Burgess, J. E., & Stuetz, R. M. (2002). Activated Sludge for the Treatment of Sulphur-rich Wastewaters. Miner. Eng., 15(11), 839–846.
Abstract: The aim of this investigation was to assess the potential of activated sludge for the remediation of sulphur-rich wastewaters. A pilot-scale activated sludge plant was acclimatised to a low load of sulphide and operated as a flow-through unit. Additional sludge samples from different full-scale plants were compared with the acclimatised and unacclimatised sludges using batch absorption tests. The effects of sludge source and acclimatisation on the ability of the sludge to biodegrade high loads of sulphide were evaluated. Acclimatisation to low-sulphide concentrations enabled the sludge to degrade subsequent high loads which were toxic to unacclimatised sludge. Acclimatisation was seen to be an effect of selection pressure on the biomass, suggesting that the treatment capability of activated sludge will develop after acclimation, indicating potential for treatment of acid mine drainage (AMD) by a standard wastewater treatment process. Existing options for biological treatment of AMD are described and the potential of activated sludge treatment for AMD discussed in comparison with existing technologies. (C) 2002 Elsevier Science Ltd.
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Matlock, M. M., Howerton, B. S., & Atwood, D. A. (2002). Chemical precipitation of heavy metals from acid mine drainage. Water Res, 36(19), 4757–4764.
Abstract: The 1,3-benzenediamidoethanethiol dianion (BDET, known commercially as MetX) has been developed to selectively and irreversibly bind soft heavy metals from aqueous solution. In the present study BDET was found to remove >90% of several toxic or problematic metals from AMD samples taken from an abandoned mine in Pikeville, Kentucky. The concentrations of metals such as iron, may be reduced at pH 4.5 from 194 ppm to below 0.009 ppm. The formation of stoichiomietric BDET-metal precipitates in this process was confirmed using X-ray powder diffraction (XRD), proton nuclear magnetic resonance (1H NMR), and infrared spectroscopy (IR).
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Wolkersdorfer, C., & Younger, P. L. (2002). Passive mine water treatment as an alternative to active systems. Grundwasser, 7(2), 67–77.
Abstract: For the treatment of contaminated mine waters reliable treatment methods with low investment and operational costs are essential. Therefore, passive treatment systems recently have been installed in Great Britain and in Germany (e.g. anoxic limestone drains, constructed wetlands, reactive barriers, roughing filters) and during the last eight years such systems successfully treated mine waters, using up to 6 ha of space. In some cases with highly contaminated mine water, a combination of active and passive systems should be applied, as in any case the water quality has to reach the limits. Because not all the processes of passive treatment systems are understood in detail, current research projects (e.g. EU-project PIRAMID) were established to clarify open questions.
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Scholz, M. (2002). Performance comparison of experimental constructed wetlands with different filter media and macrophytes treating industrial wastewater contaminated with lead and copper. Bioresource Technology, 83(2), 71–79.
Abstract: The aim of this study was to investigate the treatment efficiency of passive vertical-flow wetland filters containing different macrophytes (Phragmites and/or Typha) and granular media with different adsorption capacities. Gravel, sand, granular activated carbon, charcoal and Filtralite (light expanded clay) were used as filter media. Different concentrations of lead and copper sulfate were added to polluted urban stream inflow water to simulate pretreated mine wastewater. The relationships between growth media, microbial and plant communities as well as the reduction of predominantly lead, copper and five-day biochemical oxygen demand (BOD5) were investigated. An analysis of variance showed that concentration reductions (mg 1(-1)) of lead, copper and BOD5 were significantly similar for the six experimental wetlands. Microbial diversity was low due to metal pollution and similar for all filters. There appears to be no additional benefit in using adsorption media and macrophytes to enhance biomass performance during the first 10 months of operation. (C) 2002 Elsevier Science Ltd. All rights reserved.
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Scharp, R. A., Kawahara, F., Burckle, J., Allan, J., & Govind, R. (2002). Recovery of metals from acid mine drainage Hardrock mining 2002; issues shaping the industry..
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