| Records |
| Author |
Diz, H.R. |
| Title |
Chemical and biological treatment of acid mine drainage for the removal of heavy metals and acidity |
Type |
Book Whole |
| Year |
1997 |
Publication |
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Abbreviated Journal |
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| Volume |
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Issue |
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Pages |
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| Keywords |
acid mine drainage; copper; effluents; ferrous iron; heavy metals; iron; manganese; metals; nickel; oxidation; pH; pollution; precipitation; rates; tailings; temperature; waste water; zinc 22, Environmental geology |
| Abstract |
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| Address |
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| Corporate Author |
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Thesis |
Ph.D. thesis |
| Publisher |
Virginia Polytechnic Institute and State University, |
Place of Publication |
Blacksburg |
Editor |
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| Language |
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Summary Language |
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Original Title |
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| Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Issue |
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ISBN |
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Notes  |
Chemical and biological treatment of acid mine drainage for the removal of heavy metals and acidity; GeoRef; English |
Approved |
no |
| Call Number |
CBU @ c.wolke @ 6316 |
Serial |
400 |
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| Author |
Conca, J.L.; Wright, J. |
| Title |
An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd |
Type |
Journal Article |
| Year |
2006 |
Publication |
Appl. Geochem. |
Abbreviated Journal |
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| Volume |
21 |
Issue |
12 |
Pages |
2188-2200 |
| Keywords |
Pollution and waste management non radioactive Groundwater quality apatite groundwater remediation zinc lead cadmium acid mine drainage copper sulfate nitrate permeability water treatment precipitation chemistry |
| Abstract |
Phosphate-induced metal stabilization involving the reactive medium Apatite II(TM) [Ca10-xNax(PO4)6-x(CO3)x(OH)2], where x < 1, was used in a subsurface permeable reactive barrier (PRB) to treat acid mine drainage in a shallow alluvial groundwater containing elevated concentrations of Zn, Pb, Cd, Cu, SO4 and NO3. The groundwater is treated in situ before it enters the East Fork of Ninemile Creek, a tributary to the Coeur d'Alene River, Idaho. Microbially mediated SO4 reduction and the subsequent precipitation of sphalerite [ZnS] is the primary mechanism occurring for immobilization of Zn and Cd. Precipitation of pyromorphite [Pb10(PO4)6(OH,Cl)2] is the most likely mechanism for immobilization of Pb. Precipitation is occurring directly on the original Apatite II. The emplaced PRB has been operating successfully since January of 2001, and has reduced the concentrations of Cd and Pb to below detection (2 μg L-1), has reduced Zn to near background in this region (about 100 μg L-1), and has reduced SO4 by between 100 and 200 mg L-1 and NO3 to below detection (50 μg L-1). The PRB, filled with 90 tonnes of Apatite II, has removed about 4550 kg of Zn, 91 kg of Pb and 45 kg of Cd, but 90% of the immobilization is occurring in the first 20% of the barrier, wherein the reactive media now contain up to 25 wt% Zn. Field observations indicate that about 30% of the Apatite II material is spent (consumed). |
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Place of Publication |
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Original Title |
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Series Title |
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Abbreviated Series Title |
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Series Issue |
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Edition |
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| ISSN |
0883-2927 |
ISBN |
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| Notes |
Dec.; An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd; Science Direct |
Approved |
no |
| Call Number |
CBU @ c.wolke @ 17248 |
Serial |
44 |
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| Author |
Cravotta, C.A., III; Watzlaf, G.R.; Naftz, D.L.; Morrison, S.J.; Fuller, C.C.; Davis, J.A. |
| Title |
Design and performance of limestone drains to increase pH and remove metals from acidic mine drainage Handbook of groundwater remediation using permeable reactive barriers; applications to radionuclides, trace metals, and nutrients |
Type |
Book Chapter |
| Year |
2002 |
Publication |
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Abbreviated Journal |
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| Volume |
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Issue |
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Pages |
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| Keywords |
acid mine drainage; alkaline earth metals; aquatic environment; aquifers; calcium; carbonate rocks; chemical properties; construction; construction materials; crushed stone; dissolved materials; drainage; effluents; ground water; limestone; magnesium; metals; pH; pollution; porous materials; precipitation; retention; saturation; sedimentary rocks; sulfate ion; suspended materials 22, Environmental geology |
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Thesis |
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| Publisher |
Academic Press |
Place of Publication |
Amsterdam |
Editor |
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Summary Language |
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Original Title |
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Edition |
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ISBN |
0125135637 |
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| Notes |
Design and performance of limestone drains to increase pH and remove metals from acidic mine drainage Handbook of groundwater remediation using permeable reactive barriers; applications to radionuclides, trace metals, and nutrients; GeoRef; English; 2004-040518; References: 66; illus. incl. 4 tables |
Approved |
no |
| Call Number |
CBU @ c.wolke @ 5686 |
Serial |
81 |
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| Author |
Cram, J.C. |
| Title |
Diversion well treatment of acid water, Lick Creek, Tioga County, PA |
Type |
Book Whole |
| Year |
1996 |
Publication |
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Abbreviated Journal |
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| Volume |
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Issue |
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Pages |
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| Keywords |
acid mine drainage acid rain atmospheric precipitation carbonate rocks diversion wells Lick Creek limestone Pennsylvania pH pollution rain sedimentary rocks surface water Tioga County Pennsylvania United States water quality water treatment wells 22, Environmental geology |
| Abstract |
Diversion wells implement a fluidized bed of limestone for the treatment of acid water resulting from acid mine drainage or acid precipitation. This study was undertaken to better understand the operation of diversion wells and to define the physical and chemical factors having the greatest impact on the neutralization performance of the system. The study site was located near Lick Creek, a tributary stream of Babb Creek, near the Village of Arnot in Tioga County, Pennsylvania. Investigative methods included collection and analysis of site water quality and limestone data and field study of this as well as other diversion well sites. Analysis of data led to these general conclusions: The site received surface water influenced by three primary sources 1) precipitation, 2) mine drainage baseflow, and 3) melted snow. Water mostly influenced by precipitation events and mine drainage baseflow was more acidic than water influenced by melting snow conditions. The diversion wells were generally able to treat only half or less of the total stream flow of Lick Creek and under extremely high flow conditions the treatment provided was minimal. A range of flow conditions were identified which produced the best performance for the two diversion wells. Treatment produced by the system decreased through the loading cycle and increases to a maximum value after each weekly refilling of limestone. Fine grained sediment in the stream was found to be limestone of the same general composition as the material placed within the wells. Neutralization of acid water was largely due to microscopic particles rather than the limestone sediment discharged to the stream. Additional downstream buffering due to the limestone sediment physically discharged from the vessels was not apparent. Diversion well systems are inexpensive and simple to construct. In addition, the systems were found to be highly reliable and able to effectively treat acid water resulting from mine drainage and acid precipitation. Diversion wells provide better treatment when the treatment site is located at the source of the acidity (such as a mine discharge), rather than at the receiving stream. Systems should be designed with 15 to 20 feet of hydraulic head and the site must have year-round access. Diversion well systems require weekly addition of limestone gravel to the vessels to facilitate continual treatment. A great deal of commitment is necessary to maintain a diversion well system for long periods of time. These systems are more economical and require less attention that conventional chemical treatment of acid water. However, these systems require more attention that traditional passive treatment methods for treatment of acid, including mine drainage. |
| Address |
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| Corporate Author |
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Thesis |
Ph.D. thesis |
| Publisher |
Pennsylvania State University at University Park, |
Place of Publication |
University Park |
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Summary Language |
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Original Title |
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Conference |
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| Notes |
Diversion well treatment of acid water, Lick Creek, Tioga County, PA; GeoRef; English; References: 49; illus. |
Approved |
no |
| Call Number |
CBU @ c.wolke @ 16652 |
Serial |
411 |
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| Author |
Arango, I. |
| Title |
Evaluation of the beneficial effects of the acidophilic alga Euglena mutabilis on acid mine drainage systems |
Type |
Book Whole |
| Year |
2002 |
Publication |
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Abbreviated Journal |
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| Volume |
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Issue |
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Pages |
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| Keywords |
acid mine drainage atmospheric precipitation benthic taxa bioremediation dissolved materials dissolved oxygen electron microscopy data Euglena mutabilis Green Valley Mine ICP mass spectra Indiana iron mass spectra metals microorganisms mines oxygen pH photochemistry photosynthesis pollution rain remediation sediments soils spectra temperature United States Vigo County Indiana water 22, Environmental geology |
| Abstract |
Euglena mutabilis is an acidophilic, photosynthetic protozoan that forms benthic mats in acid mine drainage (AMD) channels. At the Green Valley mine, western Indiana, E. mutabilis resides in AMD measuring <4.2 pH, with high concentrations of dissolved constituents (up to 22.67 g/l). One of the main factors influencing E. mutabilis distribution is water temperature. The microbe forms thick (>1 mm), extensive mats during spring and fall, when water temperature is between 13 and 28 degrees C. During winter and summer, when temperatures are outside this range, benthic communities have a very patchy distribution and are restricted to areas protected from extreme temperature changes. E. mutabilis also responds to rapid increases in pH, which are associated with rainfall events. During these events pH can increase above 4.0, causing precipitation of Fe and Al oxy-hydroxides that cover the mats. The microbe responds by moving through the precipitates, due to phototaxis, and reestablishing the community at the sediment-water interface within 12 hours. The biological activities of E. mutabilis may have a beneficial effect on AMD systems by removing iron from effluent via oxygenic photosynthesis, and/or by internal sequestration. Photosynthesis by E. mutabilis contributes elevated concentrations of dissolved oxygen (DO), up to 17.25 mg/l in the field and up to 11.83 mg/l in the laboratory, driving oxidation and precipitation of reduced metal species, especially Fe (II), which are dissolved in the effluent. In addition, preliminary electro-microscopic and staining analyses of the reddish intracellular granules in E. mutabilis indicate that the granules contain iron, suggesting that E. mutabilis sequesters iron from AMD. Inductive coupled plasma analysis of iron concentration in AMD with and without E. mutabilis also shows that E. mutabilis accelerates the rate of Fe removal from the media. Whether iron removal is accelerated by internal sequestration of iron and/or by precipitation via oxygenic photosynthesis has yet to be determined. These biological activities may play an important role in the natural remediation of AMD systems. |
| Address |
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| Corporate Author |
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Thesis |
Ph.D. thesis |
| Publisher |
Indiana State University, |
Place of Publication |
Terre Haute |
Editor |
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Summary Language |
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Original Title |
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Series Issue |
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Edition |
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Conference |
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| Notes |
Evaluation of the beneficial effects of the acidophilic alga Euglena mutabilis on acid mine drainage systems; GeoRef; English; References: 39; illus. incl. 3 tables |
Approved |
no |
| Call Number |
CBU @ c.wolke @ 16491 |
Serial |
476 |
| Permanent link to this record |
