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Author Sheoran, A.S.; Sheoran, V.
Title Heavy metal removal mechanism of acid mine drainage in wetlands: A critical review Type Journal Article
Year 2006 Publication Minerals Engineering Abbreviated Journal
Volume 19 Issue 2 Pages 105-116
Keywords Acid mine drainage Metal removal mechanism Wetlands
Abstract Acid mine drainage (AMD) is one of the most significant environmental challenges facing the mining industry worldwide. Water infiltrating through the metal sulphide minerals, effluents of mineral processing plants and seepage from tailing dams becomes acidic and this acidic nature of the solution allows the metals to be transported in their most soluble form. The conventional treatment technologies used in the treatment of acid mine drainage are expensive both in terms of operating and capital costs. One of the methods of achieving compliance using passive treatment systems at low cost, producing treated water pollution free, and fostering a community responsibility for acid mine water treatment involves the use of wetland treatment system. These wetlands absorb and bind heavy metals and make them slowly concentrated in the sedimentary deposits to become part of the geological cycle. In this paper a critical review of the heavy metal removal mechanism involving various physical, chemical and biological processes, which govern wetland performance, have been made. This information is important for the siting and use of wetlands for remediation of heavy metals.
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Notes Heavy metal removal mechanism of acid mine drainage in wetlands: A critical review; Science Direct Approved no
Call Number CBU @ c.wolke @ 17252 Serial 41
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Author Potgieter-Vermaak, S.S.; Potgieter, J.H.; Monama, P.; Van Grieken, R.
Title Comparison of limestone, dolomite and fly ash as pre-treatment agents for acid mine drainage Type Journal Article
Year 2006 Publication Minerals Engineering Abbreviated Journal
Volume 19 Issue 5 Pages 454-462
Keywords Acid rock drainage Mining Tailings Environmental
Abstract The physical, chemical and biological nature of Vaal Dam water, the main source of water in Gauteng, South Africa, is often affected by underground water pollution (acid mine water) and industrial effluents. The ecological significance and detrimental effects necessitate investigations into treating the water prior to discharge into public streams. Although several acid mine water treatment techniques and methods exist, they all have certain disadvantages. Lime treatment is the most common approach. In this investigation, limestone, dolomite and fly ash were selected as pre-treatment agents based on their low cost. Simulated acid mine water containing these agents was tested using a Jar Test apparatus. Samples were analyzed before and after treatment for pH, ferrous, ferric, calcium, magnesium and sulphate ions. The study demonstrated that the quality of the water improved with an increase in the amount and surface area of the raw material dosed and an increase in contact time. It was also influenced by the chemical composition of the acid mine water and aeration. Chemical cost savings of 38% are achieved when lime is replaced with limestone, and cost savings of 23% and 48% can be accomplished when limestone is substituted with dolomite and fly ash respectively. This could result in significant savings to the gold and coal mining industries, and could lead to a mutual benefit/gain between industrialists/polluters and the public.
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ISSN 0892-6875 ISBN Medium
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Notes Apr.; Comparison of limestone, dolomite and fly ash as pre-treatment agents for acid mine drainage; Science Direct Approved no
Call Number CBU @ c.wolke @ 17461 Serial 42
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Author Conca, J.L.; Wright, J.
Title An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd Type Journal Article
Year 2006 Publication Appl. Geochem. Abbreviated Journal
Volume 21 Issue 12 Pages 2188-2200
Keywords Pollution and waste management non radioactive Groundwater quality apatite groundwater remediation zinc lead cadmium acid mine drainage copper sulfate nitrate permeability water treatment precipitation chemistry
Abstract Phosphate-induced metal stabilization involving the reactive medium Apatite II(TM) [Ca10-xNax(PO4)6-x(CO3)x(OH)2], where x < 1, was used in a subsurface permeable reactive barrier (PRB) to treat acid mine drainage in a shallow alluvial groundwater containing elevated concentrations of Zn, Pb, Cd, Cu, SO4 and NO3. The groundwater is treated in situ before it enters the East Fork of Ninemile Creek, a tributary to the Coeur d'Alene River, Idaho. Microbially mediated SO4 reduction and the subsequent precipitation of sphalerite [ZnS] is the primary mechanism occurring for immobilization of Zn and Cd. Precipitation of pyromorphite [Pb10(PO4)6(OH,Cl)2] is the most likely mechanism for immobilization of Pb. Precipitation is occurring directly on the original Apatite II. The emplaced PRB has been operating successfully since January of 2001, and has reduced the concentrations of Cd and Pb to below detection (2 μg L-1), has reduced Zn to near background in this region (about 100 μg L-1), and has reduced SO4 by between 100 and 200 mg L-1 and NO3 to below detection (50 μg L-1). The PRB, filled with 90 tonnes of Apatite II, has removed about 4550 kg of Zn, 91 kg of Pb and 45 kg of Cd, but 90% of the immobilization is occurring in the first 20% of the barrier, wherein the reactive media now contain up to 25 wt% Zn. Field observations indicate that about 30% of the Apatite II material is spent (consumed).
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ISSN 0883-2927 ISBN Medium
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Notes Dec.; An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd; Science Direct Approved no
Call Number CBU @ c.wolke @ 17248 Serial 44
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Author Hulshof, A.H.M.; Blowes, D.W.; Douglas Gould, W.
Title Evaluation of in situ layers for treatment of acid mine drainage: A field comparison Type Journal Article
Year 2006 Publication Water Res Abbreviated Journal
Volume 40 Issue 9 Pages 1816-1826
Keywords mine water Pollution and waste management non radioactive Groundwater problems and environmental effects acid mine drainage organic carbon oxidation microbial activity drainage groundwater pollution Bacteria microorganisms Contamination Groundwater Barriers Drainage Treatment
Abstract Reactive treatment layers, containing labile organic carbon, were evaluated to determine their ability to promote sulfate reduction and metal sulfide precipitation within a tailings impoundment, thereby treating tailings effluent prior to discharge. Organic carbon materials, including woodchips and pulp waste, were mixed with the upper meter of tailings in two separate test cells, a third control cell contained only tailings. In the woodchip cell sulfate reduction rates were 500 mg L-1 a-1, (5.2 mmol L-1 a-1) this was coupled with the gradual removal of 350 mg L-1 Zn (5.4 mmol L-1). Decreased δ13CDIC values from -3‰ to as low as -12‰ indicated that sulfate reduction was coupled with organic carbon oxidation. In the pulp waste cell the most dramatic change was observed near the interface between the pulp waste amended tailings and the underlying undisturbed tailings. Sulfate reduction rates were 5000 mg L-1 a-1 (52 mmol L-1 a-1), Fe concentrations decreased by 80–99.5% (148 mmol L-1) and Zn was consistently <5 mg L-1. Rates of sulfate reduction and metal removal decreased as the pore water migrated upward into the shallower tailings. Increased rates of sulfate reduction in the pulp waste cell were consistent with decreased δ13CDIC values, to as low as -22‰, and increased populations of sulfate reducing bacteria. Lower concentrations of the nutrients, phosphorus, organic carbon and nitrogen in the woodchip material contribute to the lower sulfate reduction rates observed in the woodchip cell.
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ISSN 0043-1354 ISBN Medium
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Notes May; Evaluation of in situ layers for treatment of acid mine drainage: A field comparison; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10040.pdf; Science Direct Approved no
Call Number CBU @ c.wolke @ 10040 Serial 49
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Author Agency, U.S.E.P.; Development, O. of R. and
Title Active and semi-passive lime treatment of acid mine drainage at Leviathan Mine, California Type RPT
Year 2006 Publication Abbreviated Journal
Volume Issue Pages 94
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Publisher National Risk Management Research Laboratory, Office of Research and Development, U.S. Environmental Protection Agency Place of Publication Cincinnati, OH Editor
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Notes Mar; Active and semi-passive lime treatment of acid mine drainage at Leviathan Mine, California; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/7171.pdf; Opac Approved no
Call Number CBU @ c.wolke @ 7171 Serial 62
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