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Totsche, O.; Fyson, A.; Kalin, M.; Steinberg Christian, E.W. |
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Title |
Titration curves: A useful instrument for assessing the buffer systems of acidic mining waters |
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Journal Article |
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2006 |
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ESPR Environmental Science and Pollution Research |
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13 |
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4 |
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215-224 |
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Abwasseraufbereitung Bergbau Titration Säuregehalt Grundwasser Pufferlösung Neutralisation Titrationskurve Bergbauabwasser |
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Abstract |
The acidification of mine waters is generally caused by metal sulfide oxidation, related to mining activities. These waters are characterized by low pH and high acidity due to strong buffering systems. The standard acidity parameter, the BNC (Base Neutralization Capacity), is determined by endpoint titration, and reflects a cumulative parameter of both hydrogen ions and all buffering systems, but does not give information on the individual buffer systems. It is demonstrated that a detailed interpretation of titration curves can provide information about the strength of the buffering systems. The buffering systems are of importance for environmental studies and treatment of acidic mining waters. Titrations were carried out by means of an automatic titrator using acidic mining waters from Germany and Canada. The curves were interpreted, compared with each other, to endpoint titration results and to elemental concentrations contained therein. The titration curves were highly reproducible, and contained information about the strength of the buffer systems present. Interpretations are given, and the classification and comparison of acidic mining waters, by the nature and strength of their buffering systems derived from titration curves are discussed. The BNC-values calculated from the curves were more precise than the ones determined by the standard endpoint titration method. Due to the complex buffer mechanisms in acidic mining waters, the calculation of major metal concentrations from the shape of the titration curve resulted in estimates, which should not be confused with precise elemental analysis results. Conclusion. Titration curves provide an inexpensive, valuable and versatile tool, by which to obtain sophisticated information of the acidity in acidic water. The information about the strength of the present buffer systems can help to understand and document the complex nature of acidic mining water buffer systems. Finally, the interpretation of titration curves could help to improve treatment measurements and the ecological understanding of these acidic waters. |
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Leibniz-Institut für Gewässerökologie und Binnenfischerei, Berlin, DE; Boojum Research, Toronto, CA; Humboldt-Universität Berlin, DE |
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0944-1344 |
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Titration curves: A useful instrument for assessing the buffer systems of acidic mining waters; 39481, BERG , 13.11.06; Words: 519; 200610 05282; 10 Seiten, 15 Bilder, 2 Tabellen, 39 Quellen 3UXX *Belastung von Wasser, Wasserreinhaltung, Abwasser* 3BX *chemische Grundlagen* 3IFC *Messung und Prüfung chemischer Größen, chemische Analytik* 3MZ *Bergbau, Tunnelbau, Erdöl /Erdgasförderung, Bohrtechnik*; BERG, Copyright FIZ Technik e.V.; EN Englisch |
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CBU @ c.wolke @ 17580 |
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224 |
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Author |
Driussi, C. |
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Title |
Technological options for waste minimisation in the mining industry |
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Journal Article |
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2006 |
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J. Cleaner Prod. |
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14 |
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8 |
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682-688 |
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mine water treatment |
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Just as the application of technology in mining processes can cause pollution, it can also be harnessed to minimise, and sometimes eliminate, mine-related contaminants. Waste minimisation can be achieved through decreased waste production, waste collection, waste recycling, and the neutralisation of pollutants into detoxified forms. This article reviews examples of how technology can be used to minimise air, water, land and noise pollution in the mining industry. (c) 2005 Elsevier Ltd. All rights reserved. |
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Technological options for waste minimisation in the mining industry; Wos:000237749600002; Times Cited: 1; ISI Web of Science |
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CBU @ c.wolke @ 16924 |
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110 |
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Simmons, J.A.; Andrew, T.; Arnold, A.; Bee, N.; Bennett, J.; Grundman, M.; Johnson, K.; Shepherd, R. |
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Small-Scale Chemical Changes Caused by In-stream Limestone Sand Additions to Streams |
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Journal Article |
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2006 |
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Mine Water Env. |
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25 |
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4 |
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241-245 |
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acid mine drainage aluminum calcium limestone sand sediment stream liming West Virginia |
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In-stream limestone sand addition (ILSA) has been employed as the final treatment for acid mine drainage discharges at Swamp Run in central West Virginia for six years. To determine the small-scale longitudinal variation in stream water and sediment chemistry and stream biota, we sampled one to three locations upstream of the ILSA site and six locations downstream. Addition of limestone sand significantly increased calcium and aluminum concentrations in sediment and increased the pH, calcium, and total suspended solids of the stream water. Increases in alkalinity were not significant. The number of benthic macroinvertebrate taxa was significantly reduced but there was no effect on periphyton biomass. Dissolved aluminum concentration in stream water was reduced, apparently by precipitation into the stream sediment. |
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1025-9112 |
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Small-Scale Chemical Changes Caused by In-stream Limestone Sand Additions to Streams; 1; FG 4 Abb., 2 Tab.; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 17420 |
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248 |
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Plant, J. |
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Removal of base metals from mine waters using passive treatment processes involving autocatalytic oxidation and adsorption |
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2006 |
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Acid mine drainage Water — Pollution Mineral industries. — Wales |
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Removal of base metals from mine waters using passive treatment processes involving autocatalytic oxidation and adsorption; Opac |
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CBU @ c.wolke @ 7100 |
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269 |
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Edraki, M. |
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Post closure management of the Mt Leyshon Gold Mine – Water the integrator |
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2006 |
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Water in Mining 2006, Proceedings |
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233-242 |
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mine water treatment |
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Mining at the Mt Leyshon Gold Mine in semi-arid north Queensland stopped in 2002. Newmont Australia has recently initiated a thorough post-closure water management study of the site by revisiting the existing information and conducting new water-related investigations. The focus of this paper. which is the first publication on post-closure environmental management of the site. is an overview of the site water quality in view of the sources and spatial distribution of polluted mine water, and also the performance of cover systems in controlling water flux though mine wastes. |
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Post closure management of the Mt Leyshon Gold Mine – Water the integrator; Isip:000243724400032; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 16925 |
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150 |
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