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Zhuang, J. M. (2004). Lignor(TM) process for acidic rock drainage treatment. Environ. Technol., 25(9), 1031–1040.
Abstract: The process using lignosulfonates for acidic rock drainage (ARD) treatment is referred to as the Lignor(TM) process. Lignosulfonates are waste by-products produced in the sulfite pulping process. The present study has shown lignosulfonates are able to protect lime from developing an external surface coating, and hence to favor its dissociation. Further, the addition of lignosulfonates to ARD solutions increased the clotting and settling rate of the formed sludge. The capability of lignosulfonates to form stable metal-lignin complexes makes them very useful in retaining metal ions and thus improving the long-term stability of the sludge against leaching. The Lignor(TM) process involves metal sorption with lignosulfonates, ARD neutralization by lime to about pH 7, pH adjustment with caustic soda to 9.4 – 9.6, air oxidation to lower the pH to a desired level, and addition of a minimum amount of FeCl3 for further removal of dissolved metals. The Lignor(TM) process removes all concerned metals (especially Al and Mn) from the ARD of the Britannia Mine (located at Britannia Beach, British Columbia, Canada) to a level lower than the limits of the B.C. Regulations. Compared with the high-density sludge (HDS) process, the Lignor(TM) process has many advantages, such as considerable savings in lime consumption, greatly reduced sludge volume, and improved sludge stability.
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Ye, Z. H. (2004). Use of a wetland system for treating Pb/Zn mine effluent: A case study in southern China from 1984 to 2002. Wetlands Ecosystems in Asia: Function and Management, 1, 413–434.
Abstract: A constructed wetland system in Guangdong Province, South of China has been used for treating Pb/Zn mine discharge since 1984. In this chapter, the performance of this system in the purification of mine discharge, metal accumulation in different ecological compartments and ecological succession within the system during the period of 1984-2002 has been reviewed. The data show that the wetland system not only effectively remove metals (mainly Pb, Zn, Cd and Cu) and total suspended solids from the mine discharge over a long period leading to significant improvement in water quality, but also gradually increase diversity and abundance of living organisms.
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Bolzicco, J., Carrera, J., & Ayora, C. (2004). Eficiencia de la barrera permeable reactiva de Aznalcollar (Sevilla, Espana) como remedio de aguas acidas de mina. Reactive permeable disposal barrier at Aznalcollar Mine, Seville, Spain; as remediation for acid mine drainage. Revista Latino-Americana de Hidrogeologia, 4, 27–34.
Abstract: As a result of the collapse of a mine tailing dam in april 1998 about 40 km of the Agrio and Guadiamar valleys were covered with a layer of pyrite sludge. Although most of the sludge was removed, a small amount remains in the soil of the Agrio valley and the aquifer remains polluted with acid water (ph<4) and metals (10 mg/L Zn, 5 mg/L Cu and Al). A permeable reactive barrier was build across the aquifer to increase the alcalinity and retain the metals. The barrier is made up of three sections of 30 m longX1.4 m thickX5 m deep (average) containing different proportions of limestone gravel, organic compost and zero-valent iron. The residence time of the water in the barrier is about two days. Within the barrier, the pH values increase to near neutral mainly due to calcite dissolution. Metals co-precipitate as oxyhydroxides, and they are also adsorbed on the organic matter surface. Down-stream the barrier, the total pollution removal is around 60-90% for Zn and Cu, and from 50 to 90% for Al and acidity.
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Anonymous. (2004). Development of Integrated Passive Water Treatment Systems for the Treatment of Mine Waters. The @AusIMM bulletin, 2004(1), 58–62.
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