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Author Wingenfelder, U.; Hansen, C.; Furrer, G.; Schulin, R.
Title Removal of heavy metals from mine waters by natural zeolites Type Journal Article
Year 2005 Publication (down) Environ Sci Technol, ES & T Abbreviated Journal
Volume 39 Issue 12 Pages 4606-4613
Keywords Groundwater problems and environmental effects Pollution and waste management non radioactive remediation heavy metal mine drainage acid mine drainage; acidification; Central Europe; chemical composition; chemical fractionation; dissolved materials; Europe; framework silicates; geochemistry; grain size; heavy metals; hydrochemistry; ion exchange; lead; metals; mines; mining; mobilization; models; pH; pollutants; pollution; precipitation; remediation; samples; silicates; spectra; Switzerland; toxic materials; X-ray diffraction data; X-ray fluorescence spectra; zeolite group
Abstract
Address G. Furrer, Institute of Terrestrial Ecology, Swiss Federal Institute of Technology, Zurich, Grabenstrasse 3, CH-8952 Schlieren, Switzerland gerhard.furrer@env.ethz.ch
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Publisher Place of Publication Editor
Language Summary Language Original Title
Series Editor Series Title Abbreviated Series Title
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ISSN 0013-936x ISBN Medium
Area Expedition Conference
Notes Removal of heavy metals from mine waters by natural zeolites; 2006-086777; References: 42; illus. incl. 3 tables United States (USA); GeoRef; English Approved no
Call Number CBU @ c.wolke @ 5382 Serial 71
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Author Conca, J.L.; Wright, J.
Title An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd Type Journal Article
Year 2006 Publication (down) Appl. Geochem. Abbreviated Journal
Volume 21 Issue 12 Pages 2188-2200
Keywords Pollution and waste management non radioactive Groundwater quality apatite groundwater remediation zinc lead cadmium acid mine drainage copper sulfate nitrate permeability water treatment precipitation chemistry
Abstract Phosphate-induced metal stabilization involving the reactive medium Apatite II(TM) [Ca10-xNax(PO4)6-x(CO3)x(OH)2], where x < 1, was used in a subsurface permeable reactive barrier (PRB) to treat acid mine drainage in a shallow alluvial groundwater containing elevated concentrations of Zn, Pb, Cd, Cu, SO4 and NO3. The groundwater is treated in situ before it enters the East Fork of Ninemile Creek, a tributary to the Coeur d'Alene River, Idaho. Microbially mediated SO4 reduction and the subsequent precipitation of sphalerite [ZnS] is the primary mechanism occurring for immobilization of Zn and Cd. Precipitation of pyromorphite [Pb10(PO4)6(OH,Cl)2] is the most likely mechanism for immobilization of Pb. Precipitation is occurring directly on the original Apatite II. The emplaced PRB has been operating successfully since January of 2001, and has reduced the concentrations of Cd and Pb to below detection (2 μg L-1), has reduced Zn to near background in this region (about 100 μg L-1), and has reduced SO4 by between 100 and 200 mg L-1 and NO3 to below detection (50 μg L-1). The PRB, filled with 90 tonnes of Apatite II, has removed about 4550 kg of Zn, 91 kg of Pb and 45 kg of Cd, but 90% of the immobilization is occurring in the first 20% of the barrier, wherein the reactive media now contain up to 25 wt% Zn. Field observations indicate that about 30% of the Apatite II material is spent (consumed).
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ISSN 0883-2927 ISBN Medium
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Notes Dec.; An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd; Science Direct Approved no
Call Number CBU @ c.wolke @ 17248 Serial 44
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Author Stoica, L.; Dima, G.
Title Pb(II) removal from aqueous systems by biosorption-flotation on mycelial residues of Penicillium chrysogenum Type Book Chapter
Year 2000 Publication (down) 7th international Mine Water Association congress; Mine water and the environment Abbreviated Journal
Volume Issue Pages 472-481
Keywords bioremediation; flotation; ground water; lead; metals; Penicillium; Penicillium chrysogenum; pollution; remediation; sorption; water treatment 22, Environmental geology
Abstract
Address
Corporate Author Thesis
Publisher Uniwersytet Slaski Place of Publication Sosnowiec Editor Rozkowski, A.
Language Summary Language Original Title
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ISSN ISBN 8387431230 Medium
Area Expedition Conference
Notes Pb(II) removal from aqueous systems by biosorption-flotation on mycelial residues of Penicillium chrysogenum; GeoRef; English; 2002-018169; 7th international Mine Water Association congress; Mine water and the environment, Katowice-Ustron, Poland, Sept. 11-15, 2000 References: 6; illus. incl. 4 tables Approved no
Call Number CBU @ c.wolke @ 5852 Serial 228
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Author Schwartz, M.O.; Ploethner, D.
Title From mine water to drinking water; heavy-metal removal by carbonate precipitation in the Grootfontein-Omatako Canal, Namibia Type Book Chapter
Year 1999 Publication (down) Abbreviated Journal
Volume Issue Pages
Keywords Africa; aluminum; cadmium; canals; carbonates; copper; drinking water; geochemistry; Grootfontein-Omatako Canal; heavy metals; hydrochemistry; iron; lead; manganese; metallogenic provinces; metals; mine drainage; mineral deposits, genesis; mines; Namibia; policy; precipitation; purification; Southern Africa; transport; water management; water treatment 22, Environmental geology
Abstract
Address
Corporate Author Thesis
Publisher Bundesanst. fuer Geowiss. und Rohstoffe Place of Publication Hanover Editor
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ISSN ISBN Medium
Area Expedition Conference
Notes From mine water to drinking water; heavy-metal removal by carbonate precipitation in the Grootfontein-Omatako Canal, Namibia; GeoRef; English; 2002-033925; International congress on Mine, water and environment, Seville, Spain, Sept. 13, 1999 References: 7; 2 tables, sketch maps Approved no
Call Number CBU @ c.wolke @ 5929 Serial 250
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Author Davies, G.J.; Holmes, M.; Wireman, M.; King, K.; Gertson, J.N.; Stefanic, J.M.
Title Water tracing at scales of hours to decades as an aid to estimating hydraulic characteristics of the Leadville Mine drainage tunnel Type Journal Article
Year 2001 Publication (down) Abbreviated Journal
Volume Issue Pages
Keywords acid mine drainage Arkansas River Colorado drainage dye tracers field studies fluorescence ground water Lake County Colorado Leadville Mine Leadville mining district pH quantitative analysis recharge surveys tunnels United States water treatment 30 Engineering geology 21 Hydrogeology
Abstract The Leadville Mine Drainage Tunnel (LMDT) is a 3.3 kilometer structure that was constructed in the complicated geology of the Leadville mine district in the 1940's. Discharge from the LMDT is impacted by heavy metals and is treated at a plant built in 1992 operated by the United States Bureau of Reclamation. On the surface waste rock and other remnants of the mining operations litter the landscape and this material is exposed to precipitation. As a result of contact with this material, surface water often has pH of less than 3 and its containment and disposal is necessary before it impacts surface drainage and the nearby Arkansas River. Using a borehole drilled into the mine workings the U.S. EPA has devised a plan in which the impacted water is contained on the surface which then can be discharged into the mine workings to discharge from the LMDT and be treated. The percentage of water discharging from the mining district along the drainage tunnel is unknown, and since there is no access, information about the condition of the tunnel with regards to blockages is also relatively obscure. Application of quantitative water tracing using fluorescent dyes was used to model the flow parameters at the scale of hours in the tunnel and evaluate the likelihood of blockages. Because the tunnel has intersected several lithologies and faults, other locations such as discharging shafts, adits and surface streams that could be hydraulically connected to the LMDT were also monitored. An initial tracer experiment was done using an instantaneous injection, which was followed by additional injections of water. Another tracer injection was done when there was a continuous flow of impacted water into the workings. Analysis of the tracer concentration responses at water-filled shafts and at the portal were used to model the flow along the tunnel and estimate several hydraulic parameters. Waters in these settings are mixtures of components with different residence times, so, qualitative tritium data were used to evaluate residence times of decades. The combined injected tracer and tritium data as well as other geochemical data were used to infer the nature of flow and recharge into the tunnel.
Address
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Publisher Abstracts with Programs - Geological Society of America Place of Publication Editor
Language Summary Language Original Title
Series Editor Series Title Geological Society of America, 2001 annual meeting Abbreviated Series Title
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Notes 2004-013418; Geological Society of America, 2001 annual meeting, Boston, MA, United States, Nov. 1-10, 2001; GeoRef; English Approved no
Call Number CBU @ c.wolke @ 16511 Serial 408
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