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Ball, B. R. (1996). Advanced oxidation treatment of mine drainage. Second International Symposium on Extraction and Processing for the Treatment and Minimization of Wastes – 1996, , 363–376.
Abstract: An investigation of the effects of ozone and ozone-induced hydroxyl radical on reducing whole affluent toxicity is described and discussed relative to the application of ozone for industrial water treatment. Results from operation of an ozone system treating industrial affluent from a lead and zinc mine in Colorado are presented. The mine discharges 1,000 gpm of wastewater into a tributary of the Arkansas River and has historically exceeded Whole Effluent Toxicity (WET) limits and on occasion has exceeded numeric limits for copper, ammonia, and cyanide. Based on results of a Toxicity Identification Evaluation (TIE) conducted on the effluent and individual process waste streams, the source of effluent toxicity is believed to be primarily associated with organic reagents used in the milling process.
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Blowes, D. W., Ptacek, C. J., Benner, S. G., McRae, C. W. T., & Puls, R. W. (1998). Treatment of dissolved metals using permeable reactive barriers. Groundwater Quality: Remediation and Protection, (250), 483–490.
Abstract: Permeable reactive barriers are a promising new approach to the treatment of dissolved contaminants in aquifers. This technology has progressed rapidly from laboratory studies to full-scale implementation over the past decade. Laboratory treatability studies indicate the potential for treatment of a large number of inorganic contaminants, including As, Cd, Cr, Cu, Hg, Fe, Mn, Mo, Ni, Pb, Se, Tc, U, V, NO3, PO4, and SO4. Small scale field studies have indicated the potential for treatment of Cd, Cr, Cu, Fe, Ni, Pb, NO3, PO4, and SO4. Permeable reactive barriers have been used in full-scale installations for the treatment of hexavalent chromium, dissolved constituents associated with acid-mine drainage, including SO4, Fe, Ni, Co and Zn, and dissolved nutrients, including nitrate and phosphate. A full-scale barrier designed to prevent the release of contaminants associated with inactive mine tailings impoundment was installed at the Nickel Rim mine site in Canada in August 1995. This reactive barrier removes Fe, SO,, Ni and other metals. The effluent from the barrier is neutral in pH and contains no acid-generating potential, and dissolved metal concentrations are below regulatory guidelines. A full-scale reactive barrier was installed to treat Cr(VI) and halogenated hydrocarbons at the US Coast Guard site in Elizabeth City, North Carolina, USA in June 1996. This barrier removes Cr(VI) from >8 mg l(-1) to <0.01 mg l(-1).
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Zaluski, M. (1999). Design and construction of bioreactors with sulfate-reducing bacteria for acid mine drainage control. Phytoremediation and Innovative Strategies for Specialized Remedial Applications, , 205–210.
Abstract: At many abandoned mine sites in the Western U.S., conventional treatment of AMD is not feasible due to the of lack of power and limited site accessibility. Therefore, three bioreactors were built at an abandoned mine site in Montana to demonstrate feasibility of treating AMD using sulphate reducing bacteria (SRB) in a passive water treatment train. The SRB are capable of increasing the pH and reducing the load of dissolved metals in the effluent. The reactors, constructed in the Fall of 1998, were designed to evaluate the SRB technology applied under different environmental conditions. Each bioreactor was designed with mechanisms to enable simulation of seasonal dry and wet climatic conditions. Two bioreactors were placed in trenches and one was constructed above the ground to investigate impact of seasonal freezing and thawing on SRB activity. Two bioreactors contain a passive pretreatment section to increase pH of water before the AMD enters the bioreactor chamber.
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