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Author |
Evangelou, V.P. |
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Title |
Pyrite microencapsulation technologies: Principles and potential field application |
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Journal Article |
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Year |
2001 |
Publication |
Ecological Engineering |
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17 |
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2-3 |
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165-178 |
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Keywords |
mine water treatment Acid mine drainage Acidity Alkalinity Amelioration Coating Oxidation Surface reactions |
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Abstract |
In nature, pyrite is initially oxidized by atmospheric O2, releasing acidity and Fe2+. At pH below 3.5, Fe2+ is rapidly oxidized by T. ferrooxidans to Fe3+, which oxidizes pyrite at a much faster rate than O2. Commonly, limestone is used to prevent pyrite oxidation. This approach, however, has a short span of effectiveness because after treatment the surfaces of pyrite particles remain exposed to atmospheric O2 and oxidation continuous abiotically. Currently, a proposed mechanism for explaining non-microbial pyrite oxidation in high pH environments is the involvement of OH- in an inner-sphere electron-OH exchange between pyrite/surface-exposed disulfide and pyrite/surface-Fe(III)(OH)n3-n complex and/or formation of a weak electrostatic pyrite/surface-CO3 complex which enhances the chemical oxidation of Fe2+. The above infer that limestone application to pyritic geologic material treats only the symptoms of pyrite oxidation through acid mine drainage neutralization but accelerates non-microbial pyrite oxidation. Therefore, only a pyrite/surface coating capable of inhibiting O2 diffusion is expected to control long-term oxidation and acid drainage production. The objective of this study was to examine the feasibility in controlling pyrite oxidation by creating, on pyrite surfaces, an impermeable phosphate or silica coating that would prevent either O2 or Fe3+ from further oxidizing pyrite. The mechanism underlying this coating approach involves leaching mine waste with a coating solution composed of H2O2 or hypochlorite, KH2PO4 or H4SiO4, and sodium acetate (NaAC) or limestone. During the leaching process, H2O2 or hypochlorite oxidizes pyrite and produces Fe3+ so that iron phosphate or iron silicate precipitates as a coating on pyrite surfaces. The purpose of NaAC or limestone is to eliminate the inhibitory effect of the protons (produced during pyrite oxidation) on the precipitation of iron phosphate or silicate and to generate iron-oxide pyrite coating, which is also expected to inhibit pyrite oxidation. The results showed that iron phosphate or silicate coating could be established on pyrite by leaching it with a solution composed of: (1) H2O2 0.018-0.16 M; (2) phosphate or silicate 10-3 to 10-2 M; (3) coating-solution pH [approximate]5-6; and (4) NaAC as low as 0.01 M. Leachates from column experiments also showed that silicate coatings produced the least amount of sulfate relative to the control, limestone and phosphate treatments. On the other hand, limestone maintained the leachate near neutral pH but produced more sulfate than the control. |
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0925-8574 |
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July 01; Pyrite microencapsulation technologies: Principles and potential field application; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10063.pdf; Science Direct |
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CBU @ c.wolke @ 10063 |
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37 |
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Laboratory, N.R.M.R. |
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Demonstration of Aquafix and SAPS passive mine water treatment technologies at the Summitville Mine site |
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RPT |
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2004 |
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Cincinnati, Ohio : National Risk Management Research Laboratory, Office of Research and Development, U.S. Environmental Protection Agency |
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Cincinnati, Ohio |
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June; Demonstration of Aquafix and SAPS passive mine water treatment technologies at the Summitville Mine site; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/7186.pdf; Opac |
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CBU @ c.wolke @ 7186 |
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63 |
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Ericsson, B.; Hallmans, B. |
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Title |
Treatment of saline wastewater for zero discharge at the Debiensko coal mines in Poland |
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1996 |
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Desalination |
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105 |
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1-2 |
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115-123 |
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mine water |
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The drainage water from mines in Poland has a daily contribution of, in the order of magnitude, 6,500 tons of chlorides and 0.5 ton of sulphates to the rivers Vistula (Wisla) and Oder (Odra). The largest amounts of these salts, about 78%, derive from 18 mines located mainly in the Katowice mine district. The high salt content in the water from the Vistula prevents at present its use in agriculture and causes tremendous economic losses due to corrosion attacks on pipes, machines, etc., within the industry. At present only about 4% of the river water can be classified as drinking water. To combat this problem a desalination project in Katowice has now almost been completed, including advanced treatment of wastewater for zero discharge from the two adjacent coal mines, Debiensko and Budryk. It implies elimination of 310 tons/d of salt discharge to the Odra River. The complete treatment processes are divided into three main sections: (1) pretreatment before reverse osmosis (RO) of about 12,400 m3/d drainage water from the two mines with a salinity of around 16,000 mg/l TDS on the average; (2) RO plant including post-treatment of the RO permeate; (3) a thermal plant for concentration of brine (about 4,600 m3/d) and separation of sodium chloride (NaCl) by crystallization, centrifuging and drying. The RO pretreatment includes algicide dosing in a storage tank, disinfection, flocculation/sedimentation and dual media filtration as well as granular activated carbon filtration. After a two-stage microfilter system (50 μ and 5 μ, respectively), the pretreated water is desalinated at 6-7 MPa in a RO system with spiral wound RO membranes. The RO permeate is decarbonated in a part-flow followed by addition of chemicals for disinfection and increase of the temporary hardness before distribution in the drinking water net. The flow into the thermal plant consists of the RO reject (about 2,700 m3/d) with a salinity of around 80 g/l TDS and the brine flow (about 1,870 m3/d) from the Budryk mine with about the same salinity. The first section of the thermal plant is composed of two brine concentrators, designed by Resources Conservation Company (RCC), USA. By using the seed crystal recycling technique it is possible to concentrate the feed to near the precipitation point for NaCl. The second section of the thermal plant includes one crystallizer for production of NaCl, two pusher centrifuges for salt removal from supersaturated brine and one fluidized bed dryer. The crystallizer is a forced circulation submerged-tube evaporator equipped with a mechanical vapor compressor. An additional section is also planned to be constructed for treatment of the purge from the crystallizer in order to recover other valuable chemical products and distillate. The process is fully automatic and controlled by programmable logic controllers. The plant has finally been designed by Energotechnika, Poland, after preparation of technical and economical planning of the project in coordination with Nordcap Ltd., RCC and VBB Viak-SWECO, Stockholm. In the summer 1994 the thermal plant was started up, and the RO plant is expected to be in operation during the spring 1995. The paper covers the project design with illustrations of the main parts of the plant and summarizes the results of the initial operation. |
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0011-9164 |
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June; Treatment of saline wastewater for zero discharge at the Debiensko coal mines in Poland; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/9451.pdf; Science Direct |
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CBU @ c.wolke @ 17274 |
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53 |
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Author |
Lushnikova, O.Y. |
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Kompleksirovaniye metodov tamponazha i biolokatsii dlya zashchity podzemnykh vod ot zagryazneniya i istoshcheniya. Combined methods of grouting and biolocation for protection of ground water from pollution and depletion |
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Year |
1996 |
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Izvestiya Vysshikh Uchebnykh Zavedeniy. Gornyy Zhurnal |
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1996 |
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12 |
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49-52 |
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Keywords |
acid mine drainage; conservation; ecology; fluorimetry; geochemistry; ground water; grouting; hydrology; industrial waste; land use; leaking underground storage tanks; mines; monitoring; natural resources; pollutants; pollution; reclamation; soil treatment; soils; toxic materials; waste disposal; water quality; water regimes; water table 22, Environmental geology |
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0536-1028 |
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Kompleksirovaniye metodov tamponazha i biolokatsii dlya zashchity podzemnykh vod ot zagryazneniya i istoshcheniya. Combined methods of grouting and biolocation for protection of ground water from pollution and depletion; 1997-070630; Russian Federation (RUS); GeoRef; Russian |
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CBU @ c.wolke @ 6326 |
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312 |
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Author |
Bannister, A.F. |
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Book Whole |
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1997 |
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105-122 |
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wetland coal mining Doworth |
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Chartered Institution of Water and Environmental Management |
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London |
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Younger Paul, L. |
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Minewater Treatment Using Wetlands |
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Lagoon and reed-bed treatment of colliery shale tip water at Doworth, South Yorkshire; 1; AMD ISI | Wolkersdorfer; Fg |
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CBU @ c.wolke @ 9517 |
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466 |
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