) and low pH (approx. 3.0) acid mine drainage were characterized by chemical dissolution, x-ray diffraction, thermal analysis and scanning electron microscopy. Characterization of abiotic/aerobic zones within the treatment system suggest the presence of crystalline iron oxides and hydroxides such as hematite, lepidocrocite, goethite, and jarosite. At the air/water interface of initial abiotic treatment zones, SO (sub 4) /Fe ratios were low enough (<2.0) for the formation of jarosite and goethite, but as the ratio increased due to treatment and subsequent reductions in iron concentration, jarosite was transformed to other Fe-oxyhydroxysulfates and goethite formation was inhibited. In addition, elevated pH conditions occurring in the later stages of treatment promoted the formation of amorphous iron oxyhydroxides. Biotic wetland cell substrate characterizations suggest the presence of amorphous iron minerals such as ferrihydrite and Fe(OH) (sub 3) . Apparently, high Fe (super 3+) activity, low Eh and low oxygen diffusion rates in the anaerobic subsurface environment inhibit the kinetics of crystalline iron precipitation. Some goethite, lepidocrocite and hematite, however, were observed near the surface in biotic areas and are most likely attributable to increased oxygen levels from surface aeration and/or oxygen transport by plant roots. Alkalinity generation from limestone dissolution within the substrate and bacterially mediated sulfate reduction also has a significant role on the mineral retention process. The formation of gypsum, rhodochrocite and siderite are by-products of alkalinity generating reactions in this system and may have an impact on S, Mn, and Fe solubility controls. Moreover, the buffering of acidity through excess alkalinity appears to facilitate the precipitation and retention of metals within the system. |
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Publisher |
AAPG Bulletin |
Place of Publication |
81 |
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Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage; GeoRef; English; 1997-067790; AAPG Eastern Section and the Society for Organic Petrology joint meeting, Lexington, KY, United States, Sep. 27-30, 1997 |
Approved |
no |
Call Number |
CBU @ c.wolke @ 16630 |
Serial |
70 |
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Author |
Yernberg, W.R. |
Title |
Improvements seen in acid-mine-drainage technology |
Type |
Journal Article |
Year |
2000 |
Publication |
Min. Eng. |
Abbreviated Journal |
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Volume |
52 |
Issue |
9 |
Pages |
67-70 |
Keywords |
acid mine drainage; bacteria; chemical weathering; coal mines; Colorado; copper ores; effects; geochemistry; hydrogen; inorganic acids; international cooperation; ions; lead ores; medical geology; metal ores; mines; molybdenum ores; oxidation; pH; pollution; prediction; pyrite; reclamation; remediation; research; risk assessment; silicates; soil treatment; solid waste; sulfides; sulfuric acid; Summitville Mine; tailings; tailings ponds; technology; United States; waste disposal; weathering; zinc ores 22, Environmental geology |
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Edition |
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ISSN |
0026-5187 |
ISBN |
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Notes |
Improvements seen in acid-mine-drainage technology; 2000-069686; illus. incl. sect., sketch map United States (USA); GeoRef; English |
Approved |
no |
Call Number |
CBU @ c.wolke @ 5808 |
Serial |
73 |
Permanent link to this record |
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Author |
Ye, Z.H.; Whiting, S.N.; Qian, J.H.; Lytle, C.M.; Lin, Z.Q.; Terry, N. |
Title |
Trace element removal from coal ash leachate by a 10-year-old constructed wetland |
Type |
Journal Article |
Year |
2001 |
Publication |
J. Environ. Qual. |
Abbreviated Journal |
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Volume |
30 |
Issue |
5 |
Pages |
1710-1719 |
Keywords |
acid mine drainage; Alabama; ash; bioaccumulation; boron; cadmium; constructed wetlands; environmental analysis; environmental effects; iron; Jackson County Alabama; Juncus effusus; leachate; manganese; metals; pH; pollutants; pollution; remediation; soils; sulfur; trace elements; Typha latifolia; United States; vegetation; waste water; wetlands; Widows Creek; Widows Creek Steam Plant; zinc; Typha; Juncus 22, Environmental geology |
Abstract |
This study investigated the ability of a 10-yr-old constructed wetland to treat metal-contaminated leachate emanating from a coal ash pile at the Widows Creek electric utility, Alabama (USA). The two vegetated cells, which were dominated by cattail (Typha latifolia L.) and soft rush (Juncus effusus L.), were very effective at removing Fe and Cd from the wastewater, but less efficient for Zn, S, B, and Mn. The concentrations were decreased by up to 99% for Fe, 91% for Cd, 63% for Zn, 61% for S, 58% for Mn, and 50% for B. Higher pH levels (>6) in standing water substantially improved the removing efficiency of the wetland for Mn only. The belowground tissues of both cattail and soft rush had high concentrations of all elements; only for Mn, however, did the concentration in the shoots exceed those in the belowground tissues. The concentrations of trace elements in fallen litter were higher than in the living shoots, but lower than in the belowground tissues. ne trace element accumulation in the plants accounted for less than 2.5% of the annual loading of each trace element into the wetland. The sediments were the primary sinks for the elements removed from the wastewater. Except for Mn, the concentrations of trace elements in the upper layer (0-5 cm) of the sediment profile tended to be higher than the lower layers (5-10 and 10-15 cm). We conclude that constructed wetlands are still able to efficiently remove metals in the long term (i.e., >10 yr after construction). |
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Edition |
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ISSN |
0047-2425 |
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Notes |
Aug 1; Trace element removal from coal ash leachate by a 10-year-old constructed wetland; 2002-017274; References: 33; illus. incl. 2 tables United States (USA); file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/5703.pdf; GeoRef; English |
Approved |
no |
Call Number |
CBU @ c.wolke @ 5703 |
Serial |
76 |
Permanent link to this record |
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Author |
Ziemkiewicz, P.F.; Meek, F.A., Jr.; Skousen, J.G.; Ziemkiewicz, P.F. |
Title |
Long term behavior of acid forming rock; results of 11-year field studies |
Type |
Book Chapter |
Year |
1996 |
Publication |
Acid mine drainage control and treatment |
Abbreviated Journal |
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Volume |
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Issue |
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Pages |
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Keywords |
acid mine drainage; acid rock drainage; alkaline earth metals; alkalinity; calcium; chemical composition; clastic rocks; coal mines; leachate; metals; mines; pH; pollution; prediction; reclamation; remediation; sandstone; sedimentary rocks; shale; spoils; sulfate ion; sulfur; United States; Upshur County West Virginia; waste disposal; waste rock; weathered materials; weathering; West Virginia 22, Environmental geology |
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Publisher |
West Virginia University and the National Mine Land Reclamation Center |
Place of Publication |
Morgantown |
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Notes |
Long term behavior of acid forming rock; results of 11-year field studies; GeoRef; English; 2004-051147; Edition: 2 References: 9; illus. incl. 1 table |
Approved |
no |
Call Number |
CBU @ c.wolke @ 6357 |
Serial |
190 |
Permanent link to this record |