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Goulet, R. R. (2001). The evaluation of metal retention by a constructed wetland using the pulmonate gastropod Helisoma trivolvis (Say). Archives of Environmental Contamination and Toxicology, 40(3), 303–310.
Abstract: Constructed wetlands are built because they can act as sinks fur many pollutants, thereby protecting the water quality of downstream ecosystems. The treatment performance is generally assessed using mass balance calculations. Along with the mass balance approach, we compared the metal content of populations of a common pond snail (Helisoma trivolvis Say) collected upstream and downstream of a 3-year-old constructed wetland. Snails were collected in early May, June, and August 1998. At the same time, water samples for particulate and dissolved metals were taken every 3 days for the duration of the experiment. Overall, the wetland retained most dissolved metals, including Fe, Mn, Cu, Zn, Ni, and Pb, but released dissolved As. However, the wetland released particulate Fe and Mn. With the exception of Zn, the metal concentrations of the downstream snails were on average higher than those measured in the upstream population. The higher metal content of downstream snails was likely related to the significant export of particulate metals by the wetland, despite the overall retention of dissolved metals. This study points to the need for biological as well as chemical monitoring to determine the treatment efficiency and toxicological risk associated with constructed wetlands.
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Coulton, R., Bullen, C., & Hallett, C. (2003). The design and optimisation of active mine water treatment plants. Land Contam. Reclam., 11(2), 273–280.
Abstract: This paper provides a 'state of the art' overview of active mine water treatment. The paper discusses the process and reagent selection options commonly available to the designer of an active mine water treatment plant. Comparisons are made between each of these options, based on technical and financial criteria. The various different treatment technologies available are reviewed and comparisons made between conventional precipitation (using hydroxides, sulphides and carbonates), high density sludge processes and super-saturation precipitation. The selection of reagents (quick lime, slaked lime, sodium hydroxide, sodium carbonate, magnesium hydroxide, and proprietary chemicals) is considered and a comparison made on the basis of reagent cost, ease of use, final effluent quality and sludge settling criteria. The choice of oxidising agent (air, pure oxygen, peroxide, etc.) for conversion of ferrous to ferric iron is also considered. Whole life costs comparisons (capital, operational and decommissioning) are made between conventional hydroxide precipitation and the high density sludge process, based on the actual treatment requirements for four different mine waters.
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Lawrence, R. (2002). Technology reduces sulphur compounds – A new way of treating acid mine drainage. Canadian Mining Journal, 123(7), 27.
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Driussi, C. (2006). Technological options for waste minimisation in the mining industry. J. Cleaner Prod., 14(8), 682–688.
Abstract: Just as the application of technology in mining processes can cause pollution, it can also be harnessed to minimise, and sometimes eliminate, mine-related contaminants. Waste minimisation can be achieved through decreased waste production, waste collection, waste recycling, and the neutralisation of pollutants into detoxified forms. This article reviews examples of how technology can be used to minimise air, water, land and noise pollution in the mining industry. (c) 2005 Elsevier Ltd. All rights reserved.
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Zou, L. H. (2000). Sulfide precipitation flotation for treatment of acidic mine waste water. Transactions of Nonferrous Metals Society of China, 10, 106–109.
Abstract: Sulfide precipitation flotation of copper-iron-bearing acidic waste water from a large copper mine and the stimulated waste water were studied. The pH of the waste water was 2.2, with 130 mg/L Cu2+ and 500 mg/L Fe3+ (Fe2+). Results show that, when Na2S was added as precipitating agent, sodium butylxanthate as collector and at pH 2.0, the removal of copper could be as high as 99.7 % and the residual copper decreased to 0.2 mg/L, however, almost no iron was removed. When the floated solution was neutralized to pH = 8.0, more than 98 % iron was precipitated and the residual iron was less than 10 mg/L. In experiment on actual mine effluents, after the use of precipitate flotation technology to recover copper and pH neutralization to precipitate iron, the treated waste water does meet the emission standards for sewage and valuable floating copper graded 37.12%. The chemical calculation and mechanism of solution were also presented.
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